R. Jin, C. Zeng, M. Zhou, Y. Chen-;-b)-h.-qian, M. Zhu et al., Coord. Chem. Rev, vol.116, pp.9943-9947, 2012.

Y. Liao, M. Liu, S. Chiang, J. Kahlal, C. W. Saillard et al., Angew. Chem. Int. Ed, vol.54, pp.3702-3706, 2015.

. Angew, Y. Chem-;-w.-kurashige, S. Niihori, Y. Sharma, and . Negishi, J. Phys, vol.127, pp.3773-3777, 2015.

). W. Kurashige, S. Yamazoe, M. Accepted-manuscript, K. Communication-yamaguchi, K. Nishodo et al., J. Phys. Chem. Lett, vol.5, pp.2072-2076, 2014.

). S. Wang, X. Meng, A. Das, T. Li, Y. Song et al., Angew. Chem. Int. Ed, vol.53, pp.2376-2380, 2014.

. Angew and . Chem, Angew. Chem. Int. Ed, vol.126, pp.5749-5753, 2014.

. Angew, ;. T. Chem, S. Chen, J. Yang, Y. Chai et al., Adv. 2017, 3, e1700956; d), Coord. Chem. Rev, vol.128, pp.5843-5847, 2016.

). S. Antonello, N. V. Perera, M. Ruzzi, J. A. Gasc?-n, F. Maran et al.,

M. Agrachev, S. Antonello, T. Dainese, M. Ruzzi, A. Zoleo et al., Chem. Soc, vol.135, pp.2607-2617, 2013.

). A. Dass, S. Theivendran, P. R. Nimmala, C. Kumara, V. R. Jupally et al., J. Am. Chem. Soc, vol.137, pp.1289-1296, 2010.

). S. Knoppe and T. Bürgi, Acc. Chem. Res, vol.47, pp.1318-1326, 2014.

S. Dolamic, A. Knoppe, T. Dass, and . Bürgi, Nature Commun, vol.3, p.798, 2012.

). N. Barrabés, B. Zhang, and T. Bürgi, J. Am. Chem. Soc, vol.136, pp.14361-14364, 2014.

M. Zhu, C. M. Aikens, F. J. Hollander, G. C. Schartz, R. Jin et al.,

). H. Qian, W. T. Eckenhoff, Y. Zhu, T. Pintauer, R. D. Jin-;-c)-p et al., J. Am. Chem. Soc, vol.130, pp.1206-1212, 2007.

). Y. Song, S. Wang, J. Zhang, X. Kang, S. Chen et al., J. Am. Chem. Soc, vol.136, pp.1176-1182, 2013.

). A. Desireddy, B. C. Conn, J. Guo, B. Yoon, R. N. Barnett et al., J. Am. Chem. Soc, vol.501, pp.11578-11581, 2013.

M. S. Bootharaju, C. P. Joshi, M. R. Parida, O. F. Mohammed, and O. M. Bakr, Angew. Chem. Int. Ed, vol.55, pp.922-926, 2016.

. Angew, ). J. Chem-;-b, H. Yan, H. Su, S. Yang et al., J. Am. Chem. Soc, vol.128, pp.11880-11883, 2015.

S. Xiong, H. Wang, S. Yu, Y. Jin, T. Song et al., Chem. Eur. J, vol.22, pp.17145-17150, 2016.

Y. Lin, P. V. Kishore, J. Liao, S. Kahlal, Y. Liu et al.,

J. Chiang, C. W. Saillard, and . Liu, Nanoscale, vol.10, pp.6855-6860, 2018.

). L. Abdulhalim, M. S. Bootharaju, Q. Tang, S. D. Gobbo, R. G. Abdulhalim et al., J. Am. Chem. Soc, vol.137, pp.1618-1624, 2015.

W. Chang, P. Lee, J. Liao, K. K. Chakrahari, S. Kahlal et al.,

M. Liu, J. Chiang, C. W. Saillard, and . Liu, Angew. Chem. Int. Ed, vol.56, pp.10178-10182, 2017.

. Angew and . Chem, , vol.129, pp.10312-10316, 2017.

M. Walter, J. Akola, O. Lopez-acevedo, P. D. Jadzinsky, G. Calero et al., Proc. Natl

. Acad, . Sci, and . Usa, , vol.10, pp.9157-9162, 2008.

M. S. Bootharaju, L. Sinatra, O. M. Bakr-;-b, ). X. Kang, S. Chen et al., Nanoscale, vol.8, pp.1-6, 2016.

, 8561(14) Å , ?=?=?=90 o , V=35469(5) Å 3 , Z=8, ? calcd=2.275 g.cm-3 , µ=8.067 mm-1 , Goodness-of-fit=1.067, R1=0.0829, wR2=0.2064, 19725 independent reflections, Crystallographic data of [AuAg20]: C72H168Ag20AuClO24P12Se24, cubic, P213, a=b=c=32

, ) Å 3 , Z=8, ? calcd =2.426 g.cm-3 , µ=9.840 mm-1 , Goodness-of-fit=1.147, R1=0.0576, wR2=0.1412, 10064 independent reflections, C72H168Ag18Au3ClO24P12Se24, cubic, I23, a=b=c=32.4718(16) Å , ?=?= ?=90 o , V=28523, vol.7

T. Dft, calculations were carried out at the BP86/Def2-TZVP and CAM-B3LYP/Def2-TZVP level, respectively (see the computational details in the SI)

Q. Li, K. J. Lambright, M. G. Taylor, K. Kirschbaum, T. Luo et al.,

. Chem, ;. Q. Soc, S. Li, K. Wang, K. J. Kirschbaum et al., Chem. Commun, vol.139, pp.5194-5197, 2016.

M. Zhu, P. Wang, N. Yan, X. Chai, L. He et al., Angew. Chem. Int. Ed, vol.57, pp.4500-4504, 2018.

. Angew and . Chem, , vol.130, pp.4590-4594, 2018.