Synthesis and crystal structure of a new coordination polymer based on lanthanum and 1,4-phenylenediacetate ligands

Magatte Camara 1 Insa Badiane 1 Mamoudou Diallo 2 Carole Daiguebonne 3 Olivier Guillou 3
1 LCPM - Groupe Matériaux Inorganiques:Chimie Douce et Cristallographie
2 LCPM
3 ISCR - Institut des Sciences Chimiques de Rennes
Abstract : Reaction in gel between the sodium salt of 1,4-phenyl-enedi-acetic acid (NaCOH-Na-pda) and lanthanum chloride yields single crystals of the three-dimensional coordination polymer poly[[tetra-aqua-tris-(μ-1,4-phenyl-enedi-acetato)-dilanthanum(III)] octa-hydrate], {[La(CHO)(HO)]·8HO}. The La coordination polyhedron can be described as a slightly distorted monocapped square anti-prism. One of the two -pda ligands is bound to four La ions and the other to two La ions. Each La atom is coordinated by five ligands, thereby generating a metal-organic framework with potential porosity properties.
Keywords : lanthanum ion coordination polymer crystal structure
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Journal articles
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-02086461
Contributor : Laurent Jonchère <>
Submitted on : Monday, April 1, 2019 - 1:09:47 PM
Last modification on : Friday, June 14, 2019 - 1:01:26 PM

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UNIV-RENNES1 | ISCR | UR1-UFR-SPM | INC-CNRS | UNIV-RENNES | INSA-GROUPE

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Magatte Camara, Insa Badiane, Mamoudou Diallo, Carole Daiguebonne, Olivier Guillou. Synthesis and crystal structure of a new coordination polymer based on lanthanum and 1,4-phenylenediacetate ligands. Acta crystallographica. Section E, Crystallographic communications, International Union of Crystallography, 2019, 75 (3), pp.378-+. ⟨10.1107/S2056989019002378⟩. ⟨hal-02086461⟩

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