Transformations of terpenes and terpenoids via carbon-carbon double bond metathesis

Christian Bruneau 1 Cédric Fischmeister 1 Dalmo Mandelli 2 Wagner A. Carvalho 2 Eduardo N. dos Santos 3 Pierre H. Dixneuf 1 Luciana Sarmento Fernandes 1
1 ISCR - Institut des Sciences Chimiques de Rennes
2 UFABC - Universidade Federal do ABC
3 UFMG - Federal University of Minas Gerais
Abstract : Stimulated by the strong interest in replacing fossil raw materials by renewable feedstocks in chemical industry, alkene metathesis of unsaturated bio-sourced olefins has been recently investigated with the objective of producing high-value molecules using green and atom economic strategies. It is due time to review what has been achieved in this field using terpenes and terpenoids as olefin metathesis partners. These substrates, derived from the isoprene structure, present different types of carbon-carbon double bonds that can be involved in self metathesis, ring closing metathesis, cross metathesis including ethenolysis, and ring opening metathesis. The successful achievements and remaining bottlenecks in this field will be discussed.
Document type :
Journal articles
Complete list of metadatas

Cited literature [50 references]  Display  Hide  Download
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01879772
Contributor : Laurent Jonchère <>
Submitted on : Thursday, September 27, 2018 - 3:01:55 PM
Last modification on : Sunday, December 23, 2018 - 7:06:15 PM
Long-term archiving on : Friday, December 28, 2018 - 5:53:50 PM

File

Bruneau_Transformations of ter...
Files produced by the author(s)

Identifiers

Collections

UNIV-RENNES1 | UNIV-RENNES | UR1-UFR-SPM | INC-CNRS | ISCR-OMC | ISCR | INSA-RENNES | INSA-GROUPE

Citation

Christian Bruneau, Cédric Fischmeister, Dalmo Mandelli, Wagner A. Carvalho, Eduardo N. dos Santos, et al.. Transformations of terpenes and terpenoids via carbon-carbon double bond metathesis. Catalysis Science & Technology, Royal Society of Chemistry, 2018, 8 (16), pp.3989-4004. ⟨10.1039/c8cy01152d⟩. ⟨hal-01879772⟩

Export

BibTeX TEI DC DCterms EndNote

Share

Metrics

Record views

280

Files downloads

72