M. L. Zastrow and V. L. Pecoraro, Designing Hydrolytic Zinc Metalloenzymes, Biochemistry, vol.53, issue.6, pp.957-978, 2014.
DOI : 10.1021/bi4016617

URL : https://doi.org/10.1021/bi4016617

J. L. Boer, S. B. Mulrooney, and R. P. Hausinger, Nickel-dependent metalloenzymes, Archives of Biochemistry and Biophysics, vol.544, pp.142-152, 2014.
DOI : 10.1016/j.abb.2013.09.002

URL : http://europepmc.org/articles/pmc3946514?pdf=render

M. Can, F. A. Armstrong, and S. W. Ragsdale, Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase, Chemical Reviews, vol.114, issue.8, pp.4149-4174, 2014.
DOI : 10.1021/cr400461p

R. Hille, J. Hall, and P. Basu, The Mononuclear Molybdenum Enzymes, Chemical Reviews, vol.114, issue.7, pp.3963-4038, 2014.
DOI : 10.1021/cr400443z

Y. Lin, Rational design of metalloenzymes: From single to multiple active sites, Coordination Chemistry Reviews, vol.336, pp.1-27, 2017.
DOI : 10.1016/j.ccr.2017.01.001

J. P. Collman, Inorganic Chemistry, vol.36, issue.23, pp.5145-5155, 1997.
DOI : 10.1021/ic971037w

A. Stassinopoulos, S. Mukerjee, and J. P. Caradonna, Reactivity Models for Dinuclear Iron Metalloenzymes, Mechanistic Bioinorganic Chemistry, vol.246, pp.83-120, 1996.
DOI : 10.1021/ba-1995-0246.ch004

E. I. Solomon, D. E. Heppner, E. M. Johnston, J. W. Ginsbach, J. Cirera et al.,

C. H. Kieber-emmons, R. G. Kjaergaard, L. Hadt, and . Tian, Chemical Reviews, vol.114, pp.3659-3853, 2014.

P. E. Siegbahn and M. R. Blomberg, Quantum Chemical Studies of Proton-Coupled Electron Transfer in Metalloenzymes, Chemical Reviews, vol.110, issue.12, pp.7040-7061, 2010.
DOI : 10.1021/cr100070p

J. Liu, S. Chakraborty, P. Hosseinzadeh, Y. Yu, S. Tian et al., Metalloproteins Containing Cytochrome, Iron???Sulfur, or Copper Redox Centers, Chemical Reviews, vol.114, issue.8, pp.4366-4469, 2014.
DOI : 10.1021/cr400479b

D. Schilter, J. M. Camara, M. T. Huynh, S. Hammes-schiffer, and T. B. Rauchfuss, Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides, Chemical Reviews, vol.116, issue.15, pp.8693-8749, 2016.
DOI : 10.1021/acs.chemrev.6b00180

V. C. Wang, S. Maji, P. P. Chen, H. K. Lee, S. S. Yu et al., Alkane Oxidation: Methane Monooxygenases, Related Enzymes, and Their Biomimetics, Chemical Reviews, vol.117, issue.13, pp.8574-8621, 2017.
DOI : 10.1021/acs.chemrev.6b00624

G. Schenk, N. Mitic, L. R. Gahan, D. L. Ollis, R. P. Mcgeary et al., Acc. Chem

. Res, , pp.1593-1603, 2012.

D. E. Wilcox, Binuclear Metallohydrolases, Chemical Reviews, vol.96, issue.7, pp.2435-2458, 1996.
DOI : 10.1021/cr950043b

C. Liu, L. Wang, and D. Transactions, , pp.227-239, 2009.

G. Schenk, N. Miti?, G. R. Hanson, and P. Comba, Purple acid phosphatase: A journey into the function and mechanism of a colorful enzyme, Coordination Chemistry Reviews, vol.257, issue.2, pp.473-482, 2013.
DOI : 10.1016/j.ccr.2012.03.020

