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Journal articles
Second-Sphere Biomimetic Multipoint Hydrogen-Bonding Patterns to Boost CO2 Reduction of Iron Porphyrins
Abstract : Inspired by nature's orchestra of chemical subtleties to activate and reduce CO2, we have developed a family of iron porphyrin derivatives in to which we have introduced urea groups functioning as multipoint hydrogen‐bonding pillars on the periphery of the porphyrinic ring. This structure closely resembles the hydrogen‐bond stabilization scheme of the carbon dioxide (CO2) adduct in the carbon monoxide dehydrogenase (CODH). We found that such changes to the second coordination sphere significantly lowered the overpotential for CO2 reduction in this family of molecular catalysts and importantly increased the CO2 binding rate while maintaining high turnover frequency (TOF) and selectivity. Entrapped water molecules within the molecular clefts were found to be the source of protons for the CO2 reduction.
Cited literature [38 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-02050269
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, March 13, 2019 - 3:02:16 PM
Last modification on : Thursday, July 30, 2020 - 3:11:50 AM
Document(s) archivé(s) le : Friday, June 14, 2019 - 5:25:06 PM
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, March 13, 2019 - 3:02:16 PM
Last modification on : Thursday, July 30, 2020 - 3:11:50 AM
Document(s) archivé(s) le : Friday, June 14, 2019 - 5:25:06 PM
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