Twofold Ferrocene C-H Lithiations For One-Step Difunctionalizations

Abstract : For some aromatics, a twofold C-H deprotolithiation can be achieved, allowing these compounds to be subsequently difunctionalized in one step. This short review brings together examples in which ferrocenes are converted in this way. 1 Introduction 2 Bare Ferrocene 3 Ferrocenes Substituted by Alkyl or Silyl Groups 4 Ferrocenes Substituted by Aminoalkyls 5 Ferrocenes Substituted by Halogens or Oxygen-Based Groups 6 Ferrocenes Substituted by Alkoxyalkyls or Acetals 7 Ferrocenes Substituted by Sulfoxides 8 Ferrocenes Substituted by Oxazolines 9 Ferrocenes Substituted by Carboxamides 10 Conclusion
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Submitted on : Tuesday, January 29, 2019 - 12:52:38 PM
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William Erb, Florence Mongin. Twofold Ferrocene C-H Lithiations For One-Step Difunctionalizations. SYNTHESIS, Georg Thieme Verlag, 2019, 51 (1), pp.146-160. ⟨10.1055/s-0037-1610396⟩. ⟨hal-01997977⟩



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