J. Lutz, M. Ouchi, D. R. Liu, and M. Sawamoto, Sequence-Controlled Polymers, Science, vol.109, issue.23, p.1238149, 2013.
DOI : 10.1073/pnas.1202344109

URL : https://hal.archives-ouvertes.fr/hal-01657091

J. Lutz, Defining the Field of Sequence-Controlled Polymers, Macromol. Rapid Commun, vol.2017, issue.38

J. Lutz, Sequence-Controlled Polymers, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01657091

P. L. Arnold, J. Buffet, R. P. Blaudeck, S. Sujecki, A. J. Blake et al., -Lactide, Angewandte Chemie International Edition, vol.35, issue.32, pp.6033-6036, 2008.
DOI : 10.1002/anie.200801279

C. Bakewell, T. Cao, N. Long, X. F. Le-goff, A. Auffrant et al., -Lactide Polymerization: Excellent Rates and High Iso-Selectivities, Journal of the American Chemical Society, vol.134, issue.51, pp.20577-20580, 2012.
DOI : 10.1021/ja310003v

D. C. Aluthge, B. O. Patrick, and P. Mehrkhodavandi, A highly active and site selective indium catalyst for lactide polymerization Metal-Size Influence in Iso-Selective Lactide Polymerization, Chem. Commun. Angew. Chem. Int. Ed, vol.49, issue.53, pp.4295-4297, 2013.

M. D. Jones, S. L. Hancock, P. Mckeown, P. M. Schäfer, A. Buchard et al.,

, Chem. Commun, vol.50, pp.15967-15970, 2014.

Z. Mou, B. Liu, M. Wang, H. Xie, P. Li et al., Isoselective ring-opening polymerization of rac-lactide initiated by achiral heteroscorpionate zwitterionic zinc complexes, Chemical Communications, vol.123, issue.77, pp.11411-11414, 2014.
DOI : 10.1021/ja003851f

M. D. Jones, L. Brady, P. Mckeown, A. Buchard, P. M. Schäfer et al.,

J. P. Lowe, Metal influence on the iso-and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of rac-Lactide, Chem. Sci. 2015, vol.6, pp.5034-5039

P. Mckeown, M. G. Davidson, G. Kociok-köhn, and M. D. Jones, Aluminium salalens vs. salans: ???Initiator Design??? for the isoselective polymerisation of rac-lactide, Chemical Communications, vol.45, issue.68, pp.10431-10434, 2016.
DOI : 10.1039/C5DT04695E

T. Rosen, Y. Popowski, I. Goldberg, and M. Kol, -Lactide, Chemistry - A European Journal, vol.343, issue.33, pp.11533-11536, 2016.
DOI : 10.1002/1615-4169(20010129)343:1<5::AID-ADSC5>3.0.CO;2-I

T. Xu, G. Yang, C. Liu, and X. Lu, Highly Robust Yttrium Bis(phenolate) Ether Catalysts for Excellent Isoselective Ring-Opening Polymerization of Racemic Lactide, Macromolecules, vol.50, issue.2, pp.515-522, 2017.
DOI : 10.1021/acs.macromol.6b02439

J. Carpentier, Discrete Metal Catalysts for Stereoselective Ring-Opening Polymerization of Chiral Racemic ??-Lactones, Macromolecular Rapid Communications, vol.131, issue.19, pp.1696-1705, 2010.
DOI : 10.1002/marc.201000114

URL : https://hal.archives-ouvertes.fr/hal-00576874

A. Amgoune, C. M. Thomas, S. Ilinca, T. Roisnel, and J. Carpentier, Highly Active, Productive, and Syndiospecific Yttrium Initiators for the Polymerization of Racemic ??-Butyrolactone, Angewandte Chemie International Edition, vol.21, issue.17, pp.2782-2784, 2006.
DOI : 10.1002/anie.200600058

URL : https://hal.archives-ouvertes.fr/hal-00322704

M. Bouyahyi, N. Ajellal, E. Kirillov, C. M. Thomas, and J. Carpentier, Exploring Electronic versus Steric Effects in Stereoselective Ring-Opening Polymerization of Lactide and ??-Butyrolactone with Amino-alkoxy-bis(phenolate)-Yttrium Complexes, Chemistry - A European Journal, vol.32, issue.6, pp.1872-1883, 2011.
DOI : 10.1107/S0021889899006020

