R. Chevrel, M. Sergent, and J. Prigent, Sur de Nouvelles Phases Sulfurées Ternaires Du Molybdène, J. Solid State Chem, vol.1971, issue.4, pp.515-519
DOI : 10.1016/0022-4596(71)90095-8

R. Schöllhorn, M. Kümpers, A. Lerf, E. Umlauf, and W. Schmidt, Structure and Superconductivity of Ternary Chalcogenides Cu x Mo 6 S 8 Prepared by Topotactic Electrode Reactions, Mater. Res. Bull, vol.14, issue.8, pp.1039-1047, 1979.

R. Schöllhorn, Reversible Topotactic Redox Reactions of Solids by Electron/Ion Transfer, Angew. Chem. Int. Ed. Engl, vol.19, issue.12, pp.983-1003, 1980.

D. Aurbach, Z. Lu, A. Schechter, Y. Gofer, H. Gizbar et al., Prototype Systems for Rechargeable Magnesium Batteries, Nature, vol.407, issue.6805, pp.724-727, 2000.
DOI : 10.1038/35037553

S. Seghir, C. Boulanger, S. Diliberto, J. Lecuire, M. Potel et al., Electrochemical Reactions of Reversible Intercalation in Chevrel Compounds for Cationic Transfer -Principle and Application on Co 2+ Ion, Electrochem. Commun, vol.10, issue.10, pp.1505-1508, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00401925

S. Seghir, C. Boulanger, S. Diliberto, M. Potel, and J. Lecuire, Selective Transfer of Cations between Two Electrolytes Using the Intercalation Properties of Chevrel Phases, Electrochimica Acta, vol.55, issue.3, pp.1097-1106, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00825769

E. Levi, G. Gershinsky, D. Aurbach, O. Isnard, and G. Ceder, New Insight on the Unusually High Ionic Mobility in Chevrel Phases, Chem. Mater, vol.21, issue.7, pp.1390-1399, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00988688

C. Boulanger and J. M. Lecuire, Molybdenum Cluster Chalcogenide Electrochemistry-3. Study of Cadmium Insertion into the Host-Lattices Mo y X Z, Electrochimica Acta, vol.33, issue.11, pp.1573-1579, 1988.
DOI : 10.1016/0013-4686(88)80227-5

Z. Kaidi, C. Boulanger, J. M. Lecuire, N. Lemée, M. Guilloux-viry et al., Ternary Molybdenum Cluster Sulfides: Electrochemical and Chemical Behavior of in Situ Pulsed Laser Deposited Thin Films, Solid State Sci, vol.1999, issue.7, pp.623-635

S. Boursicot, V. Bouquet, A. Bombard, M. Langer, C. Boulanger et al., Electrochemical Behaviour of Cu x Mo 6 S 8 Thin Films Synthesized by CSD, Electrochimica Acta, vol.257, pp.436-443, 2017.

M. Smeu, M. S. Hossain, Z. Wang, V. Timoshevskii, K. H. Bevan et al., Theoretical Investigation of Chevrel Phase Materials for Cathodes Accommodating Ca 2+ Ions, J. Power Sources, vol.306, pp.431-436, 2016.

L. Mei, J. Xu, Z. Wei, H. Liu, Y. Li et al., Chevrel Phase Mo 6 T 8 (T = S, Se) as Electrodes for Advanced Energy Storage, vol.13, p.1701441, 2017.

S. Hebié, F. Alloin, C. Iojoiu, R. Berthelot, and J. Leprêtre, Magnesium Anthracene SystemBased Electrolyte as a Promoter of High Electrochemical Performance Rechargeable Magnesium Batteries, ACS Appl. Mater. Interfaces, vol.10, issue.6, pp.5527-5533, 2018.

F. Murgia, P. Antitomaso, L. Stievano, L. Monconduit, and R. Berthelot, Express and Low-Cost Microwave Synthesis of the Ternary Chevrel Phase Cu 2 Mo 6 S 8 for Application in Rechargeable Magnesium Batteries, J. Solid State Chem, vol.242, pp.151-154, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01350635

E. Guyot, S. Seghir, S. Diliberto, J. Lecuire, and C. Boulanger, Lithium Recovery by Electrochemical Transfer Junction Based on Intercalation Host Matrix, Electrochem. Commun, vol.23, pp.29-32, 2012.

C. Boulanger, S. Seghir, N. Leclerc, S. Diliberto, and J. Lecuire, Method and Device for Selective Cation Extraction by Electrochemical Transfer in Solution and Applications of Said Method, vol.8449747, 2013.

J. Li, A. J. Baker, Z. Ye, H. Wang, and W. Shu, Phytoextraction of CdContaminated Soils: Current Status and Future Challenges, Crit. Rev. Environ. Sci. Technol, vol.2012, issue.20, pp.2113-2152

M. J. Mclaughlin, D. R. Parker, and J. M. Clarke, Metals and Micronutrients -Food Safety Issues, Field Crops Res, vol.60, issue.1, pp.143-163, 1999.

K. Smeets, J. Ruytinx, B. Semane, F. Van-belleghem, T. Remans et al., Cadmium-Induced Transcriptional and Enzymatic Alterations Related to Oxidative Stress, Environ. Exp. Bot, vol.63, issue.1, pp.1-8, 2008.

K. Sasaki, N. Yongvongsoontorn, K. Tawarada, Y. Ohnishi, T. Arakane et al., Cadmium Purification and Quantification Using Immunochromatography, J. Agric. Food Chem, vol.57, issue.11, pp.4514-4519, 2009.
DOI : 10.1021/jf900155t

F. Woodard and I. Woodard-&-curran, Industrial Waste Treatment Handbook

/. Elsevier and . Butterworth-heinemann,

, Boston, 2006.

