Synthesis of Quinolines Through Acceptorless Dehydrogenative Coupling Catalyzed by Rhenium PN(H)P Complexes

Abstract : A practical and sustainable synthesis of substituted quinolines was achieved through the annulation of 2-aminobenzyl alcohol with various secondary alcohols, ketones, aldehydes, or nitriles, under hydrogen-borrowing conditions. Under the catalysis of well-defined rhenium complexes bearing tridentate diphosphinoamino ligands, the reaction proceeded efficiently (31 examples were isolated with yields up to 96 %) affording a variety of quinoline derivatives.
Document type :
Journal articles
Complete list of metadatas

Cited literature [34 references]  Display  Hide  Download

https://hal-univ-rennes1.archives-ouvertes.fr/hal-02019486
Contributor : Laurent Jonchère <>
Submitted on : Monday, March 4, 2019 - 3:26:50 PM
Last modification on : Friday, June 14, 2019 - 6:31:23 PM
Long-term archiving on : Wednesday, June 5, 2019 - 3:22:32 PM

File

Wei et al_Synthesis of quinoli...
Files produced by the author(s)

Identifiers

Citation

Duo Wei, Vincent Dorcet, Christophe Darcel, Jean-Baptiste Sortais. Synthesis of Quinolines Through Acceptorless Dehydrogenative Coupling Catalyzed by Rhenium PN(H)P Complexes. ChemSusChem, ChemPubSoc Europe/Wiley, In press, ⟨10.1002/cssc.201802636⟩. ⟨hal-02019486⟩

Share

Metrics

Record views

33

Files downloads

15