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Journal articles
Acyl-Imidazoles A Privileged Ester Surrogate for Enantioselective Synthesis
Abstract : Since the first report by Evans in asymmetric Friedel‐Crafts reactions, the use of acyl‐imidazoles has blossomed as powerful ester/amide surrogates. The imidazole scaffold indeed displays stability and special activation features allowing both better reactivity and selectivity in traditional ester/amide functionalizations: α‐(enolate chemistry), β‐(conjugate additions), α,β‐(cycloadditions) or γ/δ‐(vinylogous). An overview of the contemporary and growing interest in acyl‐imidazoles in metal‐ and organo‐catalyzed transformations (bio‐hybrid catalytic systems will be fully described in a back‐to‐back Minireview) will be highlighted. Moreover, post‐functionalization expediencies are also going to be discussed in this Minireview.
Cited literature [83 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-02181832
Contributor : Laurent Jonchère <>
Submitted on : Thursday, November 7, 2019 - 12:38:54 PM
Last modification on : Tuesday, January 12, 2021 - 4:44:49 PM
Long-term archiving on: : Saturday, February 8, 2020 - 11:53:40 PM
Contributor : Laurent Jonchère <>
Submitted on : Thursday, November 7, 2019 - 12:38:54 PM
Last modification on : Tuesday, January 12, 2021 - 4:44:49 PM
Long-term archiving on: : Saturday, February 8, 2020 - 11:53:40 PM
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