Ni-2[LnCl(6)] (Ln = Eu-II, Ce-II, Gd-II) the first Ln(II) compounds stabilized in a pure inorganic lattice

Abstract : Here we report the first examples of 3d-4f compounds based on Ln(II) cations. We have obtained a series of Ni-2[LnCl(6)] isostructural compounds where Ln(II) = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm3m space group. Magnetic and optical characterization was also performed on this new class of compounds.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01861416
Contributor : Laurent Jonchère <>
Submitted on : Friday, August 24, 2018 - 2:30:00 PM
Last modification on : Friday, August 23, 2019 - 3:08:14 PM

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Bianca Baldo, Francisco Rubio, Erwin Flores, Andres Vega, Nathalie Audebrand, et al.. Ni-2[LnCl(6)] (Ln = Eu-II, Ce-II, Gd-II) the first Ln(II) compounds stabilized in a pure inorganic lattice. Chemical Communications, Royal Society of Chemistry, 2018, 54 (54), pp.7531-7534. ⟨10.1039/c7cc09921e⟩. ⟨hal-01861416⟩

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