, The authors thank Total Research and Technology Feluy and Total Corporate Research for continuous collaborative work. XD is grateful to Total Co. and ANRT for a PhD grant

A. L. Mcknight and R. M. Waymouth, Group 4 ansa-Cyclopentadienyl-Amido Catalysts for Olefin Polymerization, Chem. Rev, vol.98, pp.2587-2598, 1998.

H. G. Alt and A. Köppl, Effect of the Nature of Metallocene Complexes of Group IV Metals on Their Performance in Catalytic Ethylene and Propylene Polymerization, Chem. Rev, vol.100, pp.1205-1222, 2000.

L. Resconi, L. Cavallo, A. Fait, and F. Piemontesi, Selectivity in Propene Polymerization with Metallocene Catalysts, Chem. Rev, vol.100, pp.1253-1346, 2000.

W. Kaminsky, The discovery of metallocene catalysts and their present state of the art, J. Polym. Sci. A Polym. Chem, vol.42, pp.3911-3921, 2004.

W. Kaminsky and A. Laban, Metallocene catalysis, Appl. Catal., A, vol.222, pp.47-61, 2001.

C. Janiak and F. Blank, Metallocene Catalysts for Olefin Oligomerization, Macromol. Symp, vol.236, pp.14-22, 2006.

V. Busico, Metal-catalysed olefin polymerisation into the new millennium: a perspective outlook, pp.8794-8802, 2009.

H. H. Brintzinger and D. Fischer, Development of ansa-Metallocene Catalysts for Isotactic Olefin Polymerization, Polyolefins: 50 Years after Ziegler and Natta II, pp.29-42, 2013.

M. C. Baier, M. A. Zuideveld, and S. Mecking, Post-Metallocenes in the Industrial Production of Polyolefins, Angew. Chem. Int. Ed, vol.53, pp.9722-9744, 2014.

R. A. Collins, A. F. Russell, and P. Mountford, Group 4 metal complexes for homogeneous olefin polymerisation: a short tutorial review, Appl. Petrochem. Res, vol.5, pp.153-171, 2015.

W. Kaminsky, M. Miri, H. Sinn, and R. Woldt, Bis(cyclopentadienyl)zirkon-verbindungen und aluminoxan als Ziegler-Katalysatoren für die polymerisation und copolymerisation von olefinen, Makromol. Chem., Rapid Commun, vol.4, pp.417-421, 1983.

J. A. Ewen, Mechanisms of stereochemical control in propylene polymerizations with soluble Group 4B metallocene/methylalumoxane catalysts, J. Am. Chem. Soc, vol.106, pp.6355-6364, 1984.

H. Sinn, W. Kaminsky, H. Vollmer, and R. Woldt, Living Polymers" on Polymerization with Extremely Productive Ziegler Catalysts, Angew. Chem. Int. Ed, vol.19, pp.390-392, 1980.

F. R. Wild, M. Wasiucionek, G. Huttner, and H. H. Brintzinger, ansa-Metallocene derivatives: VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands, J. Organomet. Chem, vol.288, pp.63-67, 1985.

W. Spaleck, F. Kueber, A. Winter, J. Rohrmann, B. Bachmann et al., The Influence of Aromatic Substituents on the Polymerization Behavior of Bridged Zirconocene Catalysts, Organometallics, vol.13, pp.954-963, 1994.

W. Spaleck, M. Aulbach, B. Bachmann, F. Küber, and A. Winter, Stereospecific metallocene catalysts: Scope and limits of rational catalyst design, Macromol. Symp, vol.89, pp.237-247, 1995.

J. A. Ewen, R. L. Jones, A. Razavi, and J. D. Ferrara, Syndiospecific propylene polymerizations with Group IVB metallocenes, J. Am. Chem. Soc, vol.110, pp.6255-6256, 1988.

A. Razavi and J. L. Atwood, Preparation and crystal structures of the complexes (? 5 -C5H3Me-CMe2-? 5 -C13H8)MCl2 (M = Zr or Hf): mechanistic aspects of the catalytic formation of a syndiotactic-isotactic stereoblock-type polypropylene, J. Organomet. Chem, vol.497, pp.105-111, 1995.

