Aminofluoroalkoxide amido and boryloxo lead(ii) complexes

Adrian-Alexandru Someşan (1) , Thierry Roisnel (2) , Vincent Dorcet (2) , Cristian Silvestru (1) , Yann Sarazin (2)

1 UBB - Babes-Bolyai University [Cluj-Napoca]
2 ISCR - Institut des Sciences Chimiques de Rennes

We report here on the utilisation of a readily available bidentate aminofluoroalkoxide in lead(II) chemistry. Stable heteroleptic three-coordinate complexes can be produced in high yields, including a convenient amido synthetic precursor and a rare case of Pb II-boryloxide.

Domaines: Chimie de coordination

Adrian-Alexandru Someşan, Thierry Roisnel, Vincent Dorcet, Cristian Silvestru, Yann Sarazin. Aminofluoroalkoxide amido and boryloxo lead(ii) complexes. Dalton Transactions, 2019, 48 (27), pp.9944-9948. ⟨10.1039/c9dt02110h⟩. ⟨hal-02179649⟩