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A NdIIICuII molecular material with a honeycomb-like structure

Abstract : The first two-dimensional molecular material Nd(III)−Cu(II) has been synthesized by reaction in DMF of [Cu(opba)]2- and Nd3+. The compound {Nd2[Cu(opba)0.5(ox)]3·9DMF}·4.5DMF has been structurally characterized. Its crystalline structure can be described as the superposition of honeycomb-like molecular motifs. This material exhibits a quasi nonmagnetic ground state at low temperature.
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https://hal.archives-ouvertes.fr/hal-03670866
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Submitted on : Tuesday, May 17, 2022 - 6:27:19 PM
Last modification on : Thursday, May 19, 2022 - 3:18:56 AM

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Carole Daiguebonne, Olivier Guillou, Myrtil L Kahn, Olivier Kahn, Robert Oushoorn, et al.. A NdIIICuII molecular material with a honeycomb-like structure. Inorganic Chemistry, American Chemical Society, 2001, 40 (1), pp.176-178. ⟨10.1021/ic000375l⟩. ⟨hal-03670866⟩

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