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Journal articles
Practical Chromatography-Free Synthesis of 2-Iodo-N,N-diisopropylferrocenecarboxamide and Further Transformations
Abstract : An efficient procedure able to deliver grams of racemic and enantioenriched 2-iodo- N , N -diisopropylferrocenecarboxamide without chromatographic purification was developed. To introduce the halogen, two procedures, one using the n BuLi-TMEDA chelate and one using a lithium amide in the presence of ZnCl (2) as in situ trap were developed. Further functionalization by Suzuki-Miyaura and Ullman-type cross-couplings was investigated to access a variety of ferrocene derivatives.
Cited literature [2 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-02303395
Contributor : Laurent Jonchère <>
Submitted on : Monday, November 18, 2019 - 11:52:13 AM
Last modification on : Wednesday, April 7, 2021 - 3:18:12 PM
Contributor : Laurent Jonchère <>
Submitted on : Monday, November 18, 2019 - 11:52:13 AM
Last modification on : Wednesday, April 7, 2021 - 3:18:12 PM