A. L. Anderson, S. Chen, L. Romero, I. Top, and R. Binions, Thin films for advanced glazing applications, Buildings, vol.6, pp.37-71, 2016.

H. Khandelwal, A. Schenning, and M. G. Debije, Infrared regulating smart window based on organic materials, Adv. Energy Mater, vol.7, pp.602-209, 2017.

P. S. Kuttipillai, Y. Zhao, C. J. Traverse, R. J. Staples, B. G. Levine et al., Phosphorescent nanocluster light-emitting diodes, Adv. Mater, vol.28, pp.320-326, 2016.

M. G. Debije and P. Verbunt, Thirty years of luminescent solar concentrator research: solar energy for the built environment, Adv. Energy Mater, vol.2, pp.12-35, 2012.

Y. Zhao, G. A. Meek, B. G. Levine, and R. R. Lunt, Near-infrared harvesting transparent luminescent solar concentrators, Adv. Mater, vol.2, pp.606-611, 2014.

F. Meinardi, F. Bruni, and S. Brovelli, , 2017.

, Luminescent solar concentrators for buildingintegrated photovoltaics, Nat. Rev. Mater, vol.2, pp.1-9

F. Meinardi, S. Ehrenberg, L. Dhamo, F. Carulli, M. Mauri et al., Highly efficient luminescent solar concentrators based on earth-abundant indirect-bandgap silicon quantum dots, Nat. Photonics, vol.11, pp.177-186, 2017.

C. J. Traverse, R. Pandey, M. C. Barr, and R. R. Lunt, Emergence of highly transparent photovoltaics for distributed applications, Nature Energy, vol.2, pp.849-860, 2017.

A. Llorde, G. Garcia, J. Gazquez, and D. J. Milliron, Tunable near-infrared and visible-light transmittance in nanocrystal-in-glass composites, Nature, vol.500, pp.323-326, 2013.

J. Xamán, C. Pérez-nucamendi, J. Arce, J. Hinojosa, G. Álvarez et al., Thermal analysis for a double pane window with a solar control film for using in cold and warm climates, Energy Buildings, vol.76, pp.429-439, 2014.

L. V. Besteiro, X. T. Kong, Z. Wang, F. Rosei, and A. O. Govorov, Plasmonic glasses and films based on alternative inexpensive materials for blocking infrared radiation, Nano Lett, vol.18, pp.3147-3156, 2018.

T. G. Truong, Visible tunable lighting system based on polymer composites embedding ZnO and metallic clusters: from colloids to thin films, Sci. Technol. Adv. Mater, vol.17, pp.443-453, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01364251

T. Nguyen, New ultra-violet and near-infrared blocking filters for energy saving applications: fabrication of tantalum metal atom cluster-based nanocomposite thin films by electrophoretic deposition, J. Mater. Chem. C, vol.5, pp.477-487, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01631913

F. A. Cotton, Metal atom clusters in oxide systems, Inorg. Chem, vol.3, p.1217, 1964.

A. Perrin and C. Perrin, The molybdenum and rhenium octahedral cluster chalcohalides in solid state chemistry: from condensed to discrete cluster units, C. R. Chimie, vol.15, pp.815-836, 2012.
URL : https://hal.archives-ouvertes.fr/hal-01070078

V. Fedorov, Metal clusters: as they were born in Siberia, J. Clust. Sci, vol.26, pp.3-15, 2015.

K. Kirakci, P. Kubát, K. Fejfarová, J. Martin?ík, M. Nikl et al., X-ray inducible luminescence and singlet oxygen sensitization by an octahedral molybdenum cluster compound: a royalsocietypublishing.org/journal/rsos R. Soc. open sci. 6: 181647 11 new class of nanoscintillators, Inorg. Chem, vol.55, pp.3-809, 2016.

B. Dierre, Mo 6 cluster-based compounds for energy conversion applications: comparative study of photoluminescence and cathodoluminescence, Sci. Technol. Adv. Mater, vol.18, pp.458-466, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01578524

N. Saito, P. Lemoine, S. Cordier, Y. Wada, T. Ohsawa et al., Solvent-mediated purification of hexamolybdenum cluster halide, Cs 2 [Mo 6 Cl 14 ] for enhanced optical properties, CrystEngComm, vol.19, pp.6028-6038, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01631919

S. Akagi, S. Fujii, and N. Kitamura, A study on the redox, spectroscopic, and photophysical characteristics of a series of octahedral hexamolybdenum(II) clusters, Br, or I). Dalton Trans, vol.47, pp.1131-1139, 2018.

N. A. Vorotnikova, 23-Electron octahedral molybdenum cluster complex [fMo 6 I 8 gCl 6 ] 2, Inorg. Chem, vol.57, pp.811-820, 2018.

