Remote Deprotometalation-Iodolysis of N,N-Diisopropyl-2-trimethylsilylferrocenecarboxamide: A New Route Toward 1,1′-Disubstituted Ferrocenes
Résumé
The 1,1′-disubstitution is currently the most frequent substitution pattern encountered in the ferrocene series. Here an original access based on the remote deprotometalation of N,N-diisopropyl-2-trimethylsilylferrocenecarboxamide is reported. The key intermediate, 1′-iodo-N,N-diisopropylferrocenecarboxamide, was prepared in multiple grams and was further functionalized toward fifteen 1′-substituted iodoferrocenes.
Domaines
Chimie
Fichier principal
Kadari-2020-Remote deprotometalation-iodolysis of N,N-diisopropyl-2-trimethylsilylferrocenecarboxamide (1).pdf (624.99 Ko)
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Supporting informations (1).pdf (3.59 Mo)
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