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Journal articles
Synthesis and crystal structure of a new coordination polymer based on lanthanum and 1,4-phenylenediacetate ligands
Abstract : Reaction in gel between the sodium salt of 1,4-phenylenediacetic acid (Na 2 C 10 O 4 H 8 –Na 2 p -pda) and lanthanum chloride yields single crystals of the three-dimensional coordination polymer poly[[tetraaquatris(μ-1,4-phenylenediacetato)dilanthanum(III)] octahydrate], {[La 2 (C 10 H 8 O 4 ) 3 (H 2 O) 4 ]·8H 2 O} ∞ . The La III coordination polyhedron can be described as a slightly distorted monocapped square antiprism. One of the two p -pda 2− ligands is bound to four La III ions and the other to two La III ions. Each La III atom is coordinated by five ligands, thereby generating a metal–organic framework with potential porosity properties.
Cited literature [47 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-02086461
Contributor : Catherine Derennes <>
Submitted on : Monday, April 27, 2020 - 10:15:38 AM
Last modification on : Wednesday, April 7, 2021 - 3:18:12 PM
Contributor : Catherine Derennes <>
Submitted on : Monday, April 27, 2020 - 10:15:38 AM
Last modification on : Wednesday, April 7, 2021 - 3:18:12 PM
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