M. A. Mikhailov, K. A. Brylev, P. A. Abramov, E. Sakuda, S. Akagi et al., Synthetic tuning of redox, spectroscopic, and photophysical properties of fMo 6 I 8 g 4þ core cluster complexes by terminal carboxylate ligands, Inorg. Chem, vol.55, pp.8437-8445, 2016.

S. Fujii, T. Horiguchi, S. Akagi, and N. Kitamura, Quasi-one-step six-electron electrochemical reduction of an octahedral hexanuclear molybdenum(ii) cluster, Inorg. Chem, vol.55, pp.259-269, 2016.

N. Saito, S. Cordier, P. Lemoine, T. Ohsawa, Y. Wada et al., Lattice and valence electronic structures of crystalline octahedral molybdenum halide clusters-based compounds, Inorg. Chem, vol.56, issue.2, pp.6234-6243, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01544244

W. N. Hansen and R. A. Osteryoung, Oxidation of tantalum cluster ions, J. Amer. Chem. Soc, vol.88, pp.1063-1064, 1966.

J. Lowe, D. Stock, B. Jap, P. Zwickl, W. Baumeister et al., Science, vol.268, pp.533-539, 1995.

P. Cramer, Architecture of RNA polymerase II and implications for the transcription mechanism, Science, vol.288, pp.640-649, 2000.

K. N. Ferreira, T. M. Iverson, K. Maghlaoui, and J. Barber, Architecture of the photosynthetic oxygenevolving center, Science, vol.43, pp.1831-1839, 2004.

B. F. Mullan, M. T. Madsen, L. Messerle, V. Kolesnichenko, and J. Kruger, X-ray attenuation coefficients of high-atomic-number, hexanuclear transition metal cluster compounds: a new paradigm for radiographic contrast agents, Acad. Radiol, vol.7, pp.80475-80479, 2000.

N. Huby, Facile design of red-emitting waveguides using hybrid nanocomposites made of inorganic clusters dispersed in SU8 photoresist host, Opt. Mater, vol.52, pp.196-202, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01253411

M. Amela-cortes, S. Paofai, S. Cordier, H. Folliot, and Y. Molard, Tuned red NIR phosphorescence of polyurethane hybrid composites embedding metallic nanoclusters for oxygen sensing, Chem. Commun, vol.51, pp.8177-8180, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01146240

A. Beltran, M. Mikhailov, M. N. Sokolov, V. Perez-laguna, A. Rezusta et al., A photobleaching resistant polymer supported hexanuclear molybdenum iodide cluster for photocatalytic oxygenations and photodynamic inactivation of Staphylococcus aureus, J. Mater. Chem. B, vol.4, pp.5975-5979, 2016.

A. Renaud, Transparent tantalum cluster-based UV and IR blocking electrochromic devices, J. Mater. Chem. C, vol.5, pp.8160-8168, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01581225

J. F. Dechézelles, Fine tuning of emission through the engineering of colloidal crystals, Phys. Chem. Chem. Phys, vol.12, pp.993-1004, 2010.

C. Neaime, Time-gated luminescence bioimaging with new luminescent nanocolloids based on [Mo 6 I 8 (C 2 F 5 COO) 6 ] 22 metal atom clusters, Phys. Chem. Chem. Phys, vol.18, pp.166-196, 2016.

W. Chen, Embedding hexanuclear tantalum bromide cluster fTa 6 Br 12 g into SiO 2 nanoparticles by reverse microemulsion method, Heliyon, vol.4, p.654, 2018.

K. Kirakci, V. ?ícha, J. Holub, P. Kubát, and K. Lang, Luminescent hydrogel particles prepared by self-assembly of b-cyclodextrin polymer and octahedral molybdenum cluster complexes, Inorg. Chem, vol.53, pp.12-13, 2014.

Z. Li, H. Zhang, and J. Shen, Preparation of stable luminescent poly(methyl methacrylate)-europium complex nanospheres and application in the detection of hydrogen peroxide with the biocatalytic growth of gold nanoparticles, 2013.

, J. Appl. Polym. Sci, vol.128, pp.845-850

F. Meinardi, A. Colombo, K. A. Velizhanin, R. Simonutti, M. Lorenzon et al., Largearea luminescent solar concentrators based on 'Stokes-shift-engineered' nanocrystals in a masspolymerized PMMA matrix, Nat. Photonics, vol.8, pp.392-399, 2014.

N. D. Golubeva, O. A. Adamenko, G. N. Boiko, L. A. Petrova, Y. A. Olkhov et al., Synthesis, structure, and properties of new hybrid nanocomposites containing the, vol.40, pp.306-313, 2004.