L. R. Gahan, S. J. Smith, G. Neves, and . Schenk, Phosphate Ester Hydrolysis: Metal Complexes As Purple Acid Phosphatase and Phosphotriesterase Analogues, European Journal of Inorganic Chemistry, vol.157, issue.19, pp.2745-2758, 2009.
DOI : 10.1021/ci000046b

E. Ghanem, Y. Li, C. Xu, and F. M. , Biochemistry, vol.46, issue.31, pp.9032-9040, 2007.
DOI : 10.1021/bi700561k

F. Meyer, Clues to Dimetallohydrolase Mechanisms from Studies on Pyrazolate-Based Bioinspired Dizinc Complexes ??? Experimental Evidence for a Functional Zn???O2H3???Zn Motif, European Journal of Inorganic Chemistry, vol.43, issue.19, pp.3789-3800, 2006.
DOI : 10.1002/9783527663927

G. Parkin, Synthetic Analogues Relevant to the Structure and Function of Zinc Enzymes, Chemical Reviews, vol.104, issue.2, pp.699-768, 2004.
DOI : 10.1021/cr0206263

N. Sträter, B. Jasper, M. Scholte, B. Krebs, A. P. Duff et al.,

H. C. Averill, J. M. Freeman, and . Guss, Journal of Molecular Biology, vol.351, pp.233-246, 2005.

G. Schenk, L. R. Gahan, L. E. Carrington, N. Miti?, M. Valizadeh et al., Proceedings of the National Academy of Sciences of the United States of America, pp.273-278, 2005.

L. W. Guddat, A. S. Mcalpine, D. Hume, S. Hamilton, J. De-jersey et al., Crystal structure of mammalian purple acid phosphatase, Structure, vol.7, issue.7, pp.757-767, 1999.
DOI : 10.1016/S0969-2126(99)80100-2

Y. Lindqvist, E. Johansson, H. Kaija, P. Vihko, and G. Schneider, Three-dimensional structure of a mammalian purple acid phosphatase at 2.2 ?? resolution with a ??-(hydr)oxo bridged di-iron center, Journal of Molecular Biology, vol.291, issue.1, pp.135-147, 1999.
DOI : 10.1006/jmbi.1999.2962

J. Uppenberg, F. Lindqvist, C. Svensson, B. Ek-rylander, and G. Andersson, Crystal structure of a mammalian purple acid phosphatase 1 1Edited by R. Huber, Journal of Molecular Biology, vol.290, issue.1, pp.201-211, 1999.
DOI : 10.1006/jmbi.1999.2896

T. Klabunde, N. Sträter, R. Fröhlich, H. Witzel, and B. Krebs, Mechanism of Fe(III) ??? Zn(II) Purple Acid Phosphatase Based on Crystal Structures, Journal of Molecular Biology, vol.259, issue.4, pp.737-748, 1996.
DOI : 10.1006/jmbi.1996.0354

N. Strater, T. Klabunde, P. Tucker, H. Witzel, and B. Krebs, Crystal structure of a purple acid phosphatase containing a dinuclear Fe(III)-Zn(II) active site, Science, vol.268, issue.5216, p.1489, 1995.
DOI : 10.1126/science.7770774

G. Schenk, M. L. Korsinczky, D. A. Hume, S. Hamilton, and J. Dejersey, Purple acid phosphatases from bacteria: similarities to mammalian and plant enzymes, Gene, vol.255, issue.2, pp.419-424, 2000.
DOI : 10.1016/S0378-1119(00)00305-X

S. K. Smoukov, L. Quaroni, X. Wang, P. E. Doan, B. M. Hoffman et al., Electron???Nuclear Double Resonance Spectroscopic Evidence for a Hydroxo-Bridge Nucleophile Involved in Catalysis by a Dinuclear Hydrolase, Journal of the American Chemical Society, vol.124, issue.11, pp.2595-2603, 2002.
DOI : 10.1021/ja003169l

B. A. Averill, J. C. Davis, S. Burman, T. Zirino, J. Sanders-loehr et al., Spectroscopic and magnetic studies of the purple acid phosphatase from bovine spleen, Journal of the American Chemical Society, vol.109, issue.12, pp.3760-3767, 1987.
DOI : 10.1021/ja00246a039

B. Das, H. Daver, M. Pyrkosz-bulska, E. Persch, S. K. Barman et al.,

M. Gumienna-kontecka, F. Jarenmark, E. Himo, and . Nordlander, Journal of Inorganic Biochemistry, vol.132, pp.6-17, 2014.

