R. Noyori, N. Chem-;-b, ). K. Sanderson-;-r, and . Sheldon, Chem. Soc. Rev, vol.1, pp.1437-1451, 2009.

G. Rothenberg and ;. Beller, Catalysis: Concepts and Green Applications, vol.40, pp.4891-4892, 2008.

). J. Hartwig, Organotransition Metal Chemistry: From Bonding to

). A. De-meijere, S. Braese, and M. Oestreich, Metal-Catalyzed Cross-Coupling Reactions and More, 2009.

P. W. Van-leeuwen, Homogeneous Catalysis: Understanding the Art, Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis, 2004.

). J. Stambuli, J. F. Hartwig, ;. Cennari, and U. Piarulli, Curr. Opin. Chem. Biol, vol.7, pp.3071-3100, 2003.

T. Reetz, Angew. Chem. Int. Ed, vol.47, pp.2556-2588, 2008.

. Angew, . W. Chem-;-d)-d, J. F. Robbins, and . Hartwig, Science, vol.120, pp.1423-1427, 2008.

M. S. Sigman, K. C. Harper, E. N. Bess, A. Milo-;-b, ). S. Raugei et al., Acc. Chem. Res, vol.49, pp.248-255, 2015.

P. W. Van-leeuwen, S. Catalysis, -. Wiley, ;. M. Weinheim, P. Raynal et al., Chem. Soc. Rev, vol.43, pp.413-424, 2008.

C. J. Brown, F. D. Toste, R. G. Bergman, and K. N. Raymond, Chem. Soc. Rev, vol.115, pp.433-448, 2015.

). P. Dydio, J. N. Reek-;-b)-h, R. J. Davis, and . Phipps, Chem. Sci, vol.5, pp.637-646, 2014.

). B. Breit and W. Seiche, Pure Appl. Chem, vol.78, pp.615-621, 2006.

). A. Lifschitz, M. S. Rosen, C. M. Mcguirk, C. A. Mirkin, J. Am et al.,

). V. Soc-;-b, D. A. Blanco, V. Leigh, and . Marcos, c) M. Schmittel, vol.137, pp.14956-14968, 2015.

E. Lindback, S. Dawaigher, and K. Warnmark, Chem. Eur. J, vol.20, pp.13432-13481, 2014.

). A. Kirby, Angew. Chem. Int. Ed, vol.35, pp.707-724, 1996.

. Angew, . J. Chem-;-b)-a, F. Kirby, and . Hollender, From Enzyme Models to Model Enzymes, vol.108, pp.770-790, 1996.

. Int and . Ed, , vol.53, pp.11420-11428, 2014.

. Angew and . Chem, , vol.126, pp.11604-11612, 2014.

H. K. Coolen, J. A. Meeuwis, P. W. Van-leeuwen, and R. J. Nolte, J. Am. Chem. Soc, vol.117, pp.11906-11913, 1995.

). K. Kadish, K. M. Smith, and R. Guillard, Handbook of Porphyrin Science, vol.1, issue.44, pp.1659-1713, 2009.

). S. Yamaguchi, T. Katoh, H. Shinokubo, A. Osuka-;-b, ). H. Yorimitsu et al., Asian J. Org. Chem, vol.129, pp.5033-5043, 2007.

D. Leow, G. Li, T. Mei, J. Yu-;-b, ). L. Wan et al., J. Am. Chem. Soc, vol.486, pp.18056-18059, 2012.

M. Tang, J. Movassaghi, J. Yu, ). Am, G. Yang et al., J. Am. Chem. Soc, vol.136, pp.215-220, 2014.

M. Bera, A. Modak, T. Patra, A. Maji, and D. Maiti, Angew. Chem. Int. Ed, vol.16, pp.8515-8519, 2014.

. Angew, ). Y. Chem-;-i, J. Deng, and . Yu, Angew. Chem. Int. Ed, vol.127, pp.902-905, 2015.

. Soc-;-k)-t, S. Patra, R. Bag, A. Kancherla, A. Mondal et al., , vol.137, pp.11888-11891, 2015.

, Chem. Int. Ed, vol.55, pp.7751-7755, 2016.

. Angew, ;. Chem, S. K. Bera, D. Sahoo, and . Maiti, , vol.128, pp.3575-3579, 2016.

A. Modak, A. Mondal, R. Watile, S. Mukherjee, D. Maiti et al., Angew. Chem. Int. Ed, vol.52, pp.14903-14907, 2016.

. Angew, ;. Chem, T. G. Fang, B. L. Saint-denis, S. Taylor et al., J. Am. Chem. Soc, vol.129, pp.10702-10714, 2017.

K. Zhang, J. Tanaka, ). A. Yu-;-q, T. Modak, R. Patra et al., Organometallics, vol.543, pp.3434-3438, 2017.

M. Marty, Z. Clyde-watson, L. J. Twyman, M. Naksh, and J. K. Sanders, J. Am. Chem. Soc, vol.122, pp.5286-5293, 1998.

M. Saito, Y. Nishibayashi, and S. Uemura, Organometallics, vol.23, pp.4012-4017, 2004.

). K. Hatano, K. Kawasaki, S. Munakata, and Y. Iitaka, Bull. Chem. Soc. Jpn, vol.60, pp.1-28, 1985.

, 1843364 (for L2) and 1843365 (for [L2?P5]) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre

M. Morisue, T. Morita, Y. S. Kuroda-;-b)-j, A. M. Summers, . H. Stolzenberg-;-c et al., Org. Biomol. Chem, vol.8, pp.175-182, 1969.

S. J. Webb and J. K. Sanders, Inorg. Chem, vol.39, pp.5912-5919, 2000.

J. Cremers, S. Richert, D. V. Kondratuk, T. D. Claridge, C. R. Timmel et al., Chem. Sci, vol.7, pp.6961-6968, 2016.

R. Cacciapaglia, S. D. Stefano, and L. Mandolini, Acc. Chem. Res, vol.37, pp.113-122, 2004.

). K. Inada, N. Miyaura, ;. Feuerstein, H. Doucet, and M. Santelli, Bull. Chem. Soc. Jpn, vol.56, pp.2141-2149, 1986.

G. K. Anderson, M. Lin, . Inorg, and . Synth, Inorg. Chem, vol.28, pp.4555-4559, 1990.

C. Bianchini, A. Meli, W. I. Oberhauser-;-b)-v, J. F. Bakhmutov, F. A. Berry et al., Organometallics, vol.22, pp.1989-1992, 2003.

D. H. Barton, P. Langlois, T. Okano, N. V. Ozbalik-;-b)-e, V. V. Evdokimova et al., Angew. Chem. Int. Ed, vol.31, pp.9602-9606, 1990.

. Angew,

;. N. Chem, M. C. Yue, R. J. Jennings, and . Puddephatt, Polyhedron, vol.123, pp.67-73, 2011.

N. Kudo, M. Perseghini, and G. C. Fu, Angew. Chem. Int. Ed, vol.45, pp.1282-1284, 2006.

. Angew, ). K. Chem-;-b, S. L. Billingsley, ). S. Buchwald-;-c, J. F. Ge et al., Angew. Chem. Int. Ed, vol.118, pp.12837-12841, 2006.

. Angew and . Chem, , vol.124, pp.13009-13013, 2012.

K. Yamanishi, M. Miyazawa, T. Yairi, S. Sakai, N. Nishina et al., Angew. Chem. Int. Ed, vol.50, pp.6583-6586, 2011.

. Angew,

. Chem, , vol.123, pp.6713-6716, 2011.

L. Leondiadis and M. Momenteau, J. Org. Chem, vol.54, pp.6135-6138, 1989.