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Stable lead(II) boroxides

Abstract : The first examples of lead(ii) boroxides, [Pb(OB{CH(SiMe3)2}2)2] (1) and [{N^C}PbOB{CH(SiMe3)2}2] (5; N^C = 2-Me2NCH2C6H4), were prepared via simple protocols. These structurally characterised compounds are stable and, unlike lead(ii) alkoxides and siloxides, do not trigger uncontrolled formation of lead(ii) oxoclusters.
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Submitted on : Monday, September 3, 2018 - 10:06:21 AM
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Adrian-Alexandru Somesan, Erwann Le Coz, Thierry Roisnel, Cristian Silvestru, Yann Sarazin. Stable lead(II) boroxides. Chemical Communications, Royal Society of Chemistry, 2018, 54 (42), pp.5299-5302. ⟨10.1039/c8cc02459f⟩. ⟨hal-01866167⟩



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