E. Kirillov, N. Marquet, A. Razavi, V. Belia, F. Hampel et al., New C1-Symmetric Ph2C-Bridged Multisubstituted ansa-Zirconocenes for Highly Isospecific Propylene Polymerization: Synthetic Approach via Activated Fulvenes, vol.29, pp.5073-5082, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00576887

S. A. Miller and J. E. Bercaw, Mechanism of Isotactic Polypropylene Formation with C1-Symmetric Metallocene Catalysts, Organometallics, vol.25, pp.3576-3592, 2006.

J. Okuda, Bifunctional Cyclopentadienyl Ligands in Organotransition Metal Chemistry, Comments Inorg. Chem, vol.16, pp.185-205, 1994.

P. Jutzi and U. Siemeling, Cyclopentadienyl compounds with nitrogen donors in the side-chain, J. Organomet. Chem, vol.500, pp.175-185, 1995.

P. J. Shapiro, E. Bunel, W. P. Schaefer, and J. E. Bercaw, Scandium complex [{(? 5 -C5Me4)Me2Si(? 1 -NCMe3)}(PMe3)ScH]2: a unique example of a single-component ?-olefin polymerization catalyst, Organometallics, vol.9, pp.867-869, 1990.

D. W. Carpenetti, L. Kloppenburg, J. T. Kupec, and J. L. Petersen, Application of Amine Elimination for the Efficient Preparation of Electrophilic ansa-Monocyclopentadienyl Group 4 Complexes Containing an Appended Amido Functionality, ZrCl2(NMe2H), vol.15, pp.1572-1581, 1996.

E. Y. Tshuva, I. Goldberg, M. Kol, and Z. Goldschmidt, Zirconium Complexes of Amine?Bis(phenolate) Ligands as Catalysts for 1-Hexene Polymerization: Peripheral Structural Parameters Strongly Affect Reactivity, Organometallics, vol.20, pp.3017-3028, 2001.

E. Y. Tshuva, S. Groysman, I. Goldberg, M. Kol, and Z. Goldschmidt, Type Amine Bis(phenolate) Zirconium and Hafnium Complexes as Extremely Active 1-Hexene Polymerization Catalysts, Organometallics, vol.21, pp.662-670, 2002.

H. Makio, N. Kashiwa, T. Fujita, and . Catalysts, A New Family of High Performance Catalysts for Olefin Polymerization, Adv. Synth. Catal, vol.344, pp.477-493, 2002.

S. Matsui, M. Mitani, J. Saito, Y. Tohi, H. Makio et al., A Family of Zirconium Complexes Having Two Phenoxy?Imine Chelate Ligands for Olefin Polymerization, J. Am. Chem. Soc, vol.123, pp.6847-6856, 2001.

T. Matsugi and T. Fujita, High-performance olefin polymerization catalysts discovered on the basis of a new catalyst design concept, Chem. Soc. Rev, vol.37, pp.1264-1277, 2008.

T. R. Boussie, G. M. Diamond, C. Goh, K. A. Hall, A. M. Lapointe et al., Nonconventional Catalysts for Isotactic Propene Polymerization in Solution Developed by Using High-Throughput-Screening Technologies, Angew. Chem. Int. Ed, vol.45, pp.3278-3283, 2006.

G. J. Domski, E. B. Lobkovsky, and G. W. Coates, Polymerization of ?-Olefins with Pyridylamidohafnium Catalysts: Living Behavior and Unexpected Isoselectivity from a Cs-Symmetric Catalyst Precursor, Macromolecules, vol.40, pp.3510-3513, 2007.

S. Mehdiabadi, J. B. Soares, D. Bilbao, and J. Brinen, Ethylene Polymerization and Ethylene/1-Octene Copolymerization with rac-Dimethylsilylbis(indenyl)hafnium Dimethyl Using Trioctyl Aluminum and Borate: A Polymerization Kinetics Investigation, Macromolecules, vol.46, pp.1312-1324, 2013.

C. Chen, W. Shih, and C. Hilty, ]-Catalyzed Polymerization of 1-Hexene Using 13 C Hyperpolarized NMR, Situ Determination of Tacticity, Deactivation, and Kinetics in, vol.137, pp.6965-6971, 2015.

J. M. Estrada and A. E. Hamielec, Modelling of ethylene polymerization with Cp2ZrCl2/MAO catalyst, Polymer, vol.35, pp.808-818, 1994.

