 |
 |
Journal articles
Highly selective macrocyclic ring-closing metathesis of terminal olefins in non-chlorinated solvents at low dilution
Abstract : A set of new ruthenium-indenylidene complexes bearing two unsymmetrical unsaturated N-cycloalkyl-NHC ligands were synthesized. These catalysts proved to be highly selective in the macrocyclic ring-closing metathesis performed in non-chlorinated solvents at low dilution (0.01 M). Without the requirement of benzoquinone derivatives to prevent the isomerisation side reactions, this environmentally friendly catalytic process promoted the synthesis of macrocyclic odorant molecules with remarkable > 99% purity.
Cited literature [58 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-02049520
Contributor : Laurent Jonchère <>
Submitted on : Friday, March 22, 2019 - 2:20:15 PM
Last modification on : Tuesday, March 26, 2019 - 1:01:51 AM
Long-term archiving on: : Sunday, June 23, 2019 - 3:09:25 PM
Contributor : Laurent Jonchère <>
Submitted on : Friday, March 22, 2019 - 2:20:15 PM
Last modification on : Tuesday, March 26, 2019 - 1:01:51 AM
Long-term archiving on: : Sunday, June 23, 2019 - 3:09:25 PM
File
Dumas-2019-Highly selective ma...
Files produced by the author(s)