A tutorial review of stereoretentive olefin metathesis based on ruthenium dithiolate catalysts

Daniel S. Mueller 1 Olivier Baslé 1 Marc Mauduit 1
1 ISCR - Institut des Sciences Chimiques de Rennes
Abstract : Stereoretentive olefin metathesis based on ruthenium dithiolate complexes has become a very active field of research within the past years. This unique catalyst class is able to kinetically produce both Z-and E-alkenes in high stereochemical purity (typically >95 5) starting from stereochemically pure Z-or E-alkenes. The aim of this tutorial review is to organize the reported information concerning ruthenium dithiolate catalysts in a logic manner, thus providing an "operators handbook" for chemists who wish to apply this methodology in synthesis.
Keywords : stereoretentive ruthenium olefin metathesis catalysis
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Daniel S. Mueller, Olivier Baslé, Marc Mauduit. A tutorial review of stereoretentive olefin metathesis based on ruthenium dithiolate catalysts. Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2018, 14, pp.2999-3010. ⟨10.3762/bjoc.14.279⟩. ⟨hal-01997968⟩

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