D. B. Walker, G. Joshi, A. P. Davis, C. Mol, M. Boyle et al., Life Sci Chem. Sci. Acc. Chem. Res. Nature Chem. Soc. Rev. Angew. Chem.-Int. Ed. J. Stang, Chem. Rev. J. Am. Chem. Soc. Acc. Chem. Res. Catal. Sci. Technol. Angew. Chem.-Int. Ed. Chem. Rev. J. Hazard. Mater. Acc. Chem. Res. Russ. Chem. Bull. J. Am. Chem. Soc, vol.66, issue.138, pp.3177-3179, 1997.

R. Gramage-doria, D. Armspach, and D. Matt, Metallated cavitands (calixarenes, resorcinarenes, cyclodextrins) with internal coordination sites, Coordination Chemistry Reviews, vol.257, issue.3-4, pp.776-816, 2013.
DOI : 10.1016/j.ccr.2012.10.006

URL : https://hal.archives-ouvertes.fr/hal-01472922

L. Leclercq, A. R. Schmitzer, M. A. Moussawi, M. Haouas, S. Floquet et al., Assembly of Tunable Supramolecular Organometallic Catalysts with Cyclodextrins, Organometallics, vol.29, issue.15, pp.3442-3449, 2010.
DOI : 10.1021/om1006215

M. N. Abramov, S. Sokolov, E. Cordier, H. Monflier, D. Bricout et al., J. Am. Chem. Soc. J. Am. Chem. Soc. Nat. Accepted Manuscript Chemistry -A European Journal FULL PAPER Commun, vol.139, issue.7, pp.12793-12803, 2016.

B. Wang, L. Li, D. Wu, and . Trans, , pp.1388-1392, 2018.

Y. Yue, Y. Wang, L. Yang, and . Wu, Chem. Commun, vol.2014, issue.50, pp.10823-10826

P. A. Abramov, A. A. Ivanov, M. A. Shestopalov, M. A. Moussawi, E. Cadot et al., Supramolecular Adduct of ??-Cyclodextrin and [{Re6Q8}(H2O)6]2+ (Q=S, Se), Journal of Cluster Science, vol.44, issue.1, pp.9-13, 2014.
DOI : 10.1107/S0021889811043202

M. Amela-cortes, A. Garreau, S. Cordier, E. Faulques, J. Duvail et al., Mironov, N. G. Naumov, N. Kitamura, S. Cordier, Z. Anorg, pp.1545-1552, 2014.

A. Chem-e-)-k, P. Kirakci, K. Kubát, J. Fejfarová, M. Martin?ík et al., Inorg. Chem, vol.641, issue.55, pp.1156-1163, 2015.

K. A. Mikhailov, P. A. Brylev, E. Abramov, S. Sakuda, A. Akagi et al., Inorg. Chem. Dalton Trans. 2016 Eur. J. Inorg. Chem, vol.55, issue.2017, pp.8437-8445, 2016.

M. Cheplakova, A. O. Solovieva, T. N. Pozmogova, Y. A. Vorotnikov, K. A. Brylev et al., J. Inorg. Biochem. New J. Chem, vol.2017, issue.41, pp.100-107, 2017.

S. Choi, K. A. Brylev, J. Xu, Y. V. Mironov, V. E. Fedorov et al., J. Inorg. Biochem. Contrast Media Mol. Imaging, vol.102, issue.11, pp.459-466, 1991.

A. A. Krasilnikova, M. A. Shestopalov, K. A. Brylev, I. A. Kirilova, O. P. Khripko et al., Prospects of molybdenum and rhenium octahedral cluster complexes as X-ray contrast agents, Journal of Inorganic Biochemistry, vol.144, issue.13, pp.13-17, 2015.
DOI : 10.1016/j.jinorgbio.2014.12.016

A. Beltrán, M. Mikhailov, M. N. Sokolov, V. Pérez-laguna, A. Rezusta et al., A photobleaching resistant polymer supported hexanuclear molybdenum iodide cluster for photocatalytic oxygenations and photodynamic inactivation of Staphylococcus aureus, Journal of Materials Chemistry B, vol.5, issue.36, pp.5975-5979
DOI : 10.1002/asia.201000284

J. F. Millán-lou, M. Miravet, M. N. Mikhailov, A. Sokolov, F. Rezusta-lópez et al., J. Mater. Chem. B J. Mater. Chem. B, vol.5, issue.4, pp.6058-6064, 2016.

