Fluoro- and Chloroferrocene From 2-to 3-Substituted Derivatives

Mehdi Tazi; Madani Hedidi; William Erb; Yury S. Halauko; Oleg A. Ivashkevich; Vadim E. Matulis; Thierry Roisnel; Vincent Dorcet; Ghenia Bentabed-Ababsa; Florence Mongin

doi:10.1021/acs.organomet.8b00384

Journal articles

Fluoro- and Chloroferrocene From 2-to 3-Substituted Derivatives

Mehdi Tazi ¹ Madani Hedidi ^{1, 2} William Erb ¹ Yury S. Halauko ^{3, 4} Oleg A. Ivashkevich ⁴ Vadim E. Matulis ⁴ Thierry Roisnel ¹ Vincent Dorcet ¹ Ghenia Bentabed-Ababsa ⁵ Florence Mongin ¹

1 ISCR - Institut des Sciences Chimiques de Rennes

2 Hassiba Benbouali University of Chlef

3 UNESCO Chair of Belarusian State University

4 Belarusian State University

5 Université d'Oran 1 Ahmed Ben Bella [Oran]

Abstract : The ferrocene halogen "dance" has been deemed hardly controllable. Here, we describe the first efficient examples of this reaction. Conversion of 1-fluoro-2-iodo (or 1-chloro-2-iodo) to 1-fluoro-3-iodo (or 1-chloro-3-iodo) ferrocenes was ensured by suitably protecting the free 5 position.

Document type :

Journal articles

Domain :

Chemical Sciences

Complete list of metadatas

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01861424
Contributor : Laurent Jonchère <>
Submitted on : Friday, August 24, 2018 - 2:30:22 PM
Last modification on : Thursday, March 5, 2020 - 2:07:35 PM

Fluoro- and Chloroferrocene From 2-to 3-Substituted Derivatives

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Fluoro- and Chloroferrocene From 2-to 3-Substituted Derivatives

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