When a red NIR emissive Cs2[Mo6Br14] interacts with an active diureasil-PEO matrix design of tunable and white light emitting hybrid material

Eduardo Ferreira Molina (1) , Natana Aparecida Martins de Jesus (1) , Serge Paofai (2, 3) , Peter Hammer (4) , Maria Amela-Cortes (2) , Malo Robin (2, 3) , Stéphane Cordier (2, 3) , Yann Molard (2, 3)

1 Universidade de Franca
2 ISCR - Institut des Sciences Chimiques de Rennes
3 ScanMAT - Synthèse Caractérisation Analyse de la Matière
4 UNESP - Universidade Estadual Paulista Júlio de Mesquita Filho = São Paulo State University

Hybrid materials that combine diureasil matrices and octahedral molybdenum clusters have been synthesized to design lead-, cadmium- and rare-earth-free emitters for lighting or optoelectronic applications. This association leads to homogeneous and stable hybrids, for which the emission color can be tailored in the entire visible range, including white light; this is thanks to effective energy transfers from the host to the nanocluster.

Keywords: metal clusters; luminescence; energy transfers; hybrid materials

Domains: Chemical Sciences; Material chemistry

Eduardo Ferreira Molina, Natana Aparecida Martins de Jesus, Serge Paofai, Peter Hammer, Maria Amela-Cortes, et al.. When a red NIR emissive Cs2[Mo6Br14] interacts with an active diureasil-PEO matrix design of tunable and white light emitting hybrid material. Chemistry - A European Journal, 2019, 25 (67), pp.15248-15251. ⟨10.1002/chem.201903892⟩. ⟨hal-02307028⟩