J. Wang, M. Sánchez-roselló, J. L. Aceña, C. Del-pozo, A. E. Sorochinsky et al., Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade, vol.114, pp.2432-2506, 2001.

F. Babudri, G. M. Farinola, F. Naso, and R. Ragni, Fluorinated Organic Materials for Electronic and Optoelectronic Applications: the Role of the Fluorine Atom, Chem. Commun, pp.1003-1022, 2007.

N. Damjanov, R. S. Kauffman, and G. T. Spencer-green, Efficacy, Pharmacodynamics, and Safety of VX-702, a Novel p38 MAPK Inhibitor, in Rheumatoid Arthritis: Results of Two Randomized, Double-Blind, Placebo-Controlled Clinical Studies, Arthritis Rheum, vol.60, pp.1232-1241, 2009.

A. B. Tamayo, B. D. Alleyne, P. I. Djurovich, S. Lamansky, I. Tsyba et al., Influence of Substituents on the Energy and Nature of the Lowest Excited States of Heteroleptic Phosphorescent Ir(III) Complexes: A Joint Theoretical and Experimental Study, J. Am. Chem. Soc, vol.125, pp.136-148, 2003.

S. Ladouceur, K. N. Swanick, S. Gallagher-duval, Z. Ding, E. Zysmancolman et al., Fabrication and Efficiency Improvement of Soluble Blue Phosphorescent Organic Light-Emitting Diodes Using a Multilayer Structure Based on an Alcohol-Soluble Blue Phosphorescent Emitting Layer, Phosphorescent Iridium(III) Complexes Bearing Fluorinated Aromatic Sulfonyl Group with Nearly Unity Phosphorescent Quantum Yields and Outstanding Electroluminescent Properties, vol.22, pp.7532-7585, 2010.

H. Shi, H. Sun, H. Yang, S. Liu, G. Jenkins et al., Polyfluorenes with Phosphorescent Iridium(III) Complexes for Time-Resolved Luminescent Biosensing and Fluorescence Lifetime Imaging, Adv. Funct. Mater, vol.26, pp.6505-6505, 2016.

J. Wang, J. Xue, Z. Yan, S. Zhang, J. Qiao et al., Photoluminescence Lifetime Imaging of Synthesized Proteins in Living Cells Using an Iridium-Alkyne Probe, Angew. Chem. Int. Ed, vol.56, pp.14928-14932, 2017.

M. Ouyang, L. Zeng, H. Huang, C. Jin, J. Liu et al., Fluorinated Cyclometalated Iridium(III) Complexes as Mitochondria-Targeted Theranostic Anticancer Agents, Dalton Trans, vol.46, pp.6734-6744, 2017.

S. Tokito, T. Iijima, Y. Suzuri, H. Kita, T. Tsuzuki et al., Confinement of Triplet Energy on Phosphorescent Molecules for Highly-Efficient Organic Blue-Light-Emitting Devices, Appl. Phys. Lett, vol.83, issue.9, pp.461-476, 2003.

A. F. Henwood and E. Zysman-colman, Lessons Learned in Tuning the Optoelectronic Properties of Phosphorescent Iridium(III) Complexes, Chem. Commun, vol.53, pp.807-826, 2017.

L. Ackermann, R. Vicente, and A. R. Kapdi, Transition-MetalCatalyzed Direct Arylation of (Hetero)Arenes by C-H Bond Cleavage

X. Chen, K. M. Engle, D. Wang, J. Yu, T. Satoh et al., Palladium(II)-Catalyzed C-H Activation/C-C Cross-Coupling Reactions: Versatility and Practicality, Angew. Chem. Int. Ed, vol.48, pp.878-873, 2009.

S. K. Sinha, G. Zanoni, and D. Maiti, Natural Product Synthesis by C?H Activation, Asian J. Org. Chem, vol.7, pp.1178-1192, 2018.