M. M. Benning, J. M. Kuo, F. M. Raushel, and H. M. Holden, Three-Dimensional Structure of Phosphotriesterase: An Enzyme Capable of Detoxifying Organophosphate Nerve Agents, Biochemistry, vol.33, issue.50, pp.15001-15007, 1994.
DOI : 10.1021/bi00254a008

G. Schenk, I. Mateen, T. Ng, M. M. Pedroso, N. Mitic et al., Organophosphate-degrading metallohydrolases: Structure and function of potent catalysts for applications in bioremediation, Coordination Chemistry Reviews, vol.317, pp.122-131, 2016.
DOI : 10.1016/j.ccr.2016.03.006

E. Ghanem and F. M. , Detoxification of organophosphate nerve agents by bacterial phosphotriesterase, Toxicology and Applied Pharmacology, vol.207, issue.2, pp.459-470, 2005.
DOI : 10.1016/j.taap.2005.02.025

A. C. , , p.51

J. K. Grimsley, J. M. Scholtz, C. N. Pace, and J. R. Wild, Biochemistry, vol.36, issue.47, pp.14366-14374, 1997.
DOI : 10.1021/bi971596e

F. M. , Bacterial detoxification of organophosphate nerve agents, Current Opinion in Microbiology, vol.5, issue.3, pp.288-295, 2002.
DOI : 10.1016/S1369-5274(02)00314-4

N. Sethunathan and T. Yoshida, sp. that degrades diazinon and parathion, Canadian Journal of Microbiology, vol.19, issue.7, pp.873-875, 1973.
DOI : 10.1139/m73-138

D. M. Munnecke, Appl. Environ. Microbiol, vol.32, pp.7-13, 1976.

J. J. Brown, L. R. Gahan, A. Schoffler, E. H. Krenske, and G. Schenk, Investigation of the identity of the nucleophile initiating the hydrolysis of phosphate esters catalyzed by dinuclear mimics of metallohydrolases, Journal of Inorganic Biochemistry, vol.162, pp.356-365, 2016.
DOI : 10.1016/j.jinorgbio.2016.02.008

H. Arora, S. K. Barman, F. Lloret, and R. Mukherjee, -nitrophenylphosphate, Inorganic Chemistry, vol.51, issue.10, pp.5539-5553, 2012.
DOI : 10.1021/ic201971t

P. Comba, L. R. Gahan, V. Mereacre, G. R. Hanson, and A. K. Powell,

. Zajaczkowski-fischer, Inorganic Chemistry, vol.51, pp.12195-12209, 2012.

F. Heims, V. Mereacre, A. Ciancetta, S. Mebs, A. K. Powell et al., Eur. J

, Inorg. Chem, vol.2012, issue.4565, pp.4565-45694561, 2012.

S. Albedyhl, D. Schnieders, A. Jancso, T. Gajda, and B. Krebs, Eur. J. Inorg. Chem, pp.1400-1409, 2002.

S. Albedyhl, M. T. Averbuch-pouchot, C. Belle, B. Krebs, J. L. Pierre et al.,

E. Torelli, J. Inorg. Chem, pp.1457-1464, 2001.

M. Ghiladi, C. J. Mckenzie, A. Meier, A. K. Powell, J. Ulstrup et al., Journal of the Chemical Society, pp.4011-4018, 1997.

A. S. Borovik, V. Papaefthymiou, L. F. Taylor, O. P. Anderson, L. Que et al., J. Am. Chem

. Soc, , pp.6183-6195, 1989.

