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Journal articles
α-β Unsaturated Acylsilanes as Surrogates of Acrolein for Morita-Baylis-Hillman Reactions
Abstract : α‐β‐unsaturated acylsilanes are excellent substrates for Morita–Baylis–Hillman (MBH) reactions, affording the expected adducts in good to excellent yields. In these derivatives, as well as the corresponding acetates, the acylsilanes can be smoothly transformed into aldehydes by irradiation at 365 nm in acetone or THF/water mixtures. Therefore α‐β unsaturated acylsilanes are very useful surrogates for acrolein in MBH reactions, allowing easy preparation of simple and highly functionalized new building blocks for synthetic applications.
Cited literature [34 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01944076
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, December 4, 2018 - 1:58:42 PM
Last modification on : Thursday, January 16, 2020 - 3:34:01 PM
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, December 4, 2018 - 1:58:42 PM
Last modification on : Thursday, January 16, 2020 - 3:34:01 PM
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