Fluoro- and Chloroferrocene From 2-to 3-Substituted Derivatives

Abstract : The ferrocene halogen "dance" has been deemed hardly controllable. Here, we describe the first efficient examples of this reaction. Conversion of 1-fluoro-2-iodo (or 1-chloro-2-iodo) to 1-fluoro-3-iodo (or 1-chloro-3-iodo) ferrocenes was ensured by suitably protecting the free 5 position.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01861424
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Submitted on : Friday, August 24, 2018 - 2:30:22 PM
Last modification on : Thursday, March 7, 2019 - 3:12:02 PM

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Mehdi Tazi, Madani Hedidi, William Erb, Yury S. Halauko, Oleg A. Ivashkevich, et al.. Fluoro- and Chloroferrocene From 2-to 3-Substituted Derivatives. Organometallics, American Chemical Society, 2018, 37 (14), pp.2207-2211. ⟨10.1021/acs.organomet.8b00384⟩. ⟨hal-01861424⟩

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