R. M. Buchanan, M. S. Mashuta, K. J. Oberhausen, and J. F. Richardson,

J. Hendrickson, Am. Chem. Soc, vol.111, pp.4497-4498, 1989.

M. Suzuki, H. Oshio, A. Uehara, K. Endo, M. Yanaga et al.,

. Soc and . Jpn, , pp.3907-3913, 1988.

M. Suzuki, H. Kanatomi, and I. Murase, SYNTHESIS AND PROPERTIES OF BINUCLEAR COBALT(II) OXYGEN ADDUCT WITH 2,6-BIS[BIS(2-PYRIDYLMETHYL)AMINOMETHYL]-4-METHYLPHENOL, Chemistry Letters, vol.10, issue.12, pp.1745-1748, 1981.
DOI : 10.1246/cl.1981.1745

S. Bosch, P. Comba, L. R. Gahan, and G. Schenk, Asymmetric mono- and dinuclear Ga III and Zn II complexes as models for purple acid phosphatases, Journal of Inorganic Biochemistry, vol.162, pp.343-355, 2016.
DOI : 10.1016/j.jinorgbio.2015.12.028

P. V. Bernhardt, S. Bosch, P. Comba, L. R. Gahan, G. R. Hanson et al.,

A. K. Noble, G. Powell, and H. Schenk, Inorg. Chem, vol.54, pp.7249-7263, 2015.

A. E. Roberts, G. Schenk, and L. R. Gahan, Binding, European Journal of Inorganic Chemistry, vol.50, issue.19, pp.3076-3086, 2015.
DOI : 10.1002/ejic.201200156

URL : https://hal.archives-ouvertes.fr/hal-00178213

M. Carboni, M. Clemancey, F. Molton, J. Pecaut, C. Lebrun et al., Biologically Relevant Heterodinuclear Iron???Manganese Complexes, Inorganic Chemistry, vol.51, issue.19, pp.10447-10460, 2012.
DOI : 10.1021/ic301725z

URL : https://hal.archives-ouvertes.fr/hal-01069682

F. R. Xavier, A. J. Bortoluzzi, and A. Neves, A Synthetic Pathway for an Unsymmetrical N5O2 Heptadentate Ligand and Its Heterodinuclear Iron(III)Zinc(II) Complex: A Biomimetic Model for the Purple Acid Phosphatases, Chemistry & Biodiversity, vol.65, issue.9, pp.1794-1805, 2012.
DOI : 10.1107/S090744490804362X

E. Lambert, B. Chabut, S. Chardon-noblat, A. Deronzier, G. Chottard et al., Synthesis, Structural, Magnetic, and Redox Properties of Asymmetric Diiron Complexes with a Single Terminally Bound Phenolate Ligand. Relevance to the Purple Acid Phosphatase Enzymes, Journal of the American Chemical Society, vol.119, issue.40, pp.9424-9437, 1997.
DOI : 10.1021/ja970345q

A. Neves, M. Aires-de-brito, V. Drago, K. Griesar, and W. Haase, A new asymmetric N5O2-donor binucleating ligand and its first FeIIFeIII complex as a model for the redox properties of uteroferrin, Inorganica Chimica Acta, vol.237, issue.1-2, pp.131-135, 1995.
DOI : 10.1016/0020-1693(95)04678-3

E. Bernard, W. Moneta, J. Laugier, S. Chardon-noblat, A. Deronzier et al., A Mixed-Valent, Unsymmetrical FeIIFeIII Complex with a Terminal Phenolato Ligand as a Model for the Active Site of Purple Acid Phosphatases, Angewandte Chemie International Edition in English, vol.33, issue.8, pp.887-889, 1994.
DOI : 10.1002/anie.199408871

L. L. Mendes, D. Englert, C. Fernandes, L. R. Gahan, G. Schenk et al., Metallohydrolase biomimetics with catalytic and structural flexibility, Dalton Transactions, vol.12, issue.46, pp.18510-18521, 2016.
DOI : 10.1007/s00775-007-0286-y