Y. Molard, F. Dorson, K. A. Brylev, M. A. Shestopalov, Y. L. Gal et al., Red-NIR luminescent hybrid poly (methyl methacrylate) containing covalently linked octahedral rhenium metallic clusters, Chem. A Eur. J, vol.16, pp.5613-5619, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00829566

M. Amela-cortes, Y. Molard, S. Paofai, A. Desert, J. L. Duvail et al., , 2016.

, Versatility of the ionic assembling method to design highly luminescent PMMA

, Dalton Trans, vol.45, pp.237-245

O. A. Efremova, Photoluminescent materials based on PMMA and a highlyemissive octahedral molybdenum metal cluster complex, J. Mater. Chem. C, vol.4, pp.497-503, 2016.

M. Robin, N. Dumait, M. Amela-cortes, C. Roiland, M. Harnois et al., Direct integration of red-NIR emissive ceramic, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01716211

, Chem. Eur. J, vol.24, pp.4825-4829

M. Amela-cortes, A. Garreau, S. L. Duvail, and Y. Molard, Deep red luminescent hybrid copolymer materials with high transition metal cluster content, J. Mater. Chem. C, vol.2, pp.1545-1552, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01016524

C. Yang and R. R. Lunt, Limits of visibly transparent luminescent solar concentrators, 2017.

, Adv. Opt. Mater, vol.5, pp.1600851-1600861

T. Aubert, N. Nerambourg, N. Saito, H. Haneda, N. Ohashi et al., , 2013.

, Tunable visible emission of luminescent hybrid nanoparticles incorporating two complementary luminophores: ZnO nanocrystals and, 22 nanosized cluster units. Part. Part. Syst. Charact, vol.30, pp.90-95

L. Fei, M. Naeemi, G. Zou, and H. Luo, Chemical solution deposition of epitaxial metal-oxide nanocomposite thin films, Chem. Record, vol.13, pp.85-101, 2013.

A. K. Burrell, T. M. Mccleskey, and Q. X. Jia, Polymer assisted deposition, Chem. Commun, vol.11, pp.1271-1277, 2008.

L. Wu, D. Yang, L. Fei, Y. Huang, F. Wu et al., Dip-coating process engineering and performance optimization for three-state electrochromic devices, Nanoscale Res. Lett, vol.12, pp.390-405, 2017.

C. J. Brinker, A. J. Hurd, P. R. Schunk, G. C. Frye, and C. S. Ashley, Review of sol-gel thin film formation, 1992.

N. Sahu, B. Parija, and S. Panigrahi, Fundamental understanding and modeling of spin coating process: a review, Indian J. Phys, vol.83, pp.493-502, 2009.

M. Robin, W. Kuai, M. Amela-cortes, S. Cordier, Y. Molard et al., Epoxy based ink as versatile material for inkjet-printed devices, ACS Appl, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01205444

, Mater. Interfaces, vol.7, pp.975-996

Y. Fukada, N. Nagarajan, W. Mekky, Y. Bao, H. S. Kim et al., Electrophoretic deposition-mechanisms, myths and materials, 2004.

, J. Mater. Sci, vol.39, pp.787-801

L. Besra and M. Liu, A review on fundamentals and applications of electrophoretic deposition royalsocietypublishing, /journal/rsos R. Soc. open sci, vol.6, pp.1-61, 2007.

T. Nguyen, B. Dierre, F. Grasset, A. Renaud, S. Cordier et al., Formation mechanism of transparent Mo 6 metal atom cluster film prepared by electrophoretic deposition, J. Electrochem. Soc, vol.164, pp.412-418, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01544457

T. Nguyen, Electrophoretic coating of octahedral molybdenum metal clusters for UV/NIR light screening, vol.7, pp.114-127, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01614780

T. Nguyen, F. Grasset, B. Dierre, C. Matsunaga, S. Cordier et al., Fabrication of transparent thin film of octahedral molybdenum metal clusters by electrophoretic deposition, ECS J. Solid State Sci. Tech, vol.5, pp.178-186, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01398036

T. Nguyen, A. Renaud, B. Dierre, B. Bouteille, M. Wilmet et al., Extended study on electrophoretic deposition process of inorganic octahedral metal clusters: advanced multifunctional transparent nanocomposite thin films, Bull. Chem. Soc. Jap, vol.91, pp.1763-1774, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01997969

M. Prévôt, M. A. Cortes, S. K. Manna, R. Lefort, S. Cordier et al., Design and integration in electro-optic devices of highly efficient and robust red-NIR phosphorescent nematic hybrid liquid crystals containing, Adv. Funct. Mater, vol.25, pp.4966-4975, 2015.

K. Kirakci, P. Kubát, M. Dusek, K. Fejfarová, V. Sícha et al., A highly luminescent hexanuclear molybdenum clustera promising candidate toward photoactive materials, Eur. J. Inorg. Chem, pp.3107-3111, 2012.

