An Alternative Approach towards Poly-?-Caprolactone through a Chemoenzymatic Synthesis: Combined Hydrogenation, Bio-Oxidations and Polymerization without the Isolation of Intermediates, Green Chem, vol.19, issue.5, pp.1286-1290, 2017. ,
Caprolactam from Renewable Resources: Catalytic Conversion of 5-Hydroxymethylfurfural into Caprolactone, Angew. Chem. Int. Ed, vol.50, issue.31, pp.7083-7087, 2011. ,
URL : https://hal.archives-ouvertes.fr/hal-01664689
Synthesis of Polycaprolactone: A Review, Chem. Soc. Rev, vol.38, issue.12, pp.3484-3504, 2009. ,
Lactic Acid)-Mass Production, Processing, Industrial Applications, and End of Life, Adv. Drug Deliv. Rev, vol.107, pp.333-366, 2016. ,
New Emerging Trends in Synthetic Biodegradable PolymersPolylactide: A Critique, Eur. Polym. J, vol.43, issue.10, pp.4053-4074, 2007. ,
Poly(?-Caprolactone) Based Formulations for Drug Delivery and Tissue Engineering: A Review, J. Controlled Release, vol.2012, issue.1, pp.15-33 ,
Biocompatible Hybrid Allyl 2-Cyanoacrylate and Hydroxyapatite Mixed for Bio-Glue, J. Adhes. Sci. Technol, vol.2017, issue.12, pp.1328-1337 ,
Lactic Acid): Plasticization and Properties of Biodegradable Multiphase Systems, Polymer, vol.42, issue.14, pp.86-92, 2001. ,
Biopolymers: Overview of Several Properties and Consequences on Their Applications, Polym. Test, vol.21, issue.4, pp.107-113, 2002. ,
Synthesis of Poly(Lactide)s with Modified Thermal and Mechanical Properties, Macromol. Rapid Commun, vol.2010, issue.22, pp.1923-1937 ,
Sustained Drug Delivery Systems. I. The Permeability of Poly(?-Caprolactone), Poly(DL-Lactic Acid), and Their Copolymers, J. Biomed. Mater. Res, vol.13, issue.3, pp.497-507, 1979. ,
,
Aliphatic Polyesters. I. The Degradation of Poly(?-Caprolactone) in Vivo, J. Appl. Polym. Sci, vol.26, issue.11, pp.3779-3787, 1981. ,
Aliphatic Polyesters II. The Degradation of Poly (DL-Lactide), Poly (?-Caprolactone), and Their Copolymers in Vivo, Biomaterials, vol.1981, issue.4, pp.215-220 ,
High Molecular Weight Copolymers of L-Lactide and ?-Caprolactone as Biodegradable Elastomeric Implant Materials, Polym. Bull, vol.25, issue.3, pp.327-333, 1991. ,
Cartilage Regeneration with Highly-Elastic Three-Dimensional Scaffolds Prepared from Biodegradable Poly(LLactide-Co-?-Caprolactone), Biomaterials, vol.29, issue.35, pp.4630-4636, 2008. ,
,
,
Lotus-Leaf-like Structured Heparin-Conjugated Poly(LLactide-Co-?-Caprolactone) as a Blood Compatible Material, Colloids Surf. B Biointerfaces, vol.103, pp.463-467, 2013. ,
Shape-Memory Effect by Specific Biodegradable Polymer Blending for Biomedical Applications: Shape-Memory Effect by Specific Biodegradable Polymer, Macromol. Biosci, vol.14, issue.5, pp.667-678, 2014. ,
TGF-? 3 Encapsulated PLCL Scaffold by a Supercritical CO 2 -HFIP Co-Solvent System for Cartilage Tissue Engineering, J. Controlled Release, vol.206, pp.101-107, 2015. ,
Compatibilized Polymer Blends Based on PDLLA and PCL for Application in Bioartificial Liver, vol.9, pp.1527-1534, 2008. ,
Catalytic Metal-Based Systems for Controlled Statistical Copolymerisation of Lactide with a Lactone, Polym. Chem, vol.2018, issue.19, pp.2517-2531 ,
Guanidine and Amidine Organocatalysts for Ring-Opening Polymerization of Cyclic Esters, Macromolecules, vol.39, issue.25, pp.8574-8583, 2006. ,
Phosphazene-Catalyzed RingOpening Polymerization of ?-Caprolactone: Influence of Solvents and Initiators, Polym Chem, vol.5, issue.18, pp.5471-5478, 2014. ,
Benzo-12-Crown-4 Modified NHeterocyclic Carbene for Organocatalyst: Synthesis, Characterization and Degradation of Block Copolymers of ?-Caprolactone with L -Lactide, J. Macromol. Sci. Part A, vol.53, issue.6, pp.374-381, 2016. ,
Cationic Copolymerization of ?-Caprolactone and L,L-Lactide by an Activated Monomer Mechanism, J. Polym. Sci. Part Polym. Chem, issue.24, pp.7071-7081, 2006. ,
Polyester Oligodiols by Cationic AM Copolymerization of L,LLactide and ?-Caprolactone Initiated by Diols, J. Polym. Sci. Part Polym. Chem, issue.14, pp.3090-3097, 2007. ,
Controlled Ring-Opening Polymerization of Cyclic Esters with Phosphoric Acid as Catalysts, Colloid Polym. Sci, vol.2013, issue.9, pp.2155-2162 ,
Ring-Opening Block Copolymerization of ?-Caprolactone with L-Lactide Catalyzed by N-Heterocyclic Carbenes: Synthesis, Characteristics, Mechanism, Macromol. Res, vol.22, issue.6, pp.600-605, 2014. ,
