In contrast, 385 and 387 were was highly effective in the stereocontrol of helical chirality in Suzuki-Miyaura coupling (SMC) reactions as illustrated in entries 13-14 of Table 31, with the Suzuki coupling between diisopropyl (1-bromonaphthalen-2-yl) phosphonate 429 and o-tolylboronic acid 429' (up to 99% ee for product 430). The stereoselectivity of the reactions was elucidated with the help of DFT calculations, 99% yield with only 71% ee. Similarly, (M)-385 was also highly effective in the asymmetric allylation of indoles with 1,3-diphenylallyl acetate (up to 99% ee, entry 11), and in the etherification of alcohols (up to 96% ee, entry 12), 2003. ,
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, He is a PhD student since February 2016, preparing his research doctorate between the University of Rennes 1 in France and the University of Gabés in Tunisia and under the joint supervision of Prof. B. Jamoussi and Dr, Biographies Kais Dhbaibi obtained his Engineer degree in analytical chemistry in 2015 from Tunis-El Manar University (Tunisia)
After a one-year postdoctoral fellow at the University of Oxford with Prof. Harry L. Anderson on the synthesis of porphyrin nanorings, he was recruited as CNRS researcher at the "Institut des Sciences Chimiques de Rennes, 2019, he received the Dina Surdin prize from the Société Chimique de France. His research focuses on the design of chiral organic molecules with intense chiroptical properties ,
Her group is dealing with many fields related to chirality (organometallic and heteroatomic helicenes, fundamental aspects of chirality such as parity violation effects, chiroptical activity such as electronic and vibrational circular dichroism and circularly polarized luminescence). She has published more than 110 papers and a French monography on the Stereochemistry of Chiral Molecules, Dr. Jeanne Crassous (born Costante) received her PhD in 1996 under supervision of Prof. André collet, 2005. ,