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Stereoretentive Olefin Metathesis Made Easy: In Situ Generation of Highly Selective Ruthenium Catalysts from Commercial Starting Materials

Abstract : The in situ preparation of highly stereoretentive ruthenium-based metathesis catalysts is reported. This approach completely avoids the isolation of intermediates and air-sensitive catalysts, thus allowing for the rapid access and evaluation of numerous dithiolate Ru catalysts. A procedure was established to perform cross-metathesis reactions without the use of a glovebox, and on a small scale even Schlenk techniques are not required. Consequently, the chemistry displayed in this report is available to every practicing organic chemist and presents a powerful approach for the identification of new stereoretentive catalysts.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01903312
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Submitted on : Tuesday, November 13, 2018 - 11:37:37 AM
Last modification on : Friday, July 10, 2020 - 4:24:31 PM
Long-term archiving on: : Thursday, February 14, 2019 - 1:40:45 PM

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Daniel S Müller, Idriss Curbet, Yann Raoul, Jérôme Le Nôtre, Olivier Baslé, et al.. Stereoretentive Olefin Metathesis Made Easy: In Situ Generation of Highly Selective Ruthenium Catalysts from Commercial Starting Materials. Organic Letters, American Chemical Society, 2018, 20 (21), pp.6822-6826. ⟨10.1021/acs.orglett.8b02943⟩. ⟨hal-01903312⟩

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