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, Acknowledgements We thank China Scholarship Council for providing financial support to H. L.; CEFIPRA for providing financial support to A. S.; and ANR for providing financial support to X. S. Bibliographical sketch

H. Li-was-born-in and P. R. China, He joined the international master's program " Catalysis, Molecules and Green Chemistry " in the University of Rennes 1 (France) in 2015. He performed his master's research training in Prof. C. Darcel's team in the University of Rennes 1. He currently works towards a PhD degree of ENSCR under the supervision of Dr, Henri Doucet. He received a grant from the China Scholarship Council (CSC) in 2017. His work focuses on the C-H bond functionalization using palladium catalysis

A. Sasmal, Sc degree in Chemistry from University of Calcutta in 2014 He received his M.Sc degree in Chemistry from IIT Madras in 2016, Afterwards, he did International Master in Molecular Catalysis and Green Chemistry from University of Rennes, vol.1

, Now he is a PhD student at University of Rennes 1 (France) under the supervision of Prof. Henri Doucet and Dr

X. Shi-was-born-in and P. R. China, She joined the international master's program " Catalysis, Molecules and Green Chemistry " in the University of Rennes 1 (France) receiving grants from the Foundation Rennes 1 in 2015. She performed her master's research training in H. Doucet's team

, She currently works towards a PhD degree of University of Rennes 1 under the supervision of Dr

H. Doucet and D. , Jean-François Soulé. Her work focuses on the C-H bond functionalization using palladium catalysis

. Jean-françois, Soulé completed his PhD in 2007 working on the Petasis reaction applied on the synthesis of biological interest molecules under the supervision of the Prof

, Gif-sur-Yvette (France) In 2010, he joined the group of the Prof Shu Kobayashi at the University of Tokyo (Japan) as a postdoctoral fellow, Institut de Chimie des Substances Naturelles he was appointed as " Chargé de Recherche " CNRS at the University of Rennes 1 in the group of Dr. Henri Doucet. His main interest focuses on the development of sustainable chemistry, notably, transition-metals catalyzed C-H functionalizations, 2013.

, After post-doctoral appointments at Oxford university (UK) with Prof His research interests include organic synthesis by metal-catalyzed processes, ligands synthesis and green chemistry, Henri Doucet received his PhD in chemistry working withJapan) with Prof. R. Noyori, he moved to the University of Marseille (France) as CNRS researcher in the group of Prof M. Santelli. In 2006 he moved to Rennes 1 University, 1994.