Highly Efficient Thermally Activated Delayed Fluorescence via an Unconjugated Donor–Acceptor System Realizing EQE of Over 30%

Chen‐chen Peng (1) , Sheng‐Yi Yang (1) , Hong‐cheng Li (1) , Guo‐hua Xie (2) , Lin‐song Cui (3) , Sheng‐nan Zou (1) , Cyril Poriel (4) , Zuo‐quan Jiang (1) , Liang‐sheng Liao (1)

1 Soochow University
2 Wuhan University [China]
3 CAM - University of Cambridge [UK]
4 ISCR - Institut des Sciences Chimiques de Rennes

In this work, two novel thermally activated delayed fluorescence (TADF) emitters, 2tDMG and 3tDMG, are synthesized for high‐efficiency organic light‐emitting diodes (OLEDs), The two emitters have a tilted face‐to‐face alignment of donor (D)/acceptor (A) units presenting intramolecular noncovalent interactions. The two TADF materials are deposited either by an evaporation‐process or by a solution‐process, both of them leading to high OLED performance. 2tDMG used as the emitter in evaporation‐processed OLEDs achieves a high external quantum efficiency (EQE) of 30.8% with a very flat efficiency roll‐off of 7% at 1000 cd m−2. The solution‐processed OLEDs also display an interesting EQE of 16.2%. 3tDMG shows improved solubility and solution processability as compared to 2tDMG, and thus a high EQE of 20.2% in solution‐processed OLEDs is recorded. The corresponding evaporation‐processed OLEDs also reach a reasonably high EQE of 26.3%. Encouragingly, this work provides a novel strategy to address the imperious demands for OLEDs with high EQE and low roll‐off.

Mots clés: intramolecular spatial charge transfer; organic light-emitting diodes; thermally activated delayed fluorescence; unconjugated system

Domaines: Matériaux

Chen‐chen Peng, Sheng‐Yi Yang, Hong‐cheng Li, Guo‐hua Xie, Lin‐song Cui, et al.. Highly Efficient Thermally Activated Delayed Fluorescence via an Unconjugated Donor–Acceptor System Realizing EQE of Over 30%. Advanced Materials, 2020, 32 (48), pp.2003885. ⟨10.1002/adma.202003885⟩. ⟨hal-02997314⟩