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Journal articles
Metal-free propargylation/aza-annulation approach to substituted beta-carbolines and evaluation of their photophysical properties
Abstract : An efficient acid-catalyzed propargylation/aza-annulation sequence was developed under metal-free reaction conditions, thus leading to a one-pot synthesis of a variety of substituted beta-carbolines starting from propargylic alcohols and indole 2-carbonyls. This versatile strategy was further extended to the synthesis of 5-azaindoles and 5-azabenzothiazoles. Optical properties suggested that manipulation of electron donor and acceptor moieties on beta-carbolines has an impact on their ground and excited state electronic behavior. This leads to blue or green emission and should facilitate the development of organic light emitting diodes (OLEDs). Electrochemical and stability studies revealed that 4a-6 shows ease of redox activity and photostability during illumination.
https://hal-univ-rennes1.archives-ouvertes.fr/hal-02391906
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, December 3, 2019 - 5:26:25 PM
Last modification on : Tuesday, January 12, 2021 - 4:41:53 PM
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, December 3, 2019 - 5:26:25 PM
Last modification on : Tuesday, January 12, 2021 - 4:41:53 PM