CHAPTER 4 Secondary (Agostic Si-H/Electrostatic C-F) interactions in alkaline earth-based catalysts

Yann Sarazin (1) , J.-F. Carpentier (1)

1 ISCR - Institut des Sciences Chimiques de Rennes

The design and implementation of a selection of homogeneous alkaline earth (Ae) catalysts and precatalysts for hydroamination and hydrophosphination of olefins and for ring-opening polymerization of cyclic esters are surveyed. Emphasis is placed on the three large elements calcium, strontium and barium. The role of Ae⋯H–Si and Ae⋯F–C noncovalent interactions in the stabilization of (pre)catalysts is highlighted.

Domaines: Chimie

Yann Sarazin, J.-F. Carpentier. CHAPTER 4 Secondary (Agostic Si-H/Electrostatic C-F) interactions in alkaline earth-based catalysts. Noncovalent Interactions in Catalysis, 2019-January (37), Royal Society of Chemistry, pp.94-121, 2019, 9781788017237. ⟨10.1039/9781788016490-00094⟩. ⟨hal-02122160⟩