Late stage modifications of P-containing ligands using transition-metal-catalysed C-H bond functionalisation

Zhuan Zhang; Pierre H Dixneuf; Jean-François Soulé

Late stage modifications of P-containing ligands using transition-metal-catalysed C-H bond functionalisation

Zhuan Zhang ¹ Pierre H Dixneuf ¹ Jean-François Soulé ¹

1 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : Phosphorus containing molecules have seen widespread applications in the development of innovative metal-ligand catalysts and materials. In recent years, the implementation of late-stage modifications of phosphorus derivatives via ortho-regioselective C-H bond functionalisation has led to faster and better ways for the synthesis of complex ligands by creating new reactions with low impact on the environment. This Feature article highlights transition-metal catalysed regioselective C-H bond functionalisation of phosphorus-containing molecules, in which the phosphorus containing unit plays the role of a directing group for C-H bond activation and the synthesis of new functional phosphorus derivatives.

Document type :

Journal articles

Domain :

Chemical Sciences

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Late stage modifications of P-containing ligands using transition-metal-catalysed C-H bond functionalisation

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