For leading reviews on metal-catalyzed ROP of cyclic esters, see: (a), Dalton Trans, vol.104, pp.6147-6176, 2001. ,
, Chem. Soc. Rev, vol.39, pp.165-173, 2010.
, Top. Organomet. Chem, vol.39, pp.9007-9023, 2010.
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Handbook of RingOpening Polymerization, 2009. ,
, Nature Chem, vol.8, pp.42-49, 2016.
, Science, vol.360, pp.398-403, 2018.
It is commercially prepared from ROP of enantiomerically pure (S,S)-LA. Few catalyst/initiator systems are able to provide isotactic (sometimes stereocomplexed) PLA from ROP of rac-LA; for leading references in that field, see: Aluminum (a), When higher-strength and longer lifetime applications are targeted, crystalline isotactic PLA is the most suitable material, vol.124, pp.4510-4513, 2002. ,
, J. Am. Chem. Soc, vol.124, pp.2688-2689, 2002.
Indium: (a), Proc. Nat. Acad. Sci, vol.103, pp.4295-4297, 2006. ,
, Angew. Chem. Int. Ed, vol.56, pp.5277-5282, 2013.
, Zirconium: a), vol.3, pp.9226-9230, 2008.
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330-331; b) For a recent account, see, Organometallics, vol.34, pp.4175-4189, 2004. ,
, Chem. Eur. J, vol.12, pp.1872-1883, 2006.
,
, Angew. Chem. Int. Ed, vol.45, pp.2782-2784, 2006.
,
, Macromolecules, vol.17, pp.987-993, 2009.
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, 8 Å) involving the phenyl ?system and one methylene C?H have also been observed in the solid state structure of a Al complex bearing a model poly
, OCH
, Organometallics, vol.33, pp.309-321, 2014.
, Organometallics, vol.33, pp.5693-5707, 2014.
3141-3150 and references therein; b), Makromol. Chem., Macromol. Symp, vol.38, pp.305-314, 1986. ,
,
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, Proc. Natl. Acad. Sci. USA, vol.115, pp.16789-16794, 2004.
, Such extra stabilizing interaction between the C=O moiety of the benzyl ester group and the Nd center has been observed in DFT-computed structures related to the syndioselective ROP of MLA Bn promoted by Nd
, Chem. Eur. J, vol.20, pp.13609-13617, 2013.
, Angew. Chem. Int. Ed, vol.56, pp.10388-10393, 2017.