URL : https://hal.archives-ouvertes.fr/hal-00632117

J. Carpentier, Rare-Earth Complexes Supported by Tripodal Tetradentate Bis(phenolate) Ligands: A Privileged Class of Catalysts for Ring-Opening Polymerization of Cyclic Esters, Organometallics, vol.34, issue.17, pp.4175-4189, 2015.
DOI : 10.1021/acs.organomet.5b00540

URL : https://hal.archives-ouvertes.fr/hal-01191802

N. Ajellal, M. Bouyahyi, A. Amgoune, C. M. Thomas, A. Bondon et al., Syndiotactic-Enriched Poly(3-hydroxybutyrate)s via Stereoselective Ring-Opening Polymerization of Racemic ??-Butyrolactone with Discrete Yttrium Catalysts, Macromolecules, vol.42, issue.4, pp.987-993, 2009.
DOI : 10.1021/ma8022734

URL : https://hal.archives-ouvertes.fr/hal-00400851

C. G. Jaffredo, Y. Chapurina, S. M. Guillaume, and J. Carpentier, From Syndiotactic Homopolymers to Chemically Tunable Alternating Copolymers: Highly Active Yttrium Complexes for Stereoselective Ring-Opening Polymerization of ??-Malolactonates, Angewandte Chemie International Edition, vol.103, issue.10, pp.2687-2691, 2014.
DOI : 10.1073/pnas.0602765103

URL : https://hal.archives-ouvertes.fr/hal-01123619

C. G. Jaffredo, Y. Chapurina, E. Kirillov, J. Carpentier, and S. M. Guillaume, Highly Stereocontrolled Ring-Opening Polymerization of Racemic Alkyl ??-Malolactonates Mediated by Yttrium [Amino-alkoxy-bis(phenolate)] Complexes, Chemistry - A European Journal, vol.100, issue.22, pp.7629-7641, 2016.
DOI : 10.1063/1.467146

URL : https://hal.archives-ouvertes.fr/hal-01304299

R. Ligny, M. M. Hänninen, S. M. Guillaume, and J. Carpentier, Highly Syndiotactic or Isotactic Polyhydroxyalkanoates by Ligand-Controlled Yttrium-Catalyzed Stereoselective Ring-Opening Polymerization of Functional Racemic ?-Lactones, Angew. Chem. Int. Ed Engl, vol.2017, issue.56, pp.10388-10393
DOI : 10.1002/ange.201704283

URL : https://hal.archives-ouvertes.fr/hal-01579647

B. J. Tiegs, S. Sarkar, A. M. Condo, I. Keresztes, and G. W. Coates, Rapid Determination of Polymer Stereoregularity Using Band-Selective 2D HSQC, ACS Macro Letters, vol.5, issue.2, pp.181-184, 2016.
DOI : 10.1021/acsmacrolett.5b00866

D. G. Davis, Proton detection of long-range couplings to carbon-13 using semiselective pulses. A highresolution method for assigning amino acids in peptides, J. Magn. Reson, vol.83, pp.212-218, 1989.
DOI : 10.1016/0022-2364(89)90308-9

J. J. Led, F. Abildgaard, and H. Gesmar, Phase correction of soft-pulse heteronuclear multiple-bond correlation spectra using backward linear prediction, Journal of Magnetic Resonance (1969), vol.93, issue.3, pp.659-665, 1991.
DOI : 10.1016/0022-2364(91)90097-D

L. Poppe and H. Van-halbeek, 13C-selective,1H-detected 2D {1H,13C} correlation spectra of oligosaccharides, Magnetic Resonance in Chemistry, vol.29, issue.8, pp.848-851, 1991.
DOI : 10.1016/0022-2364(78)90003-3

T. D. Claridge and I. Pérez-victoria, C resolution in semi-selective HMBC: a band-selective, constant-time HMBC for complex organic structure elucidation by NMR, Org. Biomol. Chem., vol.39, issue.21, pp.3632-3634, 2003.
DOI : 10.1016/S0040-4039(98)01574-3

