Skip to Main content Skip to Navigation
Journal articles

Visible Light Induced Rhodium(I)-Catalyzed C-H Borylation

Abstract : An efficient visible light induced rhodium(I)-catalyzed regioselective borylation of aromatic C-H bonds is reported. The photocatalytic system is based on a single NHC-Rh complex capable of both harvesting visible light and enabling the bond breaking/forming at room temperature. The chelating nature of the NHC-carboxylate ligand was critical to ensure the stability of the Rh complex and to provide excellent photocatalytic activities. Experimental mechanistic studies evidenced a photooxidative ortho C-H bond addition upon irradiation with blue LEDs, leading to a cyclometalated Rh -hydride intermediate.
Document type :
Journal articles
Complete list of metadata

Cited literature [42 references]  Display  Hide  Download
Contributor : Laurent Jonchère Connect in order to contact the contributor
Submitted on : Monday, December 16, 2019 - 11:46:02 AM
Last modification on : Monday, July 4, 2022 - 10:18:55 AM
Long-term archiving on: : Tuesday, March 17, 2020 - 5:20:07 PM


Baslé et al-Visible Light Ind...
Files produced by the author(s)



Jompol Thongpaen, Romane Manguin, Vincent Dorcet, Thomas Vives, Carine Guyard-Duhayon, et al.. Visible Light Induced Rhodium(I)-Catalyzed C-H Borylation. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2019, 58 (43), pp.15244-15248. ⟨10.1002/anie.201905924⟩. ⟨hal-02307077⟩



Record views


Files downloads