K. A. Novstrup, N. E. Travia, G. A. Medvedev, C. Stanciu, J. M. Switzer et al., Mechanistic Detail Revealed via Comprehensive Kinetic Modeling of [rac-C2H4(1-indenyl)2ZrMe2]-Catalyzed 1-Hexene Polymerization, J. Am. Chem. Soc, vol.132, pp.558-566, 2010.

G. Natta and I. Pasquon, The Kinetics of the Stereospecific Polymerization of ?-Olefins, Advances in Catalysis, pp.60416-60418, 1959.

V. Busico, R. Cipullo, and V. Esposito, Stopped-flow polymerizations of ethene and propene in the presence of the catalyst system rac-Me2Si(2-methyl-4-phenyl-1-indenyl)2ZrCl2/methylaluminoxane, Macromol. Rapid Commun, vol.20, pp.116-121, 1999.

T. Shiono, M. Ohgizawa, and K. Soga, Reaction of the Ti-polyethylene bond with carbon monoxide over the bis(cyclopentadienyl)titanium dichloride-methylaluminoxane catalyst system, Polymer, vol.35, pp.187-192, 1994.

F. Song, R. D. Cannon, and M. Bochmann, Zirconocene-Catalyzed Propene Polymerization: A Quenched-Flow Kinetic Study, J. Am. Chem. Soc, vol.125, pp.7641-7653, 2003.

F. Ghiotto, C. Pateraki, J. R. Severn, N. Friederichs, and M. Bochmann, Rapid evaluation of catalysts and MAO activators by kinetics: what controls polymer molecular weight and activity in metallocene/MAO catalysts?, Dalton Trans, vol.42, pp.9040-9048, 2013.

V. D. Schnell and G. Fink, Elementarprozesse der Ziegler-Natta-Katalyse. I. Oligomerenkinetik im Strömungsrohr, Angew. Makromol. Chem, vol.39, pp.131-147, 1974.

T. Keii, M. Terano, K. Kimura, and K. Ishii, A kinetic argument for a quasi-living polymerization of propene with a MgCl2-supported catalyst, Makromol. Chem. Rapid Commun, vol.8, pp.583-587, 1987.

R. Cipullo, P. Melone, Y. Yu, D. Iannone, and V. Busico, Olefin polymerisation catalysts: when perfection is not enough, Dalton Trans, vol.44, pp.12304-12311, 2015.

F. Song, R. D. Cannon, S. J. Lancaster, and M. Bochmann, Activator effects in metallocenebased alkene polymerisations: unexpectedly strong dependence of catalyst activity on trityl concentration, J. Mol. Catal. A: Chem, vol.218, pp.21-28, 2004.

M. Bochmann, S. J. Lancaster, M. D. Hannant, A. Rodriguez, M. Schormann et al., Role of B(C6F5)3 in catalyst activation, anion formation, and as C6F5 transfer agent, Pure Appl. Chem, vol.75, pp.1183-1195, 2003.

Z. Liu, E. Somsook, C. B. White, K. A. Rosaaen, and C. R. Landis, Kinetics of Initiation, Propagation, and Termination for the [rac-(C2H4(1-indenyl)2)ZrMe][MeB(C6F5)3]-Catalyzed Polymerization of 1-Hexene, J. Am. Chem. Soc, vol.123, pp.11193-11207, 2001.

C. B. White, K. A. Rosaaen, and C. R. Landis, A rapid quenched-flow device for the study of homogeneous polymerization kinetics, Rev. Sci. Instrum, vol.73, pp.411-415, 2002.

M. M. Ranieri, J. Broyer, F. Cutillo, T. F. Mckenna, and C. Boisson, Site count: is a highpressure quenched-flow reactor suitable for kinetic studies of molecular catalysts in ethylene polymerization?, Dalton Trans, vol.42, pp.9049-9057, 2013.
URL : https://hal.archives-ouvertes.fr/hal-01874368

B. M. Moscato, B. Zhu, C. R. Landis, and E. , Analysis of Labeled Poly(1-Hexene): Rapid Determination of Initiated Site Counts during Catalytic Alkene Polymerization Reactions, J. Am. Chem. Soc, vol.132, pp.14352-14354, 2010.

