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Stabilization of a new nanocomposite family by reduction of gold nanoclusters with electron-reservoir complexes

Abstract : Four stable 19-electron Fe and Co sandwich electron-reservoirs and three hydride reservoir complexes reduce the prototypal nanocluster Au-25(SR)(18) (R = CH2CH2Ph) leading to a largely increased kinetic stabilization of the anionic nanocluster form compared to previously known nanocluster anion salts; these salts represent new and robust nanocomposite anionic gold clusters with 18-electron sandwich complexes as counter cations.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-02303388
Contributor : Laurent Jonchère <>
Submitted on : Monday, December 2, 2019 - 11:53:21 AM
Last modification on : Wednesday, December 4, 2019 - 10:44:26 AM
Long-term archiving on: : Tuesday, March 3, 2020 - 4:25:40 PM

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Fangyu Fu, Anthony Dedieu, Wenjuan Wang, Tao Chen, Yongbo Song, et al.. Stabilization of a new nanocomposite family by reduction of gold nanoclusters with electron-reservoir complexes. Chemical Communications, Royal Society of Chemistry, 2019, 55 (69), pp.10277-10280. ⟨10.1039/c9cc05260g⟩. ⟨hal-02303388⟩

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