In situ exsolution of Ni particles on the PrBaMn2O5 SOFC electrode material monitored by high temperature neutron powder diffraction under hydrogen

M. Bahout (1, 2) , P.B. Managutti (1, 2) , V. Dorcet (1, 2) , A. Le Gal La Salle (3) , Serge Paofai (1, 2) , T.C. Hansen (4)

1 ISCR - Institut des Sciences Chimiques de Rennes
2 ScanMAT - Synthèse Caractérisation Analyse de la Matière
3 IMN - Institut des Matériaux Jean Rouxel
4 ILL - Institut Laue-Langevin

NiO has been incorporated into the Pr0.5Ba0.5MnO3−δ perovskite to produce, upon heating under a hydrogen atmosphere, in situ exsolved Ni-catalysts supported on the PrBaMn2O5 anode material. Transmission electron microscopy (TEM) and neutron powder diffraction (NPD) showed that the initial composition obtained by annealing in air at 950 °C consists of two perovskite phases: orthorhombic Pr0.65Ba0.35Mn0.975Ni0.025O3 (S.G. Ibmm, ∼75 wt%) and 2H-hexagonal BaMnO3−δ (S.G. P63/mcm, ∼25 wt%). On heating the two-phase sample under wet hydrogen, MnO particles exsolve at T ∼ 500 °C meanwhile the orthorhombic phase transforms to tetragonal (S.G. I4/mcm) then to cubic (S.G. Pm[3 with combining macron]m) at T ∼ 665 °C. When the temperature approaches 900 °C, the emergence of Ni metal particles was detected in the neutron diffraction patterns meanwhile the two perovskite phases start to transform into a Ni-free layered double perovskite, PrBaMn2O5. In situ real time observation of the structural changes under hydrogen atmosphere provided evidence of the simultaneity of Ni exsolution and phase transformation within our timescale resolution. From quantitative Rietveld analysis, the fraction of exsolved nickel represents the whole amount of Ni introduced in the synthesis. Impedance spectroscopy measurements in a 5% H2/Ar atmosphere show promising electrochemical performance for the Ni-exsolved layered perovskite electrode with a polarization resistance of 0.4 Ω cm2 at 800 °C (0.135 Ω cm2 at 850 °C) without any optimization.

Keywords: Impedance spectroscopy measurements; Initial composition; Barium compounds; Real time observation; Orthorhombic phase; Polarization resistances; Electrode material; Anodes; Electrochemical electrodes; Electrochemical impedance spectroscopy; High resolution transmission electron microscopy; Hydrogen; Manganese oxide; Neutron powder diffraction; Neutrons; Nickel; Nickel oxide; Perovskite; Powder metals; Praseodymium compounds; Rietveld analysis; Solid oxide fuel cells (SOFC); Electrochemical performance; Hydrogen atmosphere

Domains: Chemical Sciences; Material chemistry

M. Bahout, P.B. Managutti, V. Dorcet, A. Le Gal La Salle, Serge Paofai, et al.. In situ exsolution of Ni particles on the PrBaMn2O5 SOFC electrode material monitored by high temperature neutron powder diffraction under hydrogen. Journal of Materials Chemistry A, 2020, 8 (7), pp.3590-3597. ⟨10.1039/c9ta10159d⟩. ⟨hal-02500038⟩