,
H-Bonding Organocatalysts for the Living, Solvent-Free RingOpening Polymerization of Lactones: Toward an All-Lactones, All-Conditions Approach, Macromolecules, vol.2017, issue.22, pp.8948-8954 ,
,
Extending the Scope of Benign and Thermally Stable Organocatalysts: Application of Dibenzoylmethane for the Bulk Copolymerization of L-Lactide and ?-Caprolactone, J. Polym. Sci. Part Polym. Chem, vol.56, issue.5, pp.475-479, 2018. ,
URL : https://hal.archives-ouvertes.fr/hal-01919770
Organocatalytic Copolymerization of Mixed Type Monomers, Chin. J. Polym. Sci, vol.2017, issue.5, pp.581-601 ,
Polymerization Temperature Effects on the Properties of L-Lactide and ?-Caprolactone Copolymers, Polym. Bull, vol.25, issue.3, pp.335-341, 1991. ,
Macromolecular Engineering of Polylactones and Polylactides. 7. Structural Analysis of Copolyesters of ?-Caprolactone and L-or D,L-Lactide Initiated by Triisopropoxyaluminum, Macromolecules, vol.25, issue.1, pp.37-44, 1992. ,
Synthesis and Characterization of Highly Random Copolymer of ?-Caprolactone and D,L-Lactide Using Rare Earth Catalyst, J. Polym. Sci. Part Polym. Chem, vol.34, issue.9, pp.1799-1805, 1996. ,
, , vol.34, 19960715.
Ring-Opening Copolymerization of L-Lactide with ?-Caprolactone Initiated by Diphenylzinc, Polym. Int, vol.55, issue.9, pp.1049-1056, 2006. ,
,
Effect of the Configuration of the Active Center on Comonomer Reactivities: The Case of ?-Caprolactone/L,L-Lactide Copolymerization, Angew. Chem. Int. Ed, vol.47, issue.47, pp.9088-9091, 2008. ,
Living Ring-Opening Homo-and Copolymerization of ?-Caprolactone and L,L-Lactides by ,
, Salicylaldiminato)Aluminum Compounds. Macromolecules, vol.42, issue.16, pp.6056-6062, 2009.
Microstructure Analysis and Thermal Properties of LLactide/?-Caprolactone Copolymers Obtained with Magnesium Octoate, Polymer, vol.50, issue.6, pp.1423-1429, 2009. ,
Random Copolymerization of ?-Caprolactone with Lactide Using a Homosalen?Al Complex, J. Am. Chem. Soc, issue.6, pp.1750-1751, 2010. ,
Random Copolymerization of ?-Caprolactone and Lactides Promoted by Pyrrolylpyridylamido Aluminum Complexes, Macromolecules, vol.2012, issue.21, pp.8614-8620 ,
Controlled Random Copolymerization of Rac-Lactide and ?-Caprolactone by Well-Designed Phenoxyimine Al Complexes, J. Polym. Sci. Part Polym. Chem, vol.56, issue.6, pp.611-617, 2018. ,
Copolymerization of Cyclic Esters Controlled by Chiral NNO-Scorpionate Zinc Initiators, Organometallics, vol.2016, issue.2, pp.189-197 ,
Random Copolymerization of ?-Caprolactone and L-Lactide with Molybdenum Complexes, Polym. Bull, vol.71, issue.4, pp.989-999, 2014. ,
,
Organocatalysis Paradigm Revisited: Are Metal-Free Catalysts Really Harmless?, vol.16, pp.507-514, 2015. ,
Organic Catalysis for Ring-Opening Polymerization, ACS Macro Lett, vol.2012, issue.12, pp.1409-1412 ,
Organocatalysis: Opportunities and Challenges for Polymer Synthesis, Macromolecules, vol.2010, issue.5, pp.2093-2107 ,
Organocatalytic Ring-Opening Polymerization, Chem. Rev, vol.107, issue.12, pp.5813-5840, 2007. ,
NHCs) as Organocatalysts and Structural Components in Metal-Free Polymer Synthesis, Chem. Soc. Rev, vol.42, issue.5, pp.2142-2172, 2013. ,
Hydrogen-Bonding Organocatalysts for Ring-Opening Polymerization, Green Chem, vol.16, issue.4, pp.1687-1699, 2014. ,
,
Update and Challenges in Organo-Mediated Polymerization Reactions, Prog. Polym. Sci, vol.56, pp.64-115, 2016. ,
URL : https://hal.archives-ouvertes.fr/hal-01366512
N-Heterocyclic Carbenes for Metal-Free Polymerization Catalysis: An Update: N-Heterocyclic Carbenes for Metal-Free Polymerization Catalysis, Polym. Int, vol.65, issue.1, pp.16-27, 2016. ,
Degradation of Benzoic Acid and Its Derivatives in Subcritical Water, J. Chromatogr. A, issue.15, pp.2146-2152, 2011. ,
,
Benzoic Acid-Organocatalyzed Ring-Opening (Co)Polymerization (ORO(c)P) of L-Lactide and ?-Caprolactone under Solvent-Free Conditions: From Simplicity to Recyclability, Green Chem, issue.23, pp.5385-5396, 2018. ,
URL : https://hal.archives-ouvertes.fr/hal-01919789
Nonlinear Regression by Visualization of the Sum of Residual Space Applied to the Integrated Copolymerization Equation with Errors in All Variables. I. Introduction of the Model, Simulations and Design of Experiments, J. Polym. Sci. Part Polym. Chem, vol.37, issue.20, pp.3793-3803, 1999. ,
, , vol.37, 19991015.