B. M. Moscato, B. Zhu, and C. R. Landis, Mechanistic Investigations into the Behavior of a Labeled Zirconocene Polymerization Catalyst, Organometallics, vol.31, pp.2097-2107, 2012.

J. M. Switzer, N. E. Travia, D. K. Steelman, G. A. Medvedev, K. T. Thomson et al., Kinetic Modeling of 1-Hexene Polymerization Catalyzed by Zr(tBu-ONNMe2O)Bn2/B(C6F5)3, Macromolecules, vol.45, pp.4978-4988, 2012.

D. K. Steelman, P. D. Pletcher, J. M. Switzer, S. Xiong, G. A. Medvedev et al., Comparison of Selected Zirconium and Hafnium Amine Bis(phenolate) Catalysts for 1-Hexene Polymerization, Organometallics, vol.32, pp.4862-4867, 2013.

D. K. Steelman, S. Xiong, P. D. Pletcher, E. Smith, J. M. Switzer et al., Effects of Pendant Ligand Binding Affinity on Chain Transfer for 1-Hexene Polymerization Catalyzed by Single-Site Zirconium Amine Bis-Phenolate Complexes, J. Am. Chem. Soc, vol.135, pp.6280-6288, 2013.

D. K. Steelman, S. Xiong, G. A. Medvedev, W. N. Delgass, J. M. Caruthers et al., Effects of Electronic Perturbations on 1-Hexene Polymerization Catalyzed by Zirconium Amine Bisphenolate Complexes, ACS Catal, vol.4, pp.2186-2190, 2014.

P. D. Pletcher, J. M. Switzer, D. K. Steelman, G. A. Medvedev, W. N. Delgass et al., Quantitative Comparative Kinetics of 1-Hexene Polymerization across Group IV Bis-Phenolate Catalysts, vol.6, pp.5138-5145, 2016.

A. Z. Preston, J. Kim, G. A. Medvedev, W. N. Delgass, J. M. Caruthers et al., Steric and Solvation Effects on Polymerization Kinetics, Dormancy, and Tacticity of Zr-Salan Catalysts, Organometallics, vol.36, pp.2237-2244, 2017.

J. M. Switzer, P. D. Pletcher, D. K. Steelman, J. Kim, G. A. Medvedev et al., Quantitative Modeling of the Temperature Dependence of the Kinetic Parameters for Zirconium Amine Bis(Phenolate) Catalysts for 1-Hexene Polymerization, ACS Catal, vol.8, pp.10407-10418, 2018.

N. Naga, T. Shiono, and T. Ikeda, Polymerization behavior of ?-olefins with rac-and meso-type ansa-metallocene catalysts: Effects of cocatalyst and metallocene ligand, Macromol. Chem. Phys, vol.200, pp.1587-1594, 1999.

Z. Liu, E. Somsook, and C. R. Landis, A 2 H-Labeling Scheme for Active-Site Counts in Metallocene-Catalyzed Alkene Polymerization, J. Am. Chem. Soc, vol.123, pp.2915-2916, 2001.

J. C. Chien and C. Kuo, Magnesium chloride supported high mileage catalyst for olefin polymerization. VII. Determinations of concentrations of titanium-polymer and aluminumpolymer bonds, J. Polym. Sci. Polym. Chem, vol.23, pp.731-760, 1985.

J. C. Chien and C. Kuo, Magnesium chloride supported high mileage catalyst for olefin polymerization. VIII. Decay and transformation of active sites, J. Polym. Sci. Polym. Chem, vol.23, pp.761-786, 1985.

J. C. Chien and Y. Hu, Magnesium chloride supported high-mileage catalysts for olefin polymerization. XVII. Effect of lewis base on propylene polymerization, J. Polym. Sci. A Polym. Chem, vol.25, pp.2847-2870, 1987.

J. C. Chien and Y. Hu, Magnesium chloride supported high-mileage catalysts for olefin polymerizations. XVIII. Effect of hydrogen and lewis bases, J. Polym. Sci. A Polym. Chem, vol.25, pp.2881-2892, 1987.

J. C. Chien and B. Wang, Metallocene-methylaluminoxane catalysts for olefin polymerization. I. Trimethylaluminum as coactivator, J. Polym. Sci. A Polym. Chem, vol.26, pp.3089-3102, 1987.

