Skip to Main content Skip to Navigation
New interface
Journal articles

Advances in the synthesis of silyl-modified polymers (SMPs)

Abstract : Silyl-modified polymers (SMPs) are alkoxysilyl functionalized polymers of high importance both academically and industrially. SMPs are being developed for coating, adhesive, sealant and elastomer applications. In this paper, emphasis is placed first on the different chemical modification approaches available to tackle the synthesis of SMPs by in situ functionalization (ISF) and post-polymerization functionalization (PPF) routes, with their pros and cons being underlined. Recent progress and modern trends towards alkoxysilyl telechelic polyenes and polyolefins by olefin metathesis strategies are next discussed. The state-of-the-art of alkoxysilyl functionalized polymers, especially of telechelic ones, delineated according to the latter two main synthetic pathways, is then covered along with their subsequent curing, and is illustrated by selected examples including, in particular, polyenes, polyolefins and some other selected relevant polymers.
Document type :
Journal articles
Complete list of metadata

Cited literature [135 references]  Display  Hide  Download
Contributor : Laurent Jonchère Connect in order to contact the contributor
Submitted on : Wednesday, July 18, 2018 - 3:22:35 PM
Last modification on : Tuesday, January 4, 2022 - 4:26:11 AM
Long-term archiving on: : Friday, October 19, 2018 - 9:16:16 PM


Guillaume - Advances in the sy...
Files produced by the author(s)



Sophie M. Guillaume. Advances in the synthesis of silyl-modified polymers (SMPs). Polymer Chemistry, 2018, 9 (15), pp.1911-1926. ⟨10.1039/c8py00265g⟩. ⟨hal-01807070⟩



Record views


Files downloads