, Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis, 2015; (b) M. Schröder, Functional Metal-Organic Frameworks: Gas storage, Separation and Catalysis, 2010.

. R. Macgillivray-;-d)-d.-farrusseng-;-e)-s, S. M. Batten, D. R. Neville, ). L. Turner-;-f, M. G. Sun et al., Coordination Polymers: Design, analysis and application, Metal-Organic Frameworks: Applications from Catalysis to Gas Storage, vol.55, pp.124-144, 2009.

J. Zhou, ). B. Am, Y. Li, A. Zhao, J. Kirchon et al., J. Am. Chem. Soc, vol.140, pp.6822-6826, 2018.

L. Xie, J. Liang, J. Song, C. Yin, W. S. Huang-;-b)-r et al., Sol. Energy Mater. Sol. Cells, vol.18, pp.3848-3853, 1818.

F. Schlüter, K. Riehemann, N. S. Kehr, S. Quici, C. G. Daniliuc et al., A highly fluorescent water soluble spirobifluorene dye with a large Stokes shift: synthesis, characterization and bio-applications, Chemical Communications, vol.54, issue.6, pp.642-645, 2018.

C. Poriel, Y. Ferrand, P. L. Maux, J. Rault-berthelot, G. Simonneaux et al., Tetrahedron Lett, vol.44, pp.5086-5095, 2003.

Y. Ferrand, C. Poriel, P. Le-maux, J. Rault-berthelot, and G. Simonneaux, Asymmetric heterogeneous carbene transfer catalyzed by optically active ruthenium spirobifluorenylporphyrin polymers, Tetrahedron: Asymmetry, vol.16, issue.8, pp.1463-1472, 2005.

K. Wong, Y. Liao, Y. Peng, C. Wang, S. Lin et al., A Novel Right-Angled Ligand that Forms Polymeric Metal?Organic Frameworks with Nanometer-Sized Square Cavities, Crystal Growth & Design, vol.5, issue.2, pp.667-671, 2005.

P. K. Clews, R. E. Douthwaite, B. M. Kariuki, T. Moore, and M. Taboada, Layered Compounds Incorporating 9,9?-Spirobifluorene: Hydrogen-Bonded and Metal?Organic Networks Derived from 9,9?-Spirobifluorene-2,2?,7,7?-tetracarboxylic Acid, Crystal Growth & Design, vol.6, issue.9, pp.1991-1994, 2006.

C. S. Collins, D. Sun, W. Liu, J. Zuo, and H. Zhou, Reaction-condition-controlled formation of secondary-building-units in three cadmium metal?organic frameworks with an orthogonal tetrakis(tetrazolate) ligand, Journal of Molecular Structure, vol.890, issue.1-3, pp.163-169, 2008.

L. An, H. Wang, F. Xu, X. Wang, F. Wang et al., Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers, Inorganic Chemistry, vol.55, issue.24, pp.12923-12929, 2016.

H. Li, X. Fang, S. Ma, Y. Niu, X. Zhao et al., A two-dimensional porous framework: solvent-induced structural transformation and selective adsorption towards malachite green, Dalton Transactions, vol.46, issue.26, pp.8350-8353, 2017.

H. J. Park, J. K. Jang, S. Kim, J. Ha, D. Moon et al., Synthesis of a Zr-Based Metal?Organic Framework with Spirobifluorenetetrabenzoic Acid for the Effective Removal of Nerve Agent Simulants, Inorganic Chemistry, vol.56, issue.20, pp.12098-12101, 2017.

X. Huang, Q. Li, X. Xiao, S. Jia, Y. Li et al., Nonlinear-Optical Behaviors of a Chiral Metal?Organic Framework Comprised of an Unusual Multioriented Double-Helix Structure, Inorganic Chemistry, vol.57, issue.11, pp.6210-6213, 2018.

X. Fang, L. Wang, X. He, J. Xu, and Z. Duan, A 3D Calcium Spirobifluorene Metal?Organic Framework: Single-Crystal-to-Single-Crystal Transformation and Toluene Detection by a Quartz Crystal Microbalance Sensor, Inorganic Chemistry, vol.57, issue.4, pp.1689-1692, 2018.

L. M. Aguirre-díaz, N. Snejko, M. Iglesias, F. Sánchez, E. Gutiérrez-puebla et al., Efficient Rare-Earth-Based Coordination Polymers as Green Photocatalysts for the Synthesis of Imines at Room Temperature, Inorganic Chemistry, vol.57, issue.12, pp.6883-6892, 2018.

F. Moreau, N. Audebrand, C. Poriel, V. Moizan-baslé, and J. Ouvry, A 9,9?-spirobifluorene based Metal?Organic Framework: synthesis, structure analysis and gas sorption properties, Journal of Materials Chemistry, vol.21, issue.46, p.18715, 2011.

. Bruker-nonius, Bruker AXS announces SMART BREEZE?, Anti-Corrosion Methods and Materials, vol.53, issue.1, 2006.

G. M. Sheldrick, SADABS version 2.03, 2001.

. Bruker-nonius, Bruker AXS launches SuperSpeedSolutions, III-Vs Review, vol.17, issue.1, p.29, 2004.

R. H. Blessing, An empirical correction for absorption anisotropy, Acta Crystallographica Section A Foundations of Crystallography, vol.51, issue.1, pp.33-38, 1995.

A. Altomare, M. C. Burla, M. Camalli, G. L. Cascarano, C. Giacovazzo et al., SIR97: a new tool for crystal structure determination and refinement, Journal of Applied Crystallography, vol.32, issue.1, pp.115-119, 1999.

G. M. Sheldrick, SHELXL-2018: Programs for Crystal Structure Refinement, 2018.

A. L. Spek, . Platon, . Multipurpose-crystallographic, and . Tool, , 2002.

K. Brandenburg, M. Berndt, and D. , , 2001.

D. Thirion, J. Rault-berthelot, L. Vignau, and C. Poriel, Synthesis and Properties of a Blue Bipolar Indenofluorene Emitter Based on a D-?-A Design, Organic Letters, vol.13, issue.16, pp.4418-4421, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00632543

K. Sumi and G. Konishi, Synthesis of a Highly Luminescent Three-Dimensional Pyrene Dye Based on the Spirobifluorene Skeleton, Molecules, vol.15, issue.11, pp.7582-7592, 2010.

H. Li, M. Eddaoudi, T. L. Groy, and O. M. Yaghi, Establishing Microporosity in Open Metal?Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate), Journal of the American Chemical Society, vol.120, issue.33, pp.8571-8572, 1998.

M. Köberl, M. Cokoja, W. A. Herrmann, and F. E. Kühn, From molecules to materials: Molecular paddle-wheel synthons of macromolecules, cage compounds and metal?organic frameworks, Dalton Transactions, vol.40, issue.26, p.6834, 2011.

C. Quinton, L. Sicard, N. Vanthuyne, O. Jeannin, and C. Poriel, Confining Nitrogen Inversion to Yield Enantiopure Quinolino[3,2,1-k]Phenothiazine Derivatives, Advanced Functional Materials, vol.28, issue.39, p.1803140, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01902029

D. J. Tranchemontagne, J. L. Mendoza-cortés, M. O?keeffe, and O. M. Yaghi, Secondary building units, nets and bonding in the chemistry of metal?organic frameworks, Chemical Society Reviews, vol.38, issue.5, p.1257, 2009.