Stabilization of a new nanocomposite family by reduction of gold nanoclusters with electron-reservoir complexes
Abstract
Four stable 19-electron Fe and Co sandwich electron-reservoirs and three hydride reservoir complexes reduce the prototypal nanocluster Au-25(SR)(18) (R = CH2CH2Ph) leading to a largely increased kinetic stabilization of the anionic nanocluster form compared to previously known nanocluster anion salts; these salts represent new and robust nanocomposite anionic gold clusters with 18-electron sandwich complexes as counter cations.
Domains
Chemical Sciences
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Astruc_et al_2019_Stabilization of a new nanocomposite family_accepted.pdf (1.54 Mo)
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Astruc_et al_2019_Stabilization of a new nanocomposite family_supplementary material.pdf (3.37 Mo)
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