Skip to Main content Skip to Navigation
Journal articles

Electronic Communication within Flexible Bisdithiolene Ligands Bridging Molybdenum Centers

Abstract : Bimetallic molybdenum dithiolene complexes involving two flexible ditopic conjugated linkers have been synthesized and characterized by electrochemistry, spectroelectrochemistry, and single crystal X-ray diffraction. The electrochemical investigations evidence that the two metallic bisdithiolene moieties are electronically coupled in the monocationic state. DFT and TDDFT calculations further suggest that the intervalence charge transfer within both monocations is essentially localized on the ligand and can be described as an intraligand charge transfer (ILCT).
Document type :
Journal articles
Complete list of metadatas

Cited literature [39 references]  Display  Hide  Download

https://hal-univ-rennes1.archives-ouvertes.fr/hal-02438532
Contributor : Laurent Jonchère <>
Submitted on : Friday, February 21, 2020 - 11:33:03 AM
Last modification on : Friday, July 10, 2020 - 4:24:45 PM
Long-term archiving on: : Friday, May 22, 2020 - 4:45:42 PM

File

Vacher-2019-Electronic Communi...
Files produced by the author(s)

Identifiers

Citation

Antoine Vacher, Yann Le Gal, Thierry Roisnel, Vincent Dorcet, Thomas Devic, et al.. Electronic Communication within Flexible Bisdithiolene Ligands Bridging Molybdenum Centers. Organometallics, American Chemical Society, 2019, 38 (22), pp.4399-4408. ⟨10.1021/acs.organomet.9b00485⟩. ⟨hal-02438532⟩

Share

Metrics

Record views

95

Files downloads

95