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Remote Deprotometalation-Iodolysis of N,N-Diisopropyl-2-trimethylsilylferrocenecarboxamide: A New Route Toward 1,1′-Disubstituted Ferrocenes

Abstract : The 1,1′-disubstitution is currently the most frequent substitution pattern encountered in the ferrocene series. Here an original access based on the remote deprotometalation of N,N-diisopropyl-2-trimethylsilylferrocenecarboxamide is reported. The key intermediate, 1′-iodo-N,N-diisopropylferrocenecarboxamide, was prepared in multiple grams and was further functionalized toward fifteen 1′-substituted iodoferrocenes.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-02948487
Contributor : Laurent Jonchère <>
Submitted on : Thursday, September 24, 2020 - 4:48:13 PM
Last modification on : Saturday, September 26, 2020 - 3:08:29 AM

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Lingaswamy Kadari, Thierry Roisnel, William Erb, Palakodety Radha Krishna, Florence Mongin. Remote Deprotometalation-Iodolysis of N,N-Diisopropyl-2-trimethylsilylferrocenecarboxamide: A New Route Toward 1,1′-Disubstituted Ferrocenes. Synthesis, 2020, pp.s--0040--1707175. ⟨10.1055/s-0040-1707175⟩. ⟨hal-02948487⟩

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