Crystal packing, high-temperature phase transition, second-order nonlinear optical and biological activities in a hybrid material [(S)-C7H16N2][CuBr4]

Ines Ben Hadj Sadok 1 Fadhel Hajlaoui 1 Hanen Ben Ayed 1 Nasreddine Ennaceur 2 Moncef Nasri 1 Nathalie Audebrand 3 Thierry Bataille 3 Nabil Zouari 1
1 Université de Sfax - University of Sfax
2 Science Faculty of Gafsa, Gafsa University,
3 ISCR - Institut des Sciences Chimiques de Rennes
Abstract : The directed synthesis of non-centrosymmetric copper (II) bromo-complex has been achieved through the use of homochiral organic molecule. Reaction containing (S)-(-)-3-aminoquinuclidine, CuBr2, HBr and H2O were subjected to mild hydrothermal conditions, resulting in the growth of single crystals of [(S)-C7H16N2][CuBr4]. The compound crystallizes in the non polar space group P2(1)2(1)2(1)(No. 19), which exhibits the enantiomorphic crystal class 222 (D-2). In the crystal structure, the tetrabromocuprate(II) anion is connected to three organic cations through N-H center dot center dot center dot Br hydrogen bonds to form cation-anion-cation molecular units, which are held together by means of offset face-to-face interactions to give one-dimensional chains. DSC measurements indicated that the compound [(S)-C7H16N2][CuBr4] underwent a reversible phase transition at 80 degrees C. [(S)-C7H16N2][CuBr4] is more than 1.2 times as efficient as KDP in second harmonic generation; making it a potentially attractive material for non-linear optical applications. The synthesized product was also screened for in vitro antioxidant and antimicrobial activities, while showing favorable antioxidant activities against DPPH as well as the discoloration of beta-carotene. (C) 2018 Elsevier B.V. All rights reserved.
Keywords : Chiral crystal Metal complex Second harmonic generation Phase transition Biological activities
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Journal articles
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01833240
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Submitted on : Monday, July 9, 2018 - 2:51:39 PM
Last modification on : Thursday, March 7, 2019 - 11:37:14 AM

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UNIV-RENNES1 | ISCR | UR1-UFR-SPM | ISCR-CSM | INC-CNRS | UNIV-RENNES | INSA-RENNES | INSA-GROUPE

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Ines Ben Hadj Sadok, Fadhel Hajlaoui, Hanen Ben Ayed, Nasreddine Ennaceur, Moncef Nasri, et al.. Crystal packing, high-temperature phase transition, second-order nonlinear optical and biological activities in a hybrid material [(S)-C7H16N2][CuBr4]. Journal of Molecular Structure, Elsevier, 2018, 1167, pp.316-326. ⟨10.1016/j.molstruc.2018.05.011⟩. ⟨hal-01833240⟩

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