A. Pénicaud and P. Batail, Novel redox properties of the paramagnetic hexanuclear niobium cluster halide [Nb 6 Cl 18 ] 32 and the preparation, structures, and conducting and magnetic properties of its one-dimensional mixed-valence tetramethyltetra(selena and thia)fulvalenium salts, Chem. Mater, vol.2, pp.123-132, 1990.

M. Vojnovic, S. Antolic, B. Kojic-prodic, N. Brnicevic, M. Miljak et al., Reactions of hexanuclear niobium and tantalum halide clusters with mercury(I1) halides. I Synthesis and structures of the semiconducting compounds, 1997.

O. , M. Nb, and T. , 12H 2, vol.623, pp.1247-1254

M. N. Sokolov, M. A. Mihailov, E. V. Peresypkina, K. A. Brylev, N. Kitamurac et al., Highly luminescent complexes [Mo 6 X 8 (n-C 3 F 7 COO) 6 ] 22 (X ¼ Br, I), Dalton Trans, vol.40, pp.6375-6377, 2011.

F. W. Koknat, J. A. Parsons, and A. Vongvusharintra, Metal cluster halide complexes. I. Efficient synthesis of hydrated hexanuclear niobium and tantalum cluster halides M 6 X 14 .8H 2 O, Inorg. Chem, vol.13, pp.1699-1702, 1974.

M. A. Mikhaylov, P. A. Abramov, V. Y. Komarova, and M. N. Sokolov, Cluster aqua/ hydroxocomplexes supporting extended hydrogen bonding networks. Preparation and structure of a unique series of cluster hydrates, Polyhedron, vol.122, pp.241-246, 2017.

X. Zarate, E. Schott, L. A. Soto, and R. Ramirez-tagle, A family of octahedral molybdenum cluster complexes [Mo 6 Cl 8 (H 2 O) n (OH) 62n ] n22 with n ¼ 0 -6 as a pH-sensors: a theoretical study, Chem. Phys. Lett, vol.567, pp.39-42, 2013.

R. E. Mccarley, B. G. Hughes, F. A. Cotton, and R. Zimmerman, The two-electron oxidation of metal atom cluster species of the type, Inorg. Chem, vol.4, pp.1491-1492, 1965.

R. A. Mackay and R. F. Schneider, Experimental evidence concerning the electronic structure of the Nb 6 Cl 12 cluster, Inorg. Chem, vol.6, pp.549-552, 1967.

B. G. Hughes, J. L. Meyer, P. B. Fleming, and R. E. Mccarley, Chemistry of polynuclear metal halides. III. Synthesis of some niobium and tantalum [M 6 X 12 ] nþ cluster derivatives, Inorg. Chem, vol.9, pp.1343-1346, 1970.

R. Quigley, P. A. Barnard, C. L. Husey, and K. R. Seddon, Electrochemical and spectroscopic characterization of fNb 6 Cl 12 g zþ chloride clusters in the aluminum chloride-1-methyl-3-ethylimidazolium chloride molten salt, Inorg. Chem, vol.31, pp.1255-1261, 1992.

N. Bmicevic, D. Nothig-hus, B. Kojic-prodic, Z. Ruzic-toros, Z. Danilovic et al., Synthesis and structures of hexanuclear tantalum clusters with the, Inorg. Chem, vol.31, pp.3924-3928, 1992.

G. B. Smith, C. A. Deller, P. D. Swift, A. Gentle, P. D. Garrett et al., Nanoparticle-doped polymer foils for use in solar control glazing, J. Nanopart. Res, vol.4, pp.157-165, 2002.

S. Schelm, G. B. Smith, P. D. Garrett, and W. K. Fisher, Tuning the surface-plasmon resonance in nanoparticles for glazing applications, J. Appl. Phys, vol.97, pp.124314-124322, 2005.

N. L. Stokes, J. A. Edgar, A. M. Mcdonagh, and M. B. Cortie, Spectrally selective coatings of gold nanorods on architectural glass, J. Nanopart. Res, vol.12, pp.2821-2830, 2010.

M. Carboni, M. Carravetta, X. L. Zhang, and E. Stulz, Efficient NIR light blockage with matrix embedded silver nanoprism thin films for energy saving window coating, J. Mater. Chem. C, vol.4, pp.1584-1588, 2016.

D. Liu, Y. C. Lunt, and R. R. , Halide perovskites for selective ultraviolet-harvesting transparent photovoltaics, vol.2, pp.1-11, 2018.

T. Liu, Smart window coating based on F-TiO 2 -K x WO 3 nanocomposites with heat shielding, ultraviolet isolating, hydrophilic and photocatalytic performance, /srep27373) royalsocietypublishing.org/journal/rsos R. Soc. open sci, vol.6, p.181647, 2016.