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Remote Deprotometalation-Iodolysis of N,N-Diisopropyl-2-trimethylsilylferrocenecarboxamide: A New Route Toward 1,1′-Disubstituted Ferrocenes

Abstract : The 1,1′-disubstitution is currently the most frequent substitution pattern encountered in the ferrocene series. Here an original access based on the remote deprotometalation of N,N-diisopropyl-2-trimethylsilylferrocenecarboxamide is reported. The key intermediate, 1′-iodo-N,N-diisopropylferrocenecarboxamide, was prepared in multiple grams and was further functionalized toward fifteen 1′-substituted iodoferrocenes.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-02948487
Contributor : Laurent Jonchère <>
Submitted on : Thursday, December 3, 2020 - 3:39:49 PM
Last modification on : Wednesday, April 7, 2021 - 3:18:14 PM
Long-term archiving on: : Thursday, March 4, 2021 - 7:26:17 PM

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Lingaswamy Kadari, Thierry Roisnel, William Erb, Palakodety Radha Krishna, Florence Mongin. Remote Deprotometalation-Iodolysis of N,N-Diisopropyl-2-trimethylsilylferrocenecarboxamide: A New Route Toward 1,1′-Disubstituted Ferrocenes. SYNTHESIS, Georg Thieme Verlag, 2020, 52 (21), pp.3153-3161. ⟨10.1055/s-0040-1707175⟩. ⟨hal-02948487⟩

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