Living Spontaneous Gradient Copolymers of Acrylic Acid and Styrene: One-Pot Synthesis of PH-Responsive Amphiphiles, Polym Chem, vol.2010, issue.3, pp.326-332 ,
Molecular Self-Diffusion Coefficients in Fourier Transform Nuclear Magnetic Resonance Spectrometric Analysis of Complex Mixtures, Anal. Chem, issue.13, pp.2135-2137, 1981. ,
Diffusion Ordered Nuclear Magnetic Resonance Spectroscopy: Principles and Applications, Prog. Nucl. Magn. Reson. Spectrosc, vol.34, issue.3-4, pp.3-5, 1999. ,
The Mutual Diffusion of Light and Heavy Water, J. Phys. Chem, vol.64, issue.12, pp.1914-1917, 1960. ,
Calibration in Accurate Spin-Echo Self-Diffusion Measurements Using 1H and Less-Common Nuclei, J. Magn. Reson, vol.92, issue.1, pp.115-125, 19691991. ,
Thermal Degradation of Poly(L-Lactide): Accelerating Effect of Residual DBU-Based Organic Catalysts, Polym. Degrad. Stab, vol.96, issue.5, pp.739-744, 2011. ,
,
Thermal Degradation Behaviour of Poly(Lactic Acid) Stereocomplex, Polym. Degrad. Stab, vol.86, issue.2, pp.197-208, 2004. ,
Copolymerization. I. A Basis for Comparing the Behavior of Monomers in Copolymerization; The Copolymerization of Styrene and Methyl Methacrylate, J. Am. Chem. Soc, vol.66, issue.9, pp.1594-1601, 1944. ,
,
Coordination Polymerization of Lactides, 2. Microstructure Determination of Poly[(L,L-Lactide)-Co-(?-Caprolactone)] with 13C Nuclear Magnetic Resonance Spectroscopy, Makromol. Chem, issue.8, pp.1777-1787, 1991. ,
Coordination Polymerization of Lactides, 4. The Role of Transesterification in the Copolymerization of L,L-Lactide and ?-Caprolactone, Makromol. Chem, vol.194, issue.3, pp.913-925, 1993. ,
Revealing the Cytotoxicity of Residues of Phosphazene Catalysts Used for the Synthesis of Poly(Ethylene Oxide), vol.18, pp.3233-3237, 2017. ,
Inflammatory Cytokines Promote the Retrodifferentiation of Tumor-Derived Hepatocyte-like, Cells to Progenitor Cells: HEPATOLOGY, vol.00, issue.X, pp.2077-2090, 2014. ,
URL : https://hal.archives-ouvertes.fr/hal-01134747
Transdifferentiation of Hepatocyte-like Cells from the Human Hepatoma HepaRG Cell Line through Bipotent Progenitor, Hepatology, vol.45, issue.4, pp.957-967, 2007. ,
URL : https://hal.archives-ouvertes.fr/hal-00690471
Expression Of Cytochromes P450, Conjugating Enzymes And Nuclear Receptors In Human Hepatoma Heparg Cells, Drug Metab. Dispos, vol.34, issue.1, pp.75-83, 2005. ,
URL : https://hal.archives-ouvertes.fr/hal-00702085
Production of Chlorzoxazone Glucuronides via Cytochrome P4502E1 Dependent and Independent Pathways in Human Hepatocytes, Arch. Toxicol, vol.92, issue.10, pp.3077-3091, 2018. ,
URL : https://hal.archives-ouvertes.fr/hal-01863847
Long-Term Functional Stability of Human HepaRG Hepatocytes and Use for Chronic Toxicity and Genotoxicity Studies, Drug Metab. Dispos, vol.36, issue.6, pp.1111-1118, 2008. ,
Evaluation of Genotoxicity Using Automated Detection of ?H2AX in Metabolically Competent HepaRG Cells, Mutagenesis, 2015. ,