S. Bosch, P. Comba, L. R. Gahan, and G. Schenk, Dinuclear Zinc(II) Complexes with Hydrogen Bond Donors as Structural and Functional Phosphatase Models, Inorganic Chemistry, vol.53, issue.17, pp.9036-9051, 2014.
DOI : 10.1021/ic5009945

K. Selmeczi, C. Michel, A. Milet, and I. Gautier-luneau,

A. Schnieders, C. Rompel, and . Belle, Chemistry ? A European Journal, vol.13, pp.9093-9106, 2007.

E. Kinoshita, M. Takahashi, H. Takeda, M. Shiro, and T. Koike, Dalton Transactions, pp.1189-1193, 2004.

B. De-souza, G. L. Kreft, T. Bortolotto, H. Terenzi, A. J. Bortoluzzi et al.,

J. B. Peralta, A. Domingos, and . Neves, Inorganic Chemistry, vol.52, pp.3594-3596, 2013.

S. J. Smith, R. A. Peralta, R. Jovito, A. Horn, A. J. Bortoluzzi et al.,

T. Cavalett, G. Bortolotto, H. Razzera, A. Terenzi, M. J. Neves et al., Inorganic Chemistry, vol.51, pp.2065-2078, 2012.

C. Piovezan, R. Jovito, A. J. Bortoluzzi, H. Terenzi, F. L. Fischer et al.,

G. G. Pich, R. A. Azzolini, L. M. Peralta, A. Rossi, and . Neves, Inorganic Chemistry, vol.49, pp.2580-2582, 2010.

F. R. Xavier, A. Neves, A. Casellato, R. A. Peralta, A. J. Bortoluzzi et al.,

H. Severino, Z. Terenzi, S. Tomkowicz, W. Ostrovsky, A. Haase et al.,

G. Telser, L. R. Schenk, and . Gahan, Inorganic Chemistry, vol.48, pp.7905-7921, 2009.

A. Neves, M. Lanznaster, A. J. Bortoluzzi, R. A. Peralta, A. Casellato et al.,

M. J. Herrald, G. Riley, and . Schenk, Journal of the American Chemical Society, vol.129, pp.7486-7487, 2007.

M. Lanznaster, A. Neves, A. J. Bortoluzzi, V. V. Aires, B. Szpoganicz et al.,

J. M. Severino, S. C. Fuller, L. R. Drew, G. R. Gahan, M. J. Hanson et al., JBIC Journal of Biological Inorganic Chemistry, vol.10, pp.319-332, 2005.

S. C. Batista, A. Neves, A. J. Bortoluzzi, I. Vencato, R. A. Peralta et al.,

H. Aires, P. C. Terenzi, and . Severino, Inorganic Chemistry Communications, vol.6, pp.1161-1165, 2003.

M. Lanznaster, A. Neves, A. J. Bortoluzzi, B. Szpoganicz, and E. Schwingel, Bond as a Structural and Functional Model for the Active Site of Red Kidney Bean Purple Acid Phosphatase, Inorganic Chemistry, vol.41, issue.22, pp.5641-5643, 2002.
DOI : 10.1021/ic025892d

P. Karsten, A. Neves, A. J. Bortoluzzi, M. Lanznaster, and V. Drago, BPBPMP as a Model for the PAP in Sweet Potato, Inorganic Chemistry, vol.41, issue.18, pp.4624-4626, 2002.
DOI : 10.1021/ic025674k

C. Belle, I. Gautier-luneau, L. Karmazin, J. Pierre, S. Albedyhl et al., Eur. J. Inorg. Chem, pp.3087-3090, 2002.

C. Belle, I. Gautier-luneau, G. Gellon, and J. Pierre,

. Aman, Journal of the Chemical Society Dalton Transactions, The Royal Society of Chemistry, pp.3543-3546, 1997.

