Teaching an old molecule new tricks Evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]

Abstract : We report the luminescence and magnetic properties of the mononuclear Dy(iii) complex [DyTp2Acac] (Tp = tris-pyrazolylborohydride and Acac = 2,4-pentanedionate). This complex displays peculiar slow magnetisation dynamics at low temperature in the absence of a static field, which we managed to interpret using its resolved luminescence spectrum and ab initio calculations.
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Frédéric Guégan, François Riobé, Olivier Maury, Julie Jung, Boris Le Guennic, et al.. Teaching an old molecule new tricks Evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]. Inorganic Chemistry Frontiers, Royal Society of Chemistry, 2018, 5 (6), pp.1346-1353. ⟨10.1039/c8qi00174j⟩. ⟨hal-01835016⟩

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