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Journal articles
Bipyrrole boomerangs via Pd-mediated tandem cyclization-oxygenation. Controlling reaction selectivity and electronic properties
Abstract : Boomerang-shaped bipyrroles containing donor-acceptor units were obtained through a tandem palladium-mediated reaction consisting of a cyclization step, involving double C-H bond activation, and a double alpha-oxygenation. The latter reaction can be partly suppressed for the least reactive systems, providing access to alpha-unsubstituted boomerangs for the first time. These "alpha-free" systems are highly efficient fluorophores, with emission quantum yields exceeding 80% in toluene. Preliminary measurements show that helicene-like boomerangs may be usable as circularly polarized luminescent materials.
Cited literature [40 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-02797043
Contributor : Laurent Jonchère <>
Submitted on : Friday, June 5, 2020 - 2:24:26 PM
Last modification on : Tuesday, January 19, 2021 - 11:07:30 AM
Contributor : Laurent Jonchère <>
Submitted on : Friday, June 5, 2020 - 2:24:26 PM
Last modification on : Tuesday, January 19, 2021 - 11:07:30 AM
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