M. Carboni, M. Clémancey, F. Molton, J. Pécaut, C. Lebrun et al., Biologically Relevant Heterodinuclear Iron???Manganese Complexes, Inorganic Chemistry, vol.51, issue.19, pp.10447-10460, 2012.
DOI : 10.1021/ic301725z

URL : https://hal.archives-ouvertes.fr/hal-01069682

B. Das, H. Daver, A. Singh, R. Singh, M. Haukka et al.,

M. Jarenmark, F. Himo, and E. Nordlander, European Journal of Inorganic Chemistry, vol.2014, pp.2204-2212, 2014.

L. J. Daumann, L. Marty, G. Schenk, and L. R. Gahan, Asymmetric zinc(ii) complexes as functional and structural models for phosphoesterases, Dalton Transactions, vol.43, issue.26, pp.9574-9584, 2013.
DOI : 10.1021/ic035491d

M. Jarenmark, M. Haukka, S. Demeshko, F. Tuczek, L. Zuppiroli et al.,

. Nordlander, Inorganic Chemistry, vol.50, pp.3866-3887, 2011.

M. Jarenmark, E. Csapo, J. Singh, S. Wockel, E. Farkas et al.,

D. Nordlander and . Transactions, , pp.8183-8194, 2010.

M. Jarenmark, H. Carlsson, V. M. Trukhan, M. Haukka, and S. E. ,

V. Fullagar, E. Sundstroem, and . Nordlander, Inorg. Chem. Commun, vol.13, pp.334-337, 2010.

M. Jarenmark, S. Kappen, M. Haukka, and E. Nordlander, Dalton Trans., Royal Society of Chemistry, pp.993-996, 2008.

T. P. Camargo, F. F. Maia, C. Chaves, B. De-souza, and A. J. Bortoluzzi,

H. Bortolotto, E. E. Terenzi, W. Castellano, Z. Haase, R. A. Tomkowicz et al., Journal of Inorganic Biochemistry, vol.146, pp.77-88, 2015.

L. J. Daumann, K. E. Dalle, G. Schenk, R. P. Mcgeary, P. V. Bernhardt et al.,

D. Gahan and . Transactions, , pp.1695-1708, 2012.

J. Martinez-sanchez, R. Bastida, A. Macias, H. Adams, D. E. Fenton et al., , pp.2651-2656, 2010.

R. R. Buchholz, M. E. Etienne, A. Dorgelo, R. E. Mirams, S. J. Smith et al.,

G. B. Hanton, G. Jameson, L. R. Schenk, D. Gahan, and . Transactions, , pp.6045-6054, 2008.

A. Neves, M. A. De-brito, I. Vencato, V. Drago, K. Griesar et al., Complexes as Synthetic Analogues for the Oxidized and Reduced Forms of Purple Acid Phosphatases, Inorganic Chemistry, vol.35, issue.8, pp.2360-2368, 1996.
DOI : 10.1021/ic950456v

A. C. , , p.56

B. Krebs, K. Schepers, B. Bremer, G. Henkel, E. Althaus et al.,

W. Griesar and . Haase, Inorganic Chemistry, vol.33, pp.1907-1914, 1994.

S. Mandal, V. Balamurugan, F. Lloret, and R. Mukherjee, -nitrophenylphosphate, Inorganic Chemistry, vol.48, issue.16, pp.7544-7556, 2009.
DOI : 10.1021/ic8018937

T. Koga, H. Furutachi, T. Nakamura, N. Fukita, M. Ohba et al., Dinuclear Nickel(II) Complexes of Phenol-Based ???End-Off??? Compartmental Ligands and Their Urea Adducts Relevant to the Urease Active Site, Inorganic Chemistry, vol.37, issue.5, pp.989-996, 1998.
DOI : 10.1021/ic971209p

, Dalton Transactions, vol.40, pp.1372-1381, 2011.

