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Journal articles
High-Throughput Screening of the Alkoxide/Oxime-Based Library An Alternative to Organotin Compounds for the Alkoxysilane Condensation in Adhesives and Sealants
Abstract : In this work, a high-throughput screening (HTS) method was used to discover new efficient catalysts to substitute organotin compounds (DBTDL) for the cross-linking of silyl-modified polymers (SMPs). We report here on the use of our HTS method to investigate a library of alkoxide/oxime systems with different metal/ligand (M/L) ratios. Among the 156 candidates tested, 40 interesting hits were detected. Then, the cross-linking times for the better hits were measured on the SMP. Some of these seem to be more efficient than DBTDL and exhibit a good stability during storage in cartridges. Thereby, a high efficiency of alkoxide/oxime systems was established that shows great potential for the generation of new ligands to provide new tin-free catalysts for the cross-linking of adhesives and sealants.
Cited literature [30 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-02050595
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, March 13, 2019 - 10:56:54 AM
Last modification on : Wednesday, May 27, 2020 - 2:56:04 PM
Document(s) archivé(s) le : Friday, June 14, 2019 - 12:44:32 PM
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, March 13, 2019 - 10:56:54 AM
Last modification on : Wednesday, May 27, 2020 - 2:56:04 PM
Document(s) archivé(s) le : Friday, June 14, 2019 - 12:44:32 PM
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