Halogen and chalcogen-bonding interactions in sulphur-rich π-electron acceptors

Y. Le Gal; A. Colas; F. Barrière; V. Dorcet; T. Roisnel; D. Lorcy

doi:10.1039/c8ce02046a

Journal articles

Halogen and chalcogen-bonding interactions in sulphur-rich π-electron acceptors

Y. Le Gal ¹ A. Colas ¹ F. Barrière ¹ V. Dorcet ¹ T. Roisnel ¹ D. Lorcy ^{1, *}

* Corresponding author

1 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : In order to explore the feasibility of generating halogen bonding interactions between sulphur-rich π-electron acceptors, we prepared three bithiazolidinylidene derivatives substituted by iodine atoms, namely 3,3′-bis(iodophenyl)bithiazolidinylidene-2,4,2′,4′-tetrathione (BIP-BTTT). Sulphur and iodine heteroatoms were introduced to the skeleton of the acceptor molecule to induce chalcogen...chalcogen and halogen bonding interactions. Both interactions can be evidenced by X-ray diffraction studies in the synthetic precursors as well as in the acceptors themselves.

Keywords : X-ray diffraction studies Sulfur Synthetic precursors Iodine Acceptor molecules Bonding interactions Electron acceptor Halogen bonding Heteroatoms Iodine atoms

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Journal articles

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Chemical Sciences / Organic chemistry

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Submitted on : Wednesday, April 17, 2019 - 11:33:16 AM
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Halogen and chalcogen-bonding interactions in sulphur-rich π-electron acceptors

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Halogen and chalcogen-bonding interactions in sulphur-rich π-electron acceptors

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