Tailoring heterometallic cluster functional building blocks synthesis, separation, structural and DFT studies of [Re6-xMoxSe8(CN)6]n

Abstract : Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n- (x= 2, 3; n= 4, 5) were obtained as individual salts. Their isomeric composition and bond lengths distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS and DFT calculations.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-02280841
Contributor : Laurent Jonchère <>
Submitted on : Friday, September 6, 2019 - 4:19:10 PM
Last modification on : Saturday, September 7, 2019 - 1:24:05 AM

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V K Muravieva, y M Gayfulin, C Prestipino, P Lemoine, M R Ryzhikov, et al.. Tailoring heterometallic cluster functional building blocks synthesis, separation, structural and DFT studies of [Re6-xMoxSe8(CN)6]n. Chemistry, 2019, ⟨10.1002/chem.201903321⟩. ⟨hal-02280841⟩

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