J. C. Chien and B. Wang, Metallocene-methylaluminoxane catalysts for olefin polymerizations. IV. Active site determinations and limitation of the 14 CO radiolabeling technique, J. Polym. Sci. A Polym. Chem, vol.27, pp.1539-1557, 1989.

J. C. Chien and A. Razavi, Metallocene-methylaluminoxane catalyst for olefin polymerization. II. Bis-? 5 -(neomenthyl cyclopentadienyl)zirconium dichloride, J. Polym. Sci. A Polym. Chem, vol.26, pp.2369-2380, 1988.

J. C. Chien and R. Sugimoto, Kinetics and stereochemical control of propylene polymerization initiated by ethylene bis(4,5,6,7-tetrahydro-1-indenyl) zirconium dichloride/methyl aluminoxane catalyst, J. Polym. Sci. A Polym. Chem, vol.29, pp.459-470, 1991.

J. C. Chien, W. Song, and M. D. Rausch, Effect of counterion structure on zirconocenium catalysis of olefin polymerization, vol.26, pp.3239-3240, 1993.

J. C. Chien, G. H. Llinas, M. D. Rausch, G. Y. Lin, H. H. Winter et al., Two-state propagation mechanism for propylene polymerization catalyzed by rac-[antiethylidene(1-? 5 -tetramethylcyclopentadienyl)(1-? 5 -indenyl)] dimethyltitanium, J. Am. Chem. Soc, vol.113, pp.8569-8570, 1991.

V. Warzelhan, T. F. Burger, and D. J. Stein, Über die bestimmung der zahl polymerisationsaktiver zentren von ziegler-natta-katalysatoren. Eine modifizierte methode mit 14 C-markierten kohlenstoffoxiden, Makromol. Chem, vol.183, pp.489-504, 1982.

T. Shiono, M. Ohgizawa, and K. Soga, Reaction between carbon monoxide and a Tipolyethylene bond with a MgCl2-supported TiCl4 catalyst system, Makromol. Chem, vol.194, pp.2075-2085, 1993.

J. Mejzlík and M. Lesná, Determination of active centers in heterogeneous Ziegler-Natta catalytic systems using carbon oxides, Makromol. Chem, vol.178, pp.261-266, 1977.

J. Mejzlík, M. Lesná, and J. Majer, Comparison of methods for determination of the number of active centers in Ziegler-Natta polymerizations, Makromol. Chem, vol.184, pp.1975-1985, 1983.

G. D. Bukatov, V. S. Goncharov, and V. A. Zakharov, Interaction of 14 CO with Ziegler-type heterogeneous catalysts and effect of interaction products on the determination of the centers, Makromol. Chem, vol.187, pp.1041-1051, 1986.

M. M. Marques, P. J. Tait, J. Mejzlík, and A. R. Dias, Polymerization of ethylene using highactivity Ziegler-type catalysts: Active center determination, J. Polym. Sci. A Polym. Chem, vol.36, pp.573-585, 1998.

T. K. Han, Y. S. Ko, J. W. Park, and S. I. Woo, Determination of the Number of Active Sites for Olefin Polymerization Catalyzed over Metallocene/MAO Using the CO Inhibition Method, Macromolecules, vol.29, pp.7305-7309, 1996.

V. Busico, M. Guardasole, A. Margonelli, and A. L. Segre, Insertion of Carbon Monoxide into Zr?Polymeryl Bonds, J. Am. Chem. Soc, vol.122, pp.5226-5227, 2000.

P. J. Tait, B. L. Booth, and M. O. Jejelowo, The effect of 14 CO contact times on active centre determinations for the polymerization of ethylene catalysed by bis(?cyclopentadienyl)zirconium(IV) dichloride/methylaluminoxane, Makromol. Chem., Rapid Commun, vol.9, pp.393-398, 1988.

P. J. Tait, B. L. Booth, and M. O. Jejelowo, Rate of Ethylene Polymerization with the Catalyst System (? 5 -RC5H4)2ZrCl2-Methylaluminoxane, in: Catalysis in Polymer Synthesis, pp.78-87, 1992.

J. Mejzlík, M. Lesná, and J. Kratochvíla, Determination of the number of active centers in Ziegler-Natta polymerizations of olefins, in: Catalytical and Radical Polymerization, pp.83-120, 1986.