V. K. Bhardwaj and A. Singh, Comparative DNA Binding Abilities and Phosphatase-Like Activities of Mono-, Di-, and Trinuclear Ni(II) Complexes: The Influence of Ligand Denticity, Metal???Metal Distance, and Coordinating Solvent/Anion on Kinetics Studies, Inorganic Chemistry, vol.53, issue.19, pp.10731-10742, 2014.
DOI : 10.1021/ic501961d

D. Volkmer, B. Hommerich, K. Griesar, W. Haase, and B. Krebs, Dinuclear Nickel(II) Complexes as Models for the Active Site of Urease, Inorganic Chemistry, vol.35, issue.13, pp.3792-3803, 1996.
DOI : 10.1021/ic951567x

M. K. Panda, M. M. Shaikh, R. J. Butcher, and P. Ghosh, Functional mimics of catechol oxidase by mononuclear copper complexes of sterically demanding [NNO] ligands, Inorganica Chimica Acta, vol.372, issue.1, pp.145-151, 2011.
DOI : 10.1016/j.ica.2011.01.081

M. K. Panda, A. John, M. M. Shaikh, and P. Ghosh, O] Ligand, Inorganic Chemistry, vol.47, issue.24, pp.11847-11856, 2008.
DOI : 10.1021/ic801576f

A. John, M. M. Shaikh, and P. Ghosh, Dalton Trans, pp.2815-2824, 2008.

C. Pathak, S. K. Gupta, M. K. Gangwar, A. P. Prakasham, P. Ghosh et al., , pp.4737-4750, 2017.

M. Ghiladi, K. B. Jensen, J. Jiang, C. J. Mckenzie, S. Morup et al., Journal of the Chemical Society, pp.2675-2681, 1999.

G. G. Bozzo, K. G. Raghothama, and W. C. Plaxton, Structural and kinetic properties of a novel purple acid phosphatase from phosphate-starved tomato (Lycopersicon esculentum) cell cultures, Biochemical Journal, vol.377, issue.2, p.419, 2004.
DOI : 10.1042/bj20030947

A. C. , , p.57

J. B. Vincent, G. L. Olivier-lilley, and B. A. Averill, Proteins containing oxo-bridged dinuclear iron centers: a bioinorganic perspective, Chemical Reviews, vol.90, issue.8, pp.1447-1467, 1990.
DOI : 10.1021/cr00106a004

N. Mitic, C. J. Noble, L. R. Gahan, G. R. Hanson, and G. Schenk, Active Site, Journal of the American Chemical Society, vol.131, issue.23, pp.8173-8179, 2009.
DOI : 10.1021/ja900797u

Y. Yang, J. M. Mccormick, and E. I. Solomon, Circular Dichroism and Magnetic Circular Dichroism Studies of the Mixed-Valence Binuclear Non-Heme Iron Active Site in Uteroferrin and Its Anion Complexes, Journal of the American Chemical Society, vol.119, issue.49, pp.11832-11842, 1997.
DOI : 10.1021/ja971896j

S. S. Massoud, C. C. Ledet, T. Junk, S. Bosch, P. Comba et al.,

R. C. Travnicek, F. A. Fischer, and . Mautner, Dalton Transactions, vol.45, pp.12933-12950, 2016.

A. Greatti, M. Scarpellini, R. A. Peralta, A. Casellato, A. J. Bortoluzzi et al.,

M. Jovito, B. Aires-de-brito, Z. Szpoganicz, M. Tomkowicz, W. Rams et al., Inorg. Chem, vol.47, pp.1107-1119, 2008.

G. B. Deacon and R. J. Phillips, Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination, Coordination Chemistry Reviews, vol.33, issue.3, pp.227-250, 1980.
DOI : 10.1016/S0010-8545(00)80455-5

C. Selleck, D. Clayton, L. R. Gahan, N. Mitic, R. P. Mcgeary et al.,

G. Guddat and . Schenk, Chem. -Eur. J, vol.23, pp.4778-4781, 2017.

N. Straeter, T. Klabunde, P. Tucker, H. Witzel, and B. Krebs, Science Advancement of Science, vol.268, pp.1489-1492, 1995.

