Straightforward Preparation of a Solid-state Luminescent Cu-11 Polymetallic Assembly via Adaptive Coordination-driven Supramolecular Chemistry - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie Année : 2020

Straightforward Preparation of a Solid-state Luminescent Cu-11 Polymetallic Assembly via Adaptive Coordination-driven Supramolecular Chemistry

Résumé

The tridentate dpmp ligand was reacted with Cu-I salt and cyano ligand affording selectively and unexpectedly the polymetallic Cu-11 complex 2 along one-step reaction. The formation of this derivative 2 can be explained by self-assembling processes controlled by adaptive coordination-driven supramolecular chemistry. The solid-state photophysical behavior of 2 was studied suggesting TADF properties.
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Dates et versions

hal-02498316 , version 1 (15-04-2020)

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Sloane Evariste, Mehdi El Sayed Moussa, Hok-Lai Wong, Guillaume Calvez, Vivian Wing-Wah Yam, et al.. Straightforward Preparation of a Solid-state Luminescent Cu-11 Polymetallic Assembly via Adaptive Coordination-driven Supramolecular Chemistry. Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie, 2020, 646 (13), pp.754-760. ⟨10.1002/zaac.201900314⟩. ⟨hal-02498316⟩
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