D. L. Nelsen, B. J. Anding, J. L. Sawicki, M. D. Christianson, D. J. Arriola et al., Chromophore Quench-Labeling: An Approach to Quantifying Catalyst Speciation As Demonstrated for (EBI)ZrMe2/B(C6F5)3-Catalyzed Polymerization of 1-Hexene, ACS Catal, vol.6, pp.7398-7408, 2016.

E. S. Cueny, H. C. Johnson, B. J. Anding, and C. R. Landis, Mechanistic Studies of Hafnium-Pyridyl Amido-Catalyzed 1-Octene Polymerization and Chain Transfer Using Quench-Labeling Methods, J. Am. Chem. Soc, vol.139, pp.11903-11912, 2017.

H. C. Johnson, E. S. Cueny, and C. R. Landis, Chain Transfer with Dialkyl Zinc During Hafnium-Pyridyl Amido-Catalyzed Polymerization of 1-Octene: Relative Rates, Reversibility, and Kinetic Models, ACS Catal, pp.4178-4188, 2018.

E. S. Cueny, H. C. Johnson, and C. R. Landis, Selective Quench-Labeling of the Hafnium-Pyridyl Amido-Catalyzed Polymerization of 1-Octene in the Presence of Trialkyl-Aluminum Chain-Transfer Reagents, ACS Catal, pp.11605-11614, 2018.

R. Cipullo, S. Mellino, and V. Busico, Identification and Count of the Active Sites in Olefin Polymerization Catalysis by Oxygen Quench, Macromolecular Chemistry and Physics, vol.215, pp.1728-1734, 2014.

G. Ciancaleoni, N. Fraldi, P. H. Budzelaar, V. Busico, R. Cipullo et al., Structure?Activity Relationship in Olefin Polymerization Catalysis: Is Entropy the Key?, J. Am. Chem. Soc, vol.132, pp.13651-13653, 2010.

M. Vatamanu, B. N. Boden, and M. C. Baird, An Investigation into the Identities and the Relative Concentrations of the Zr?Polymeryl Species Present during Ethylene and Propylene Polymerizations by Zirconocene-Based Ziegler Catalysts, Macromolecules, vol.38, pp.9944-9949, 2005.

X. Shen, J. Hu, Z. Fu, J. Lou, and Z. Fan, Counting the number of active centers in MgCl2-supported Ziegler-Natta catalysts by quenching with 2-thiophenecarbonyl chloride and study on the initial kinetics of propylene polymerization, Catal Commun, vol.30, pp.66-69, 2013.

J. Hu, B. Han, X. Shen, Z. Fu, and Z. Fan, Probing the roles of diethylaluminum chloride in propylene polymerization with MgCl2-supported ziegler-natta catalysts, Chin. J. Polym. Sci, vol.31, pp.583-590, 2013.

X. Shen, Z. Fu, J. Hu, Q. Wang, and Z. Fan, Mechanism of Propylene Polymerization with MgCl2-Supported Ziegler-Natta Catalysts Based on Counting of Active Centers: The Role of External Electron Donor, J. Phys. Chem. C, vol.117, pp.15174-15182, 2013.

Y. Guo, F. He, Z. Zhang, A. Khan, Z. Fu et al., Influence of trimethylaluminum on kinetics of rac-Et(Ind)2ZrCl2/aluminoxane catalyzed ethylene polymerization, J. Organomet. Chem, vol.808, pp.109-116, 2016.

Y. Guo, Z. Zhang, W. Guo, A. Khan, Z. Fu et al., Kinetics and mechanism of metallocene-catalyzed olefin polymerization: Comparison of ethylene, propylene homopolymerizations, and their copolymerization, J. Polym. Sci. A Polym. Chem, vol.55, pp.867-875, 2017.

G. Fink and D. Schnell, Elementarprozesse der Ziegler-Katalyse. IV. Kinetische Auswertung der im Strömungsrohr erzeugten Oligomerenverteilungen, Angew. Chem. Int. Ed, vol.105, pp.39-48, 1982.

G. Ciancaleoni, N. Fraldi, P. H. Budzelaar, V. Busico, and A. Macchioni, Activation of a bis(phenoxy-amine) precatalyst for olefin polymerisation: first evidence for an outer sphere ion pair with the methylborate counterion, pp.8824-8827, 2009.