M. M. Benning, H. Shim, F. M. Raushel, and H. M. Holden, Biochemistry, vol.40, issue.9, pp.2712-2722, 2001.
DOI : 10.1021/bi002661e

A. S. Borovik, L. Que, V. Papaefthymiou, E. Muenck, L. F. Taylor et al., Heterobimetallic complexes with (.mu.-phenoxo)bis(.mu.-carboxylato) cores, Journal of the American Chemical Society, vol.110, issue.6, pp.1986-1988, 1988.
DOI : 10.1021/ja00214a065

A. C. , , p.58

J. Martínez-sánchez, R. Bastida, A. Macías, H. Adams, D. E. Fenton et al., , pp.2651-2656, 2010.

H. Adams, D. Bradshaw, and D. E. Fenton, Eur. J. Inorg. Chem

, GmbH, pp.535-538, 2002.

M. Arnold, D. A. Brown, O. Deeg, W. Errington, W. Haase et al.,

R. Nimir and . Werner, Inorganic Chemistry, vol.37, pp.2920-2925, 1998.

A. Greatti, M. Scarpellini, R. A. Peralta, A. Casellato, A. J. Bortoluzzi et al.,

M. A. Jovito, B. De-brito, Z. Szpoganicz, M. Tomkowicz, W. Rams et al., Inorganic Chemistry, vol.47, pp.1107-1119, 2008.

H. Carlsson, M. Haukka, A. Bousseksou, J. Latour, and E. Nordlander, Nickel Complexes of Carboxylate-Containing Polydentate Ligands as Models for the Active Site of Urease, Inorganic Chemistry, vol.43, issue.26, pp.8252-8262, 2004.
DOI : 10.1021/ic049048u

N. F. Chilton, R. P. Anderson, L. D. Turner, A. Soncini, and K. S. Murray, -block complexes, Journal of Computational Chemistry, vol.57, issue.13, pp.1164-1175, 2013.
DOI : 10.1039/j19680002086

, The Journal of Chemical Physics, vol.26, pp.1405-1406, 1957.

M. B. Twitchett, G. Schenk, M. A. Aquino, D. T. Yiu, T. Lau et al., Metal-Substituted Derivatives of Pig Purple Acid Phosphatase (Uteroferrin) with Phosphate, Inorganic Chemistry, vol.41, issue.22, pp.5787-5794, 2002.
DOI : 10.1021/ic020037f

S. J. Smith, K. S. Casellato, N. Hadler, M. J. Miti?, A. J. Riley et al.,

G. Szpoganicz, A. Schenk, L. R. Neves, and . Gahan, JBIC Journal of Biological Inorganic Chemistry, vol.12, pp.1207-1220, 2007.

D. E. Ferreira, W. B. De-almeida, A. Neves, and W. R. Rocha, Theoretical investigation of the reaction mechanism for the phosphate diester hydrolysis using an asymmetric dinuclear metal complex as a biomimetic model of the purple acid phosphatase enzyme, Physical Chemistry Chemical Physics, vol.1, issue.46, pp.7039-7046, 2008.
DOI : 10.1016/j.crci.2007.02.015

C. A. Bunton and S. J. Farber, Hydrolysis of bis(2,4-dinitrophenyl) phosphate, The Journal of Organic Chemistry, vol.34, issue.4, pp.767-772, 1969.
DOI : 10.1021/jo01256a001

M. E. Amato, F. P. Ballistreri, A. Pappalardo, D. Sciotto, G. A. Tomaselli et al.,

T. Toscano, , pp.9751-9757, 2007.

L. J. Farrugia, : an update, Journal of Applied Crystallography, vol.45, issue.4, pp.849-854, 2012.
DOI : 10.1107/S0021889812029111

G. M. Sheldrick, Acta Crystallographica Section C Structural Chemistry, vol.44, issue.1, pp.3-8, 2015.
DOI : 10.1107/S0021889811041768