C. Boulanger and J. M. Lecuire, Molybdenum Cluster Chalcogenide Electrochemistry-2. Determination of the Insertion System Normal Potentials from the Analysis of the i = f(E) Curves in the Potentiodynamic Way, Electrochimica Acta, vol.33, issue.11, pp.1567-1571, 1988.
DOI : 10.1016/0013-4686(88)80227-5

E. Gocke, W. Schramm, P. Dolscheid, and R. Schöllhorn, Molybdenum Cluster Chalcogenides Mo 6 X 8 : Electrochemical Intercalation of Closed Shell Ions Zn 2+ , Cd 2+ , and Na, J. Solid State Chem, vol.70, issue.1, pp.71-81, 1987.

J. M. Tarascon, G. W. Hull, P. Marsh, and T. Haar, and y = 0 to 2), Structural, and Physical Properties of the Sodium Chevrel Phases, vol.66, pp.204-224, 1987.

M. S. Chae, J. W. Heo, S. Lim, and S. Hong, Electrochemical Zinc-Ion Intercalation Properties and Crystal Structures of ZnMo 6 S 8 and Zn 2 Mo 6 S 8 Chevrel Phases in Aqueous Electrolytes, Inorg. Chem, issue.7, pp.3294-3301, 2016.

B. Lee, H. R. Lee, T. Yim, J. H. Kim, J. G. Lee et al.,

, Chevrel Phase. J. Electrochem. Soc, vol.163, issue.6, pp.1070-1076, 2016.

C. Fischer, E. Gocke, U. Stege, and R. Schöllhorn, Molybdenum Cluster Chalcogenides: In Situ XRay Studies on the Formation of Cu x Mo 6 S 8 via Electron/Ion Transfer, J. Solid State Chem, vol.102, issue.1, pp.54-68, 1993.

E. Levi, G. Gershinsky, D. Aurbach, O. Isnard, . Cd et al., Crystallography of Chevrel Phases, Inorg. Chem, vol.6, issue.18, pp.8751-8758, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00988696

J. Hodeau, P. Bordet, M. Anne, A. Prat, A. N. Fitch et al., Nine-Crystal Multianalyzer Stage for High-Resolution Powder Diffraction between 6 KeV and 40 KeV, 1998.
DOI : 10.1117/12.332525

J. Rodríguez-carvajal, Recent Advances in Magnetic Structure Determination by Neutron Powder Diffraction, Phys. B Condens. Matter, vol.192, issue.1-2, pp.55-69, 1993.

V. Pet?í?ek, M. Du?ek, and L. Palatinus, Crystallographic Computing System JANA2006: General Features, Z. Für Krist. -Cryst. Mater, vol.229, issue.5, pp.345-352, 2014.

K. Momma, T. Ikeda, A. A. Belik, F. Izumi, and . Dysnomia, Computer Program for MaximumEntropy Method (MEM) Analysis and Its Performance in the MEM-Based Pattern Fitting, Powder Diffr, vol.28, issue.3, pp.184-193, 2013.

K. Momma and F. Izumi, VESTA 3 for Three-Dimensional Visualization of Crystal, Volumetric and Morphology Data, J. Appl. Crystallogr, vol.44, issue.6, pp.1272-1276, 2011.

B. Cordero, V. Gómez, A. E. Platero-prats, M. Revés, J. Echeverría et al., Covalent Radii Revisited. Dalton Trans, issue.21, 2008.

S. Belin, R. Chevrel, and M. Sergent, Single Crystal Structural Investigations on Ni y Mo 6 Se 8?x S x Solid Solution: A New Location of Nickel Counterions, J. Solid State Chem, vol.155, issue.1, pp.250-258, 2000.

C. Boulanger and J. M. Lecuire, Molybdenum Cluster Chalcogenide Electrochemistry-1. Potentiodynamic Study of Topotactic Insertion Reactions, Electrochimica Acta, vol.33, issue.11, pp.1561-1565, 1988.

E. Levi, Y. Gofer, Y. Vestfreed, E. Lancry, and D. Aurbach, Cu 2 Mo 6 S 8 Chevrel Phase, A Promising Cathode Material for New Rechargeable Mg Batteries: A Mechanically Induced Chemical Reaction, Chem. Mater, vol.14, issue.6, pp.2767-2773, 2002.

M. B. Armand, Intercalation Electrodes. In Materials for Advanced Batteries

D. W. Murphy, J. Broadhead, and B. Steele, NATO Conference Series, pp.145-161, 1980.

, Superconductivity in Ternary Compounds II

M. B. Maple and Ø. Fischer, Topics in Current Physics

H. Springer-berlin, , vol.34, 1982.

S. Kumazawa, Y. Kubota, M. Takata, M. Sakata, and Y. Ishibashi, MEED: A Program Package for Electron-Density-Distribution Calculation by the Maximum-Entropy Method, J. Appl. Crystallogr, vol.26, issue.3, pp.453-457, 1993.

E. Levi, A. Mitelman, O. Isnard, M. Brunelli, and D. Aurbach, 3. The Crystal Structure of Triclinic Mg 2 Mo 6 Se 8, Inorg. Chem, issue.6, pp.1975-1983, 2008.
URL : https://hal.archives-ouvertes.fr/hal-01892651

S. Adams, Practical Considerations in Determining Bond Valence Parameters, Bond Valences

I. D. Brown and K. R. Poeppelmeier, , 2013.

E. Levi, D. Aurbach, and O. Isnard, Bond-Valence Model for Metal Cluster Compounds. I. Common Lattice Strains, Acta Crystallogr. Sect. B Struct. Sci. Cryst. Eng. Mater, vol.69, issue.5, pp.419-425, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00989331