J. Szejtli, Medicinal Applications of Cyclodextrins, Medicinal Research Reviews, vol.16, issue.3, pp.353-386, 1994.
DOI : 10.1002/jccs.198800025

K. I. Assaf, M. S. Ural, F. Pan, T. Georgiev, S. Simova et al., Water Structure Recovery in Chaotropic Anion Recognition: High-Affinity Binding of Dodecaborate Clusters to ??-Cyclodextrin, Angewandte Chemie International Edition, vol.137, issue.23, pp.6852-6856, 2015.
DOI : 10.1021/jacs.5b00187

Y. V. Mironov, J. A. Cody, T. E. Albrecht-schmitt, and J. A. Ibers, = 0???8), Journal of the American Chemical Society, vol.119, issue.3, pp.493-498, 1997.
DOI : 10.1021/ja962264k

A. J. Valente, R. A. Carvalho, and O. Söderman, , pp.6314-6320, 2015.

M. V. Rekharsky and Y. Inoue, Complexation Thermodynamics of Cyclodextrins, Chemical Reviews, vol.98, issue.5, pp.1875-1917, 1998.
DOI : 10.1021/cr970015o

T. Matsue, D. H. Evans, T. Osa, and N. Kobayashi, Electron-transfer reactions associated with host-guest complexation. Oxidation of ferrocenecarboxylic acid in the presence of .beta.-cyclodextrin, Journal of the American Chemical Society, vol.107, issue.12, pp.3411-3417, 1985.
DOI : 10.1021/ja00298a003

W. A. Rabanal-leo?n, J. A. Murillo-lo?pez, D. Páez-hernández, and R. Arratia-pe?rez, Clusters, The Journal of Physical Chemistry A, vol.118, issue.46, pp.11083-11089, 2014.
DOI : 10.1021/jp508892r

T. Yoshimura, S. Ishizaka, Y. Sasaki, H. Kim, N. Kitamura et al., Chemistry Letters, vol.28, issue.10, pp.1121-1122, 1999.
DOI : 10.1246/cl.1999.1121

K. Lang, J. Mosinger, and D. M. Wagnerová, Photophysical properties of porphyrinoid sensitizers non-covalently bound to host molecules; models for photodynamic therapy, Coordination Chemistry Reviews, vol.248, issue.3-4, pp.321-350, 2004.
DOI : 10.1016/j.ccr.2004.02.004

A. O. Solovieva, K. Kirakci, A. A. Ivanov, P. Kubát, T. N. Pozmogova et al., (Q = S, Se, Te), Inorganic Chemistry, vol.56, issue.21, pp.13491-13499, 2017.
DOI : 10.1021/acs.inorgchem.7b02212

H. Imoto, N. G. Naumov, A. V. Virovets, T. Saito, V. E. Federov-b-)-n et al., Naumov, A. V. Virovets, N. V. Podberezskaya, V. E. Federov, pp.720-727, 1997.

M. A. Delsuc and T. E. Malliavin, Maximum Entropy Processing of DOSY NMR Spectra, Analytical Chemistry, vol.70, issue.10, pp.2146-2148, 1998.
DOI : 10.1021/ac9800715

, Oxford Diffraction. CrysAlis CCD and CrysAlis RED, including ABSPACK Versions 1.171, 2006.

G. M. Sheldrick, SADABS, program for scaling and correction of area detector data, 1997.

G. M. Sheldrick and A. Cryst, , pp.3-8, 2015.

O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. Howard, and H. Puschmann, : a complete structure solution, refinement and analysis program, Journal of Applied Crystallography, vol.42, issue.2, pp.339-341, 2009.
DOI : 10.1107/S0021889808042726

A. Manuscript-chemistry-a-european, F. Journal, . Paper, and . Paper, Supramolecular recognition dictated by chaotropic effect. Water-soluble [Re6Q8(CN)6] 4? (Q = S, Se, Te) octahedral clusters react with ?-cyclodextrin producing supramolecular inclusion systems. The nature of the inner Q ligands influences strongly the water structure?breaking character of the clusters, resulting in different host-guest stability. The encapsulation modifies significantly the intrinsic physical-chemical properties of the inorganic guest

A. A. Ivanov, C. Falaise, P. A. Abramov, *. M. Shestopalov, K. Kirakci et al.,

, Host-Guest Binding Hierarchy within Redox-and Luminescence Responsive Supramolecular Self- Assembly Based on Chalcogenide Clusters and ??Cyclodextrin