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Journal articles
Redox-active Chiroptical Switching in Mono- and Bis-Iron-Ethynyl-Carbo[6]Helicenes Studied by Electronic and Vibrational Circular Dichroism and Resonance Raman Optical Activity
Abstract : Introducing one or two alkynyl-iron moieties onto a carbo[6]helicene results in organometallic helicenes (2 a,b) that display strong chiroptical activity combined with efficient redox-triggered switching. The neutral and oxidized forms have been studied in detail by electronic and vibrational circular dichroism, as well as by Raman optical activity (ROA) spectroscopy. The experimental results were analyzed and spectra were assigned with the help of first-principles calculations. In particular, a recently developed method for ROA calculations under resonance conditions has been used to study the intricate resonance effects on the ROA spectrum of mono-iron ethynylhelicene 2 a.
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01862498
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, September 12, 2018 - 11:15:40 AM
Last modification on : Wednesday, January 13, 2021 - 9:41:30 AM
Long-term archiving on: : Thursday, December 13, 2018 - 1:13:48 PM
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, September 12, 2018 - 11:15:40 AM
Last modification on : Wednesday, January 13, 2021 - 9:41:30 AM
Long-term archiving on: : Thursday, December 13, 2018 - 1:13:48 PM
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Crassous et al_Redox-active Ch...
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