Accurate wavenumber measurements for the S-0(0), S-0(1), and S-0(2) pure rotational Raman lines of D-2

Abstract : We present accurate measurements for the wavenumbers of the S-0(0), S-0(1), and S-0(2) pure rotational Raman lines in D-2. Our measurements improve the accuracy of the previously available experimental data by an order of magnitude. They also show complete agreement with the state-of-the-art ab initio calculations of the D-2 rotational splitting, which include both relativistic and Quantum electrodynamics (QED) corrections.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-02049443
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Submitted on : Tuesday, February 26, 2019 - 1:55:18 PM
Last modification on : Friday, March 1, 2019 - 10:06:12 AM

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Raul Z. Martinez, Dionisio Bermejo, Piotr Wcislo, Franck Thibault. Accurate wavenumber measurements for the S-0(0), S-0(1), and S-0(2) pure rotational Raman lines of D-2. Journal of Raman Spectroscopy, Wiley, 2019, 50 (1), pp.127-129. ⟨10.1002/jrs.5499⟩. ⟨hal-02049443⟩

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