L. Ping, D. S. Chung, J. Bouffard, and S. Lee, Transition Metal-Catalyzed Site-and Regio-Divergent C-H Bond Functionalization, Chem. Soc. Rev, vol.46, pp.4299-4328, 2017.

N. Kuhl, M. N. Hopkinson, J. Wencel-delord, F. Glorius, Z. Chen et al., Transition MetalCatalyzed C-H Bond Functionalizations by the Use of Diverse Directing Groups, Angew. Chem. Int. Ed, vol.51, pp.1107-1295, 2012.

D. Leow, G. Li, T. Mei, and J. Yu, Activation of Remote meta-C-H Bonds Assisted by an End-on Template, Nature, vol.486, p.518, 2012.

S. Bag, T. Patra, A. Modak, A. Deb, S. Maity et al., Remote para-C-H Functionalization of Arenes by a D-Shaped Biphenyl Template-Based Assembly, Angew. Chem. Int. Ed, vol.137, issue.14, p.538, 2015.

M. Yu, W. Lee, C. Chen, F. Tsai, T. Ong et al., Controlled Regiodivergent C-H Bond Activation of Imidazo[1,5-a]pyridine via Synergistic Cooperation between Aluminum and Nickel, Regiodivergent Cross-Dehydrogenative Coupling of Pyridines and Benzoxazoles: Discovery of Organic Halides as Regio-Switching Oxidants, vol.16, pp.4826-4829, 2014.

W. Hagui, N. Besbes, E. Srasra, T. Roisnel, J. Soulé et al., Short Synthesis of Sulfur Analogues of Polyaromatic Hydrocarbons through Three Palladium-Catalyzed C-H Bond Arylations, A Lesson for Site-Selective C-H Functionalization on 2-Pyridones: Radical, Organometallic, Directing Group and Steric Controls, vol.18, pp.22-32, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01367240

L. Ping, D. S. Chung, J. Bouffard, S. Lee, M. Lafrance et al., (sp2)-H Borylation of Fluorinated Arenes Using an AirStable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities, J. Am. Chem. Soc, vol.46, pp.2825-2832, 2006.

L. Davin, R. Mclellan, A. R. Kennedy, E. Hevia, P. B. Arockiam et al., LigandInduced Reactivity of ?-Diketiminate Magnesium Complexes for Regioselective Functionalization of Fluoroarenes via C-H or C-F Bond Activations, Ruthenium(II)-Catalyzed C-H Bond Activation and Functionalization, vol.53, pp.11650-11653, 2017.

P. Nareddy, F. Jordan, and M. Szostak, Recent Developments in Ruthenium-Catalyzed C-H Arylation: Array of Mechanistic Manifolds, Chem. Rev, vol.112, pp.5721-5745, 2012.

M. Simonetti, G. J. Perry, X. C. Cambeiro, F. Juliá-hernández, J. N. Arokianathar et al., Ru-Catalyzed C-H Arylation of Fluoroarenes with Aryl Halides, J. Am. Chem. Soc, vol.138, pp.3596-3606, 2016.

O. Eisenstein, J. Milani, R. N. Perutz, C. Selectivity-of-c-h-activation-and-competition-between-c-h, D. L. Bond-;-davies et al., Cycloruthenated CompoundsSynthesis and Applications, Room-Temperature Cyclometallation of Amines, Imines and Oxazolines with [MCl2Cp*]2 (M = Rh, Ir) and, vol.117, pp.817-853, 2003.

E. Ferrer-flegeau, C. Bruneau, P. H. Dixneuf, A. Jutand, Q. Bu et al., Autocatalysis for C-H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes, Angew. Chem. Int. Ed, vol.133, pp.765-768, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00651994

N. Matsuo, A. M. Bünzli, E. C. Constable, C. E. Housecroft, A. Prescimone et al., Exceptionally Long-Lived Light-Emitting Electrochemical Cells: Multiple Intra-Cation ?-Stacking Interactions in, Synthesis of a Few Derivatives of Cycloiridated 2-(2-Thienyl)pyridine, vol.52, pp.6385-6397, 1979.