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Journal articles
Stereoretentive Olefin Metathesis Made Easy: In Situ Generation of Highly Selective Ruthenium Catalysts from Commercial Starting Materials
Abstract : The in situ preparation of highly stereoretentive ruthenium-based metathesis catalysts is reported. This approach completely avoids the isolation of intermediates and air-sensitive catalysts, thus allowing for the rapid access and evaluation of numerous dithiolate Ru catalysts. A procedure was established to perform cross-metathesis reactions without the use of a glovebox, and on a small scale even Schlenk techniques are not required. Consequently, the chemistry displayed in this report is available to every practicing organic chemist and presents a powerful approach for the identification of new stereoretentive catalysts.
Cited literature [10 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01903312
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, November 13, 2018 - 11:37:37 AM
Last modification on : Thursday, March 5, 2020 - 2:08:42 PM
Document(s) archivé(s) le : Thursday, February 14, 2019 - 1:40:45 PM
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, November 13, 2018 - 11:37:37 AM
Last modification on : Thursday, March 5, 2020 - 2:08:42 PM
Document(s) archivé(s) le : Thursday, February 14, 2019 - 1:40:45 PM
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