J. M. Bernassau and J. M. Nuzillard, Clean Selective Excitation of Heteronuclear Spin Systems, Journal of Magnetic Resonance, Series A, vol.104, issue.2, pp.212-221, 1993.
DOI : 10.1006/jmra.1993.1212

J. M. Bernassau and J. M. Nuzillard, Enhancement of F1-Selective HMQC and HSQC Experiments by Field-Gradient Pulses, Journal of Magnetic Resonance, Series A, vol.108, issue.2, pp.248-254, 1994.
DOI : 10.1006/jmra.1994.1119

C. Gaillet, C. Lequart, P. Debeire, and J. Nuzillard, Band-Selective HSQC and HMBC Experiments Using Excitation Sculpting and PFGSE, Journal of Magnetic Resonance, vol.139, issue.2, pp.454-459, 1999.
DOI : 10.1006/jmre.1999.1808

J. M. Bernassau and J. M. Nuzillard, Selective HMBC Experiments Using Soft Inversion Pulses, Journal of Magnetic Resonance, Series B, vol.103, issue.1, pp.77-81, 1994.
DOI : 10.1006/jmrb.1994.1011

J. Saurí, M. Reibarkh, T. Zhang, R. D. Cohen, X. Wang et al., C Nuclei, Organic Letters, vol.18, issue.19, pp.4786-4789, 2016.
DOI : 10.1021/acs.orglett.6b02158

X. Wang, B. M. Duggan, and T. Molinski, . Band-Selective Heteronuclear Single Quantum Coherence for Discrimination of Bromo???Chloro Regioisomerism in Natural Products, Journal of the American Chemical Society, vol.137, issue.38, pp.12343-12351, 2015.
DOI : 10.1021/jacs.5b07858

X. Wang, B. M. Duggan, and T. Molinski, C in natural products drug discovery, Magnetic Resonance in Chemistry, vol.59, issue.4, pp.263-268, 2017.
DOI : 10.1246/bcsj.59.2547

D. J. Milanowski, N. Oku, L. K. Cartner, H. R. Bokesch, R. T. Williamson et al., Unequivocal determination of caulamidines A and B: application and validation of new tools in the structure elucidation tool box, Chemical Science, vol.48, issue.2, pp.307-314, 2018.
DOI : 10.4269/ajtmh.1993.48.205

C. Dalvit, Semi-selective two-dimensional homonuclear and heteronuclear NMR experiments recorded with pulsed field gradients, Magnetic Resonance in Chemistry, vol.68, issue.7, pp.570-576, 1995.
DOI : 10.1016/0022-2364(76)90028-7

T. L. Hwang and A. J. Shaka, Water Suppression That Works. Excitation Sculpting Using Arbitrary Wave-Forms and Pulsed-Field Gradients, Journal of Magnetic Resonance, Series A, vol.112, issue.2, pp.275-279, 1995.
DOI : 10.1006/jmra.1995.1047

S. Berger, NMR techniques employing selective radiofrequency pulses in combination with pulsed field gradients, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.30, issue.3-4, pp.137-156, 1997.
DOI : 10.1016/S0079-6565(97)00003-4

K. E. Kövér, K. Fehér, L. Szilágyi, A. Borbás, P. Herczegh et al., 2D NMR spectra of oligosaccharides enhanced by band-selective suppression of unwanted signals, Tetrahedron Letters, vol.41, issue.3, pp.393-396, 2000.
DOI : 10.1016/S0040-4039(99)02068-7

L. Emsley and G. Bodenhausen, Optimization of shaped selective pulses for NMR using a quaternion description of their overall propagators, Journal of Magnetic Resonance (1969), vol.97, issue.1, pp.135-148, 1992.
DOI : 10.1016/0022-2364(92)90242-Y

L. Emsley and G. Bodenhausen, Gaussian pulse cascades: New analytical functions for rectangular selective inversion and in-phase excitation in NMR, Chemical Physics Letters, vol.165, issue.6, pp.469-476, 1990.
DOI : 